File name: Pandora108s1_Egbert_20190420_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T092700.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v4d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20190420_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20190420 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190420T103346.0Z 7049.440116 164 1 32.01 2 89.78 74.08 81.66 244.12 0.00 1 0.00 1 0 50 1.827e-01 1.519e-01 2.141e-01 1.986e-01 -4.707223e+03 1.191385e+04 3.710070e+02 -6.000000e+00 1.021409e+04 277.28 -2.00 20.00 -2.00 505.09 0.00e+00 1.904521e-03 5.504140e-03 2.015947e-05 -6.000000e+00 5.110105e-03 277.28 -2.00 20.00 -2.00 499.77 0.00e+00 2.300630e+00 4.226420e+00 2.694193e-02 -6.000000e+00 3.691201e+00 228.51 -2.00 3.58 -2.00 501.38 0.00e+00 20.300 0.164 489.00 513.00 1 1.0597e+01 3.2581e-01 3.6363e-02 -6.0000e+00 2.8272e-01 1.7866e-01 8.4933e-02 2.0071e-03 -6.0000e+00 7.3071e-02 2.3666e-06 -3.6666e-02 2.0421e-02 5.4742e-05 -6.0000e+00 2.0216e-02 4.7970e-02 9.9493e-05 12 8 8 10 0 0 -134.11 19.81 10.81 0.04797 -0.20636 8 2 1 4 0 4000.000 24.65 15.00 19.81 -11957 16013 -3458 941 9913 -15338 22078 -17528 14560 -8670 17754 7709 3379 7442 11854 25546 -20121 18680 -3514 29119 -11858 23534 3198 11601 8813 -8949 7926 -7636 23622 -12287 17906 -22083 20358 -5006 6742 8100 -14069 15313 -10653 -4476 -8153 4335 -8842 25173 -2213 -5051 -9276 14846 28756 -5348 6133 -13773 -7677 -13876 13096 -7428 11122 15266 1956 21318 2854 8448 8410 23027 -10341 8246 7236 -48 -1737 -7454 2534 -16746 9987 -14923 7444 -6662 13575 -4270 1612 1622 -6882 19161 -17944 25789 -20644 8735 -6044 4977 11753 -3798 24675 -16653 11728 -19428 30633 4185 7299 8157 18350 9452 -9488 33380 -21436 57912 -27356 17427 -8334 1099 -433 23858 15588 -20135 27061 -4699 88782 -1371 23686 -15897 11922 -5151 6744 38288 2451 23972 -15425 14949 -22318 34650 -19855 26233 -11211 -8786 17341 10596 25778 -14003 20123 -14891 28682 -11534 18094 -2308 1089 21448 8017 8340 -22163 39286 -13677 26562 900000 -14136 13899 -3622 958 9494 -19511 19824 -23869 14599 -11028 17270 8191 3692 7685 11531 21409 -26498 16773 -3996 24403 -15262 21484 3590 11979 9364 -11383 8540 -9599 21563 -15813 16614 -29742 17670 -5619 6861 8364 -18528 15124 -13551 -5292 -9882 4606 -10718 21850 -2550 -6047 -11660 14663 24529 -6323 6332 -16901 -8616 -16197 11563 -8114 10320 13936 2078 18822 3033 8471 8432 19987 -12535 8268 7255 -51 -1845 -8255 2503 -19798 8967 -17196 6907 -7178 11986 -4473 1568 1553 -7106 15198 -20677 19296 -24715 7844 -6331 4692 10377 -3922 19202 -18281 10530 -22408 23379 3896 7100 7255 15652 8628 -9493 22979 -23533 31199 -32693 13561 -8454 1008 -397 18209 11914 -22104 18802 -4571 37202 -1333 18103 -18114 10271 -5225 5998 24474 2214 17322 -16504 11841 -25741 22630 -22349 18591 -11529 -8790 13253 8540 17553 -14010 14261 -15106 19131 -11701 13829 -2181 999 16095 6907 7185 -25870 24566 -14254 18086 900000 SO 20190420T103750.0Z 7049.442940 168 1 32.01 2 89.07 74.79 82.31 244.84 0.00 1 0.00 1 0 15 2.033e-01 1.797e-01 1.653e-01 1.503e-01 3.791126e+03 1.043337e+04 9.195125e+01 -6.000000e+00 1.137022e+04 277.28 -2.00 20.00 -2.00 505.21 0.00e+00 -3.260486e-03 4.188257e-03 1.610229e-04 -6.000000e+00 5.688054e-03 277.28 -2.00 20.00 -2.00 499.55 0.00e+00 3.715401e+00 3.226910e+00 1.108701e-01 -6.000000e+00 4.107223e+00 228.51 -2.00 3.58 -2.00 501.27 0.00e+00 18.941 0.133 489.00 513.00 1 1.0445e+01 2.4892e-01 3.3473e-02 -6.0000e+00 3.1462e-01 1.2273e-01 6.2024e-02 2.4557e-03 -6.0000e+00 8.1254e-02 3.1239e-06 1.7464e-03 1.5339e-02 6.5946e-05 -6.0000e+00 2.2503e-02 -3.0167e-02 6.1036e-04 12 9 8 11 8 0 88.16 19.80 -0.79 -0.03017 -0.01805 8 2 1 4 0 4000.000 24.65 15.00 19.80 6714 24826 1092 29302 -17292 29330 -22853 25744 -15019 3979 5091 11187 11151 -15915 30184 -14083 36240 -28109 21521 3108 14092 7069 -632 23401 -8644 36002 -10953 27403 -4989 20947 -19686 3597 -2255 -5861 14304 -18993 25772 -7739 17669 -14947 5157 6626 10877 -1391 -21 36887 -16869 23391 -12989 28896 -6788 7343 -14388 16076 13961 -9937 29998 -5636 30319 -21778 14867 -5140 10721 -4684 -5851 11479 -6837 18437 -28030 32567 -12684 34151 -4275 8545 -1986 2185 17886 -8890 36342 137 26972 -37072 18368 -13355 27035 31213 -2928 28026 -11315 28381 -9255 21435 -10556 24246 -19631 -8181 -1761 8630 17957 -8820 49733 -14845 36140 -13893 20386 8719 6406 5197 -4781 26363 -12174 43018 -28501 26047 196 45072 -16616 6140 1352 -12251 10870 -21619 25171 -5584 22160 -78 1171 7963 720 21293 6430 17454 -254 48577 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900000 SO 20190420T104157.0Z 7049.445799 172 1 32.01 2 88.36 75.50 82.97 245.57 0.00 1 0.00 1 0 22 1.474e-01 1.321e-01 1.266e-01 1.193e-01 6.516682e+03 8.663283e+03 3.464743e+02 -6.000000e+00 8.240407e+03 277.28 -2.00 20.00 -2.00 505.19 0.00e+00 -1.140564e-03 3.280727e-03 1.138720e-04 -6.000000e+00 4.119279e-03 277.28 -2.00 20.00 -2.00 499.66 0.00e+00 7.064836e-01 2.540793e+00 1.190550e-01 -6.000000e+00 2.960941e+00 228.51 -2.00 3.58 -2.00 501.32 0.00e+00 17.097 0.098 489.00 513.00 1 1.0660e+01 1.9463e-01 2.9071e-02 -6.0000e+00 2.2710e-01 1.6199e-01 4.9046e-02 2.6414e-03 -6.0000e+00 5.8130e-02 4.0102e-06 -1.6028e-02 1.1885e-02 3.6590e-05 -6.0000e+00 1.6251e-02 2.2827e-02 -1.9593e-04 12 8 8 10 0 0 77.99 19.80 9.41 0.02283 -0.08835 8 2 1 4 0 4000.000 24.65 14.99 19.80 -10614 20053 -5745 9094 -10321 -7537 3894 -5248 16824 -8328 23855 -12917 19936 773 4322 -7735 -6628 11220 -4237 16604 2272 28960 -9007 13727 -5618 8985 2340 -2715 11025 -8696 4119 -8262 19047 -5332 9924 3644 -6671 942 -5407 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