File name: Pandora108s1_Egbert_20190706_L2Fit_fout2c5d20180328p1-8.txt File generation date: 20251214T094104.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v4d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20190706_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20190706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0568 305.1976 305.3385 305.4793 305.6201 305.7609 305.9017 306.0425 306.1833 306.3241 306.4648 306.6056 306.7463 306.8871 307.0278 307.1685 307.3092 307.4499 307.5905 307.7312 307.8719 308.0125 308.1531 308.2937 308.4344 308.5750 308.7155 308.8561 308.9967 309.1372 309.2778 309.4183 309.5588 309.6993 309.8399 309.9803 310.1208 310.2613 310.4017 310.5422 310.6826 310.8231 310.9635 311.1039 311.2443 311.3846 311.5250 311.6654 311.8057 311.9461 312.0864 312.2267 312.3670 312.5073 312.6476 312.7879 312.9281 313.0684 313.2086 313.3488 313.4891 313.6293 313.7695 313.9096 314.0498 314.1900 314.3301 314.4703 314.6104 314.7505 314.8906 315.0307 315.1708 315.3109 315.4509 315.5910 315.7310 315.8711 316.0111 316.1511 316.2911 316.4311 316.5710 316.7110 316.8510 316.9909 317.1308 317.2707 317.4106 317.5505 317.6904 317.8303 317.9702 318.1100 318.2498 318.3897 318.5295 318.6693 318.8091 318.9489 319.0886 319.2284 319.3682 319.5079 319.6476 319.7873 319.9270 320.0667 320.2064 320.3461 320.4857 320.6254 320.7650 320.9047 321.0443 321.1839 321.3235 321.4630 321.6026 321.7422 321.8817 322.0213 322.1608 322.3003 322.4398 322.5793 322.7188 322.8582 322.9977 323.1371 323.2765 323.4160 323.5554 323.6948 323.8342 323.9735 324.1129 324.2522 324.3916 324.5309 324.6702 324.8095 324.9488 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20190706T122729.8Z 7126.519094 3 1 33.51 2 63.25 83.57 105.92 53.63 0.00 1 0.00 1 0 17 1.166e-02 4.557e-03 4.315e-03 7.094e-04 2.870984e-01 3.668494e-04 3.432435e-03 -6.000000e+00 6.931089e-03 232.99 -2.00 3.58 -2.00 318.98 0.00e+00 4.164309e-04 8.116318e-05 1.781195e-04 -6.000000e+00 3.048227e-04 285.38 -2.00 20.00 -2.00 318.16 0.00e+00 2.209 0.000 302.00 328.00 3 1.3833e+00 1.0217e-03 2.6581e-02 -6.0000e+00 1.7415e-02 -1.2644e-02 1.1684e-03 1.5503e-02 -6.0000e+00 1.8810e-02 4.1361e-03 7.7097e-04 7.4886e-03 -6.0000e+00 1.1180e-02 -5.4482e-03 3.9441e-04 2.0577e-03 -6.0000e+00 4.6798e-03 1.1004e-02 -3.2986e-05 2.2153e-05 2.3752e-05 -6.0000e+00 3.3554e-04 -8.1991e-03 -2.6867e-07 10 0 0 10 0 0 67.59 19.77 0.18 -0.00820 -0.00845 823 161 1 5 0 40.560 24.56 15.00 19.77 -1639 -2750 -1259 -5642 -1868 -6195 282 -2089 -667 -3190 -3223 -1375 -1984 502 -1065 448 -583 979 85 543 -152 -89 1118 365 518 -439 -532 -1899 -617 -500 884 565 1015 -1196 -2941 -1415 -1822 -388 -536 -615 -1038 -797 -835 -533 -198 -426 -585 -719 -564 -237 838 447 935 934 810 918 786 408 312 792 1078 1714 1818 1708 365 -35 -9 -81 1019 747 276 345 251 97 -194 -560 -634 -877 -481 -696 -1228 -1184 -1725 -1203 -697 -348 33 435 528 528 382 269 215 306 489 74 618 629 219 -369 -382 -729 -484 -85 -893 -916 -653 -391 -21 482 368 343 174 16 -128 -127 30 -131 107 -198 -146 113 264 429 352 342 -4 797 248 124 -95 -171 -121 26 102 -64 193 233 126 -97 -94 -392 -398 -84 -157 -73 -326 -95 -313 14 -119 -42 -216 -221 -96 -156 44 -110 50 -70 122 11 73 -21 -12 158 55 82 -73 -89 -306 -93 -74 136 95 184 -230 -551 -257 -358 -87 -145 -195 -364 -294 -318 -206 -76 -164 -223 -269 -208 -88 324 187 413 436 393 456 398 208 156 393 549 929 1070 1073 234 -21 -5 -49 589 486 198 260 190 71 -146 -383 -394 -520 -296 -480 -961 -1025 -1613 -1072 -661 -352 36 478 582 562 417 270 198 273 458 77 711 801 271 -457 -490 -866 -543 -97 -1108 -1208 -900 -564 -31 704 570 540 266 25 -188 -174 41 -185 162 -320 -242 185 420 655 513 475 -6 1052 350 189 -154 -285 -206 46 191 -127 391 483 264 -198 -186 -748 -743 SU 20190706T122900.7Z 7126.520147 5 1 33.39 2 62.98 83.82 105.72 53.93 0.00 1 0.00 1 0 17 1.035e-02 4.552e-03 4.377e-03 7.321e-04 2.848337e-01 3.793549e-04 3.406006e-03 -6.000000e+00 6.151181e-03 232.99 -2.00 3.58 -2.00 318.96 0.00e+00 4.519940e-04 8.266501e-05 1.903588e-04 -6.000000e+00 2.705249e-04 285.38 -2.00 20.00 -2.00 318.13 0.00e+00 2.189 0.000 302.00 328.00 3 1.4356e+00 1.0556e-03 2.6341e-02 -6.0000e+00 1.5455e-02 -1.1453e-02 1.2050e-03 1.5367e-02 -6.0000e+00 1.6694e-02 3.5710e-03 7.9133e-04 7.4239e-03 -6.0000e+00 9.9218e-03 -5.3720e-03 4.0445e-04 2.0396e-03 -6.0000e+00 4.1532e-03 1.0675e-02 -5.6504e-05 2.3033e-05 2.3982e-05 -6.0000e+00 2.9778e-04 -8.1269e-03 3.7544e-07 10 0 0 10 0 0 74.79 19.77 0.20 -0.00813 -0.00855 823 161 1 5 0 40.558 24.65 15.00 19.77 -1770 -2552 -2385 -4299 -3610 -3497 -984 -704 -569 -2777 -2683 -1729 -778 -523 -146 -313 -692 -100 -137 611 -122 370 939 905 461 46 -1094 -1243 -847 -296 1060 654 939 -1621 -2796 -1781 -1509 -956 -266 -520 -999 -745 -793 -630 -332 -409 -740 -423 -752 -190 743 513 862 954 858 859 802 272 431 586 1193 1616 1809 1628 364 -6 -30 -1 986 903 264 330 155 156 -94 -664 -528 -902 -445 -781 -1098 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4.566e-03 4.147e-03 7.113e-04 2.820163e-01 3.676031e-04 3.377548e-03 -6.000000e+00 6.786108e-03 232.99 -2.00 3.58 -2.00 318.91 0.00e+00 4.492070e-04 7.964643e-05 1.724909e-04 -6.000000e+00 2.984504e-04 285.38 -2.00 20.00 -2.00 318.09 0.00e+00 2.169 0.000 302.00 328.00 3 1.4513e+00 1.0210e-03 2.6105e-02 -6.0000e+00 1.7051e-02 -1.1581e-02 1.1658e-03 1.5228e-02 -6.0000e+00 1.8417e-02 4.8662e-03 7.6306e-04 7.3551e-03 -6.0000e+00 1.0946e-02 -6.0940e-03 3.8969e-04 2.0235e-03 -6.0000e+00 4.5818e-03 1.0751e-02 -7.1636e-05 2.2191e-05 2.3347e-05 -6.0000e+00 3.2852e-04 -8.1965e-03 -3.5635e-06 10 0 0 10 0 0 70.29 19.78 0.20 -0.00820 -0.00873 784 154 1 5 0 42.616 24.65 15.00 19.78 913 -3820 -30 -5725 -2936 -3280 -2350 11 -2927 -538 -4526 307 -2493 851 -381 -269 -300 -436 990 -216 978 -1207 1528 -68 594 -412 -676 -1087 -765 818 57 1622 198 -843 -3206 -1005 -1744 -563 -218 -907 -729 -1036 -495 -990 -101 -607 -499 -706 -887 107 494 740 625 1156 492 1133 627 404 431 584 1209 1473 1939 1479 567 -70 285 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