File name: Pandora108s1_Egbert_20190531_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T093210.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v4d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20190531_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20190531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190531T094605.0Z 7090.407002 302 1 32.01 2 89.78 58.88 76.13 93.64 0.00 1 0.00 1 0 22 1.096e-01 1.023e-01 1.097e-01 1.048e-01 7.784964e+03 7.805078e+03 2.847553e+02 -6.000000e+00 6.239329e+03 281.87 -2.00 20.00 -2.00 505.22 0.00e+00 -2.079421e-03 2.916177e-03 1.354751e-04 -6.000000e+00 3.099287e-03 281.87 -2.00 20.00 -2.00 499.58 0.00e+00 1.595390e+00 2.241116e+00 9.203330e-02 -6.000000e+00 2.219144e+00 231.87 -2.00 3.58 -2.00 501.28 0.00e+00 20.150 0.161 489.00 513.00 1 1.0040e+01 1.7179e-01 3.6652e-02 -6.0000e+00 1.7016e-01 1.7157e-01 4.3731e-02 2.5704e-03 -6.0000e+00 4.4024e-02 4.6853e-06 -6.8149e-03 1.0612e-02 4.9621e-05 -6.0000e+00 1.2133e-02 5.7410e-02 -7.5252e-04 12 8 8 10 0 0 42.35 19.76 10.37 0.05741 0.01014 8 2 1 4 0 4000.000 24.65 15.00 19.76 900000 -7502 -4726 9806 -8797 6376 -9941 3479 -6514 19589 -4338 10029 -7026 7197 3332 -3944 5848 -7622 18854 -9116 28630 -7078 6230 -7622 -80 4813 -9018 15108 -8206 24043 -9476 7872 -10511 734 -2212 4291 -312 -6056 9742 820 18498 -12163 14389 -9193 8457 622 -4082 11952 -5372 10427 -12988 13611 -3088 15843 -9385 6810 3727 -6999 5939 -4996 16265 -8604 18220 -13720 12121 2996 4332 -6849 -5078 10227 -660 17662 -8630 11854 -6932 775 -11735 10556 1835 -12142 9896 -8544 19297 -4528 16533 -7785 5952 -2109 -277 6221 540 5675 -15359 18214 -9549 17381 -7683 8704 -9886 -2778 11861 1522 3095 -4759 23922 -4948 2985 1012 12852 -11461 -4783 13333 -6840 19245 -3969 18848 -18002 17565 -5842 8480 -3740 -6274 7015 5878 9691 -12683 23486 -4703 8710 -7927 -5624 -2648 -5767 13331 -6175 17105 -17507 22363 -4203 16583 -8306 9428 -346 -6804 5218 3257 13456 -16648 18992 -13711 8832 900000 -8261 -5116 9427 -10509 6724 -12617 3928 -8207 19014 -5304 10483 -8590 7523 3576 -4527 6113 -9247 17948 -11741 25651 -9116 7036 -9888 -96 5525 -11867 15510 -10492 21766 -11674 8008 -12851 816 -2601 4846 -373 -7630 10365 941 17609 -15665 14234 -11583 8997 720 -4953 12270 -6468 10509 -16122 12576 -3285 13751 -10511 6610 3827 -7484 6152 -5300 15180 -9422 16665 -15846 11765 2896 4077 -7089 -5083 9449 -615 14836 -8639 9736 -6939 723 -12349 8760 1633 -12258 7958 -8260 14198 -4261 12730 -7726 5194 -2003 -258 5429 499 5000 -16819 14336 -9885 13531 -7493 7000 -9303 -2377 8625 1224 2489 -4275 16782 -4784 2707 935 10446 -11766 -4583 10722 -6788 14818 -3871 14674 -20329 13975 -5897 7400 -3648 -6173 5941 4978 7876 -12912 16677 -4426 7153 -7663 -5293 -2401 -5329 10036 -5599 12292 -17973 15688 -3920 12768 -8314 7985 -326 -6868 4688 2982 11051 -18231 14298 -14076 7178 SO 20190531T095036.0Z 7090.410139 306 1 32.01 2 89.08 59.67 75.34 94.41 0.00 1 0.00 1 0 15 7.409e-02 6.965e-02 6.977e-02 6.807e-02 7.470284e+03 4.922798e+03 3.209853e+02 -6.000000e+00 4.217846e+03 281.87 -2.00 20.00 -2.00 505.29 0.00e+00 1.655315e-03 1.895270e-03 8.184059e-05 -6.000000e+00 2.092821e-03 281.87 -2.00 20.00 -2.00 499.89 0.00e+00 2.760675e+00 1.415563e+00 8.893213e-02 -6.000000e+00 1.489047e+00 231.87 -2.00 3.58 -2.00 501.59 0.00e+00 18.841 0.131 489.00 513.00 1 9.6398e+00 1.0863e-01 3.2737e-02 -6.0000e+00 1.1438e-01 1.2244e-01 2.7075e-02 2.4246e-03 -6.0000e+00 2.9232e-02 7.3368e-06 -2.2415e-03 6.9877e-03 2.7455e-05 -6.0000e+00 8.1684e-03 -2.8220e-02 1.6239e-04 12 9 8 11 8 0 -281.82 19.76 1.29 -0.02822 -0.04377 8 2 1 4 0 4000.000 24.65 14.99 19.76 1916 -5237 208 -12374 11370 -4625 8137 -8266 3059 -991 -1848 1531 533 4286 -6102 19386 -2657 5800 -6097 7653 57 -3399 5251 -3539 10361 -3417 6181 -4737 2281 -6617 291 1718 -1718 4865 -3561 4703 -2849 10997 -2593 4696 -6251 658 -7381 3976 1984 -9782 5590 -4471 11185 600 2953 -5800 1735 -5744 -6715 7235 1666 6225 -9695 9786 3337 950 -2742 -1399 1912 -6115 11342 443 12816 -3987 5117 -7522 5084 -2208 5509 2055 -2394 9857 -13273 18847 -2713 7884 -6736 9734 -1511 2512 5642 -3809 14844 -11373 10008 -10353 10437 -3200 3396 4739 -11444 -1937 -1658 1123 -4682 16139 210 6143 -3325 83 -4576 -2188 7789 -8462 7833 -10461 13893 -1801 7608 9879 2113 -6575 -2080 -7438 -6920 13803 -8140 20166 897 10583 -5476 1522 1390 -5288 4051 -4745 11271 -10821 18559 -3390 2172 -5747 158 -2174 -6678 11254 -8245 13409 -3880 8909 -2534 7658 -275 -8589 -1532 1907 -5618 216 -15062 11249 -5501 8683 -10522 3486 -1167 -2168 1711 593 4526 -7089 17456 -3013 6158 -7456 8295 67 -4157 5896 -4348 11115 -3892 6906 -5395 2574 -7334 294 1701 -1781 4842 -3965 4898 -3201 10664 -2847 4747 -7024 693 -8483 4121 2117 -11794 5765 -5047 10617 619 2894 -6041 1647 -5864 -7029 6756 1684 6100 -11192 9289 3373 984 -2955 -1486 1952 -6683 10242 438 11048 -4010 4647 -7718 4617 -2175 5060 1950 -2346 8395 -14029 14312 -2547 6674 -6635 8191 -1434 2307 5037 -3732 12034 -11963 8524 -10890 8996 -3169 3119 4207 -11626 -1739 -1446 933 -4084 11510 180 5138 -3156 77 -4485 -2077 6634 -8466 6712 -10896 11477 -1756 6792 8668 2017 -6882 -2081 -7785 -7102 11332 -8228 15314 829 8905 -5423 1406 1283 -5210 3617 -4577 9137 -10827 13807 -3166 1950 -5691 150 -2141 -6956 9874 -8841 11627 -4002 8045 -2535 6798 -259 -8726 -1454 SO 20190531T095504.0Z 7090.413241 310 1 32.01 2 88.39 60.44 74.55 95.17 0.00 1 0.00 1 0 15 7.395e-02 7.033e-02 4.621e-02 4.488e-02 5.821114e+03 3.247130e+03 2.607372e+02 -6.000000e+00 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