File name: Pandora108s1_Egbert_20190818_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T094949.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v4d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20190818_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20190818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190818T103158.0Z 7169.438866 167 1 32.01 2 89.78 71.77 65.25 231.90 0.00 1 0.00 1 0 36 2.132e-02 2.097e-02 7.349e-03 7.258e-03 1.664816e+04 5.346699e+02 1.038144e+03 -6.000000e+00 1.235404e+03 286.61 -2.00 20.00 -2.00 505.52 0.00e+00 4.759121e-03 2.074006e-04 2.658574e-04 -6.000000e+00 6.092816e-04 286.61 -2.00 20.00 -2.00 501.48 0.00e+00 7.502679e-01 1.386965e-01 1.312597e-01 -6.000000e+00 4.268311e-01 231.64 -2.00 3.58 -2.00 502.89 0.00e+00 20.022 0.158 489.00 513.00 1 7.2411e+00 1.0631e-02 3.7655e-02 -6.0000e+00 3.2849e-02 -3.3037e-02 2.6103e-03 3.5327e-03 -6.0000e+00 8.3794e-03 7.5798e-05 1.8520e-03 7.2757e-04 1.3477e-04 -6.0000e+00 2.3517e-03 3.5321e-02 -1.9275e-04 12 8 8 10 0 0 4.52 19.77 17.61 0.03532 0.04817 8 2 1 4 0 4000.000 24.56 15.00 19.77 -5248 -4570 -1236 -408 1470 4364 2007 4793 1995 3635 392 569 -921 -2072 -725 -2643 128 -1585 1187 -166 1439 -39 1951 1504 2128 3109 383 1482 -1904 -1123 -4528 -613 -3219 52 -128 1403 2086 -57 1526 -1975 883 -1558 2790 2340 1816 2449 1421 1728 -456 336 -3214 -2439 -5461 -1840 -2566 -14 975 1116 2274 1936 3040 774 3697 1144 1458 175 442 -640 -1021 -1395 -3253 -1349 -1873 -407 -2347 -239 -3081 -2346 -2169 -2874 -1914 -3305 -73 -2872 698 -1566 -490 -674 -664 227 -829 2056 1051 2400 1161 3112 -143 -108 -2322 -3813 -3880 -3460 -1382 -1856 898 -1883 -155 -1686 -771 -1922 -943 885 247 2301 1811 4820 2890 4746 2003 2896 346 467 1125 536 2779 946 3873 -190 1415 -830 37 -731 -1811 -1948 -2624 -466 -2273 889 -447 1905 504 1159 243 1242 1949 -104 1396 -1784 -1484 -4041 -839 -4445 -3901 -1053 -357 1303 3854 1851 4345 1862 3309 364 521 -844 -1903 -654 -2445 117 -1381 1030 -148 1274 -35 1733 1351 1916 2786 352 1336 -1741 -995 -4085 -533 -2932 47 -120 1314 1939 -54 1408 -1882 822 -1502 2616 2240 1771 2392 1403 1686 -448 322 -3112 -2298 -5263 -1726 -2484 -14 963 1119 2268 1944 3030 794 3707 1179 1491 179 447 -646 -1022 -1388 -3280 -1337 -1883 -408 -2417 -240 -3152 -2348 -2142 -2842 -1874 -3298 -71 -2909 690 -1597 -496 -681 -668 227 -841 2049 1068 2400 1154 2948 -136 -99 -2135 -3510 -3571 -3229 -1311 -1852 906 -2000 -163 -1796 -813 -2065 -1017 951 271 2488 1982 5165 3200 5223 2277 3243 392 520 1230 590 3010 1052 4208 -216 1583 -876 39 -759 -1882 -2020 -2753 -486 -2459 950 -493 2083 566 1308 278 1416 2205 -120 1562 -2031 -1665 -4642 -942 SO 20190818T103604.0Z 7169.441713 171 1 32.01 2 89.08 72.48 65.81 232.81 0.00 1 0.00 1 0 50 1.705e-02 1.669e-02 4.768e-03 4.709e-03 1.769332e+04 3.492022e+02 1.129071e+03 -6.000000e+00 9.881326e+02 286.61 -2.00 20.00 -2.00 505.49 0.00e+00 4.038215e-03 1.337076e-04 2.197661e-04 -6.000000e+00 4.874524e-04 286.61 -2.00 20.00 -2.00 501.43 0.00e+00 8.362988e-01 9.017867e-02 1.246898e-01 -6.000000e+00 3.417955e-01 231.64 -2.00 3.58 -2.00 502.83 0.00e+00 18.729 0.129 489.00 513.00 1 6.9502e+00 6.9242e-03 3.3765e-02 -6.0000e+00 2.6300e-02 -4.5763e-02 1.6824e-03 3.4330e-03 -6.0000e+00 6.7174e-03 1.2146e-04 4.3962e-03 4.6216e-04 1.3543e-04 -6.0000e+00 1.8796e-03 -4.3908e-02 1.8940e-04 12 8 8 10 0 0 -38.47 19.77 14.22 -0.04391 -0.01341 8 2 1 4 0 4000.000 24.65 15.00 19.77 -4692 -1958 -2912 1112 113 2729 1706 3551 2132 2239 748 -296 101 -2128 -393 -2563 -273 -626 1338 779 939 1235 1688 2377 1085 2390 596 1579 -1314 -1331 -2354 -3106 -1275 -1429 1296 -26 1522 -573 773 -899 320 0 763 802 1153 2867 1869 1364 -336 -301 -2682 -3674 -2431 -2891 -593 -818 1146 844 2442 1308 1819 1600 2408 1900 1594 1430 -580 175 -1294 -590 -3016 -451 -2063 -273 -749 -1077 -1710 -3071 -1548 -3204 -1384 -2399 -1165 -1225 -596 -683 -1456 -973 -973 481 -559 1620 1022 2384 1244 915 799 -508 -1030 -3230 -2535 -3306 -1499 -1612 793 -957 3 -898 -1656 -80 -900 1420 43 1886 2103 3561 2814 3340 1864 1347 1498 495 674 1137 1398 1122 2761 -193 1823 259 -958 481 -1670 -154 -2275 -732 -1210 -241 700 425 1349 685 1011 794 1532 -350 138 -1368 -1526 -2599 -1464 -4033 -1660 -2568 977 95 2289 1475 3050 1860 1937 649 -256 86 -1834 -332 -2221 -235 -552 1186 706 856 1127 1541 2170 1011 2209 560 1457 -1225 -1211 -2129 -2836 -1166 -1350 1226 -25 1458 -557 736 -868 306 0 746 796 1156 2845 1874 1364 -337 -295 -2636 -3575 -2316 -2788 -572 -816 1150 863 2474 1344 1867 1656 2487 1976 1656 1474 -602 178 -1321 -592 -3085 -450 -2113 -278 -772 -1113 -1756 -3150 -1545 -3231 -1371 -2413 -1167 -1241 -608 -704 -1516 -1006 -1002 488 -576 1650 1056 2422 1254 898 759 -474 -945 -2990 -2330 -3121 -1444 -1630 816 -1028 3 -970 -1660 -80 -914 1428 44 1922 2152 3623 2924 3499 1993 1439 1575 517 695 1166 1439 1167 2843 -206 1904 275 -1024 501 -1761 -159 -2420 -778 -1318 -265 777 480 1533 793 1175 929 1777 -412 160 -1585 -1751 -3010 -1693 SO 20190818T104009.0Z 7169.444549 175 1 32.01 2 88.38 73.19 66.38 233.70 0.00 1 0.00 1 0 22 1.040e-02 1.024e-02 6.099e-03 6.036e-03 2.100672e+04 4.639531e+02 1.380066e+03 -6.000000e+00 6.024133e+02 286.61 -2.00 20.00 -2.00 505.48 0.00e+00 2.799159e-03 1.700582e-04 1.596661e-04 -6.000000e+00 2.972753e-04 286.61 -2.00 20.00 -2.00 501.28 0.00e+00 9.593449e-01 1.156451e-01 1.245163e-01 -6.000000e+00 2.086775e-01 231.64 -2.00 3.58 -2.00 502.71 0.00e+00 16.987 0.096 489.00 513.00 1 7.4668e+00 8.8561e-03 2.9437e-02 -6.0000e+00 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