File name: Pandora108s1_Egbert_20190331_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T092044.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v4d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20190331_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20190331 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190331T110838.0Z 7029.464329 356 1 32.01 2 89.75 84.46 74.51 136.85 0.00 1 0.00 1 0 15 8.253e-02 7.782e-02 6.286e-02 6.057e-02 -3.307199e+03 3.666900e+03 3.309978e+02 -6.000000e+00 4.570845e+03 274.97 -2.00 20.00 -2.00 505.21 0.00e+00 2.161544e-03 1.645790e-03 6.668240e-05 -6.000000e+00 2.292978e-03 274.97 -2.00 20.00 -2.00 499.60 0.00e+00 3.644715e+00 1.280183e+00 1.786352e-02 -6.000000e+00 1.654122e+00 226.89 -2.00 3.58 -2.00 501.29 0.00e+00 20.330 0.165 489.00 513.00 1 9.2970e+00 9.8054e-02 3.6400e-02 -6.0000e+00 1.2682e-01 1.5493e-01 2.4896e-02 2.0628e-03 -6.0000e+00 3.2405e-02 8.0070e-06 -1.5784e-03 6.3733e-03 4.6727e-05 -6.0000e+00 9.0936e-03 -3.0817e-02 2.5641e-04 12 8 8 10 0 0 18.31 19.79 2.82 -0.03082 -0.04177 8 2 1 4 0 4000.000 24.65 15.00 19.79 -5924 7407 -3362 5972 -8478 -2565 -7860 -5101 5013 -4164 14407 -2634 9690 -4653 13516 -9053 6018 -1950 5493 1690 -4075 8251 -709 5572 -1089 12016 -6236 6906 -3288 -919 4886 -6403 12170 -7539 9910 -9202 2642 -5230 7279 -5631 -3652 5871 -2447 14501 -1060 5394 -10363 4777 -8203 2036 719 -4918 14184 -3554 16423 -9529 8003 -7442 5882 -3650 -1479 5052 -2268 7505 -5652 13575 -3468 4590 -1193 6572 -1141 -4681 2105 -10933 13281 -7784 10974 -6336 7900 778 1818 495 -4484 1518 4356 3167 -11776 9239 -12703 11288 -2819 3081 4394 2096 11850 -11790 10512 -9304 18737 -9350 6235 -6768 -262 10758 -6305 8677 -14290 5437 -9930 24641 -7774 9036 -472 3852 7226 -4378 7461 -7004 5078 -1674 21268 -8699 14578 -6387 4912 9289 -1407 8116 -13747 15171 -9536 13547 -2784 5621 -6470 7298 1659 -6362 562 -4722 10913 -14411 11122 -6373 4236 2588 4462 1748 -7888 6804 -5997 -6425 7074 -3665 6122 -10338 -3017 -9923 -6330 5626 -5078 14381 -3070 9830 -5372 12908 -10844 6267 -2241 5987 1942 -4991 8949 -842 6224 -1304 12643 -7840 7527 -3886 -1032 5062 -7394 11820 -9152 10374 -11817 3008 -6378 7737 -6745 -4276 6272 -2865 14475 -1247 5966 -13363 5232 -10047 2197 764 -5387 12628 -3778 14533 -11209 8074 -8134 6157 -4195 -1660 5316 -2356 7694 -6010 12818 -3499 4200 -1139 5721 -1061 -4491 1894 -11302 10839 -7815 9010 -6080 6486 681 1574 435 -4169 1336 3749 2772 -11998 7632 -13069 9156 -2649 2758 3933 1939 9964 -12480 8787 -9295 13809 -8925 5027 -6226 -229 8620 -6081 7210 -14772 4545 -9577 16819 -7421 7419 -434 3449 6326 -4331 6569 -7101 4521 -1573 15674 -8562 11320 -6129 4227 7673 -1295 6784 -14279 11780 -9433 10520 -2507 4587 -5920 5847 1427 -6041 506 -4531 9014 -15395 9241 -6336 3792 2343 3906 1539 -7491 5519 -5546 SO 20190331T111255.0Z 7029.467303 360 1 32.01 2 88.99 85.21 74.00 137.74 0.00 1 0.00 1 0 15 3.114e-02 3.048e-02 4.259e-02 4.153e-02 1.865572e+03 2.692636e+03 6.828582e+01 -6.000000e+00 1.724276e+03 274.97 -2.00 20.00 -2.00 505.21 0.00e+00 7.295127e-04 1.129622e-03 5.706396e-05 -6.000000e+00 8.657521e-04 274.97 -2.00 20.00 -2.00 499.64 0.00e+00 1.845006e+00 8.849474e-01 3.048670e-02 -6.000000e+00 6.277324e-01 226.89 -2.00 3.58 -2.00 501.33 0.00e+00 18.788 0.130 489.00 513.00 1 9.2699e+00 6.7635e-02 3.1846e-02 -6.0000e+00 4.8058e-02 1.6685e-01 1.7332e-02 1.8216e-03 -6.0000e+00 1.2408e-02 1.1839e-05 7.8588e-05 4.3861e-03 2.2549e-05 -6.0000e+00 3.4415e-03 2.6786e-02 -3.9485e-04 12 8 8 10 0 0 -70.33 19.80 2.03 0.02679 0.02733 8 2 1 4 0 4000.000 24.65 15.00 19.80 900000 341 -3240 900 2138 3502 106 3287 -3395 -1892 -3227 2050 -1806 -1613 1836 1035 2622 -2308 -2975 -1882 2088 2308 2027 -1056 -506 261 -1699 5385 -6147 4891 -650 -107 -881 3224 2603 -4035 4049 -2027 2258 -5933 950 1417 1092 2664 2529 -1274 1032 1653 -5808 3497 -1015 1548 -6 -1846 -4059 1936 -944 -1437 88 -3986 2170 1194 3442 -4695 27 -2839 -329 827 3720 4605 -283 2993 -4398 5355 2348 2729 4280 687 6226 -3929 739 -1611 126 5120 -1022 -4267 -6304 -482 -1641 4801 -3366 -392 -3620 -2255 -1809 3156 -2136 -17 2167 1596 5294 -2669 4447 -2899 512 1828 3142 1639 2042 -666 -1537 2748 -2576 1481 -3467 3568 -1141 -982 65 -260 3847 -267 -552 -1955 3217 -2970 3523 -2656 -2894 178 -5505 6555 -5100 -736 -4915 -689 7216 5692 -124 -2923 921 387 3454 -3124 7073 -6890 4689 469 2677 120 -3819 900000 346 -3475 956 2309 3821 121 3708 -4107 -2240 -3820 2267 -2044 -1796 1956 1110 2793 -2629 -3489 -2221 2387 2637 2325 -1249 -597 306 -2024 5916 -7435 5156 -707 -114 -962 3458 2888 -4866 4507 -2377 2506 -7067 1051 1562 1216 2946 2825 -1485 1172 1846 -6874 3686 -1088 1574 -6 -1898 -4324 1991 -1023 -1589 96 -4541 2319 1290 3642 -4935 29 -2878 -320 853 3674 4445 -260 2649 -4205 4684 2134 2470 3773 618 5214 -3610 647 -1448 112 4357 -932 -4051 -6134 -443 -1525 4183 -3195 -364 -3511 -2171 -1730 2836 -1984 -15 1837 1331 4200 -2298 3634 -2625 460 1643 2781 1456 1786 -597 -1397 2422 -2428 1356 -3362 3242 -1091 -939 62 -244 3405 -242 -498 -1783 2792 -2749 3058 -2449 -2669 158 -5170 5401 -4652 -634 -4383 -591 5799 4728 -111 -2725 834 354 3080 -2987 6116 -6822 4085 418 2287 104 -3431 SO 20190331T111706.0Z 7029.470208 364 1 32.01 2 88.24 85.93 73.51 138.61 0.00 1 0.00 1 0 15 4.377e-02 4.080e-02 3.333e-02 3.243e-02 3.634538e+03 2.197452e+03 3.332485e+02 -6.000000e+00 2.423538e+03 274.97 -2.00 20.00 -2.00 505.23 0.00e+00 2.150317e-05 8.795014e-04 1.123560e-05 -6.000000e+00 1.216146e-03 274.97 -2.00 20.00 -2.00 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