File name: Pandora108s1_Egbert_20191020_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T100024.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v4d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20191020_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20191020 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191020T114615.0Z 7232.490451 218 1 32.01 2 89.76 104.74 27.53 224.92 0.00 1 0.00 1 0 22 1.293e-01 1.237e-01 1.262e-01 1.212e-01 1.499046e+03 7.544918e+03 6.107532e+01 -6.000000e+00 7.294710e+03 279.77 -2.00 20.00 -2.00 505.24 0.00e+00 9.211334e-04 3.302879e-03 1.518318e-05 -6.000000e+00 3.637175e-03 279.77 -2.00 20.00 -2.00 499.95 0.00e+00 6.764396e-01 2.485924e+00 1.911932e-02 -6.000000e+00 2.577365e+00 224.86 -2.00 3.58 -2.00 501.59 0.00e+00 20.219 0.162 489.00 513.00 1 1.0252e+01 1.9036e-01 3.6047e-02 -6.0000e+00 1.9801e-01 1.7847e-01 4.8950e-02 2.0013e-03 -6.0000e+00 5.0488e-02 3.8782e-06 -9.8920e-03 1.2788e-02 5.6104e-06 -6.0000e+00 1.4255e-02 -3.7996e-02 3.0554e-04 12 9 8 11 8 0 -281.54 19.89 -0.56 -0.03800 -0.10661 8 2 1 4 0 4000.000 24.75 15.00 19.89 14950 -11607 10906 -11830 9192 -13700 7436 -5003 7708 1437 -3747 11740 -11360 12471 -10987 11927 -1891 20111 -1457 10746 8234 -4461 4385 -8787 21927 -4606 22944 -14311 10099 -4327 27010 -9051 -1116 16688 -13380 22645 -17032 13791 -7409 976 5462 -4513 10610 -6065 18190 -11875 15924 -18223 30052 -18304 7144 9126 16139 21996 -11316 17696 -9556 15991 -9192 7449 -15188 17803 -4244 8625 410 1991 4969 -21965 10357 -13680 22642 -1161 7541 4562 3640 9687 -8181 11368 -3490 29223 -16505 19692 -8992 7312 4272 3242 15732 -16174 19201 -10578 29968 -15625 8400 -16550 15285 9440 2119 13562 -18423 14225 -1605 15949 -15993 13632 -4593 6984 22463 -8964 -1601 -17087 10625 -10669 20618 -14226 7696 232 13501 10807 -303 -1251 9086 18765 -9524 14018 -5618 8351 880 -2797 10064 2056 17645 -17879 6886 -12006 2488 -7681 5693 -10810 7117 883 -7723 7997 -14666 25503 3369 8665 -4179 13762 -7299 -3585 6589 12837 -12935 9863 -13832 8984 -17270 7743 -5987 8167 1615 -4381 11581 -13904 11847 -13047 11222 -2056 17819 -1637 10896 8649 -5339 4807 -10996 20229 -5554 20958 -18824 10240 -4941 21959 -10417 -1192 15244 -16988 20478 -23025 13605 -8934 1070 5688 -5194 10564 -7202 17114 -15186 15419 -24635 24706 -23910 7048 8586 13857 17681 -12818 15356 -11173 14753 -10999 7553 -17906 16262 -4846 8667 445 2110 5039 -26643 9650 -14852 18201 -1177 7026 4417 3591 9025 -8397 10176 -3316 21355 -17640 15829 -9000 6264 3804 2942 12677 -17971 14983 -11125 21098 -17494 7481 -19091 12835 8327 1977 11043 -20158 10980 -1430 11905 -16686 10869 -4519 6220 17148 -9276 -1521 -18841 8922 -11222 16089 -15928 6985 228 11680 9625 -301 -1242 8015 14802 -9855 11414 -5576 7225 821 -2705 8536 1884 13769 -19715 5841 -12119 2153 -7362 4829 -11003 6157 824 -7926 7055 -16296 19036 3143 7644 -4148 11206 -7181 -3345 5533 SO 20191020T115039.0Z 7232.493507 222 1 32.01 2 89.00 105.51 28.08 226.68 0.00 1 0.00 1 0 15 5.872e-02 5.714e-02 1.001e-01 9.790e-02 2.908755e+03 6.560901e+03 2.776728e+02 -6.000000e+00 3.312186e+03 279.77 -2.00 20.00 -2.00 505.31 0.00e+00 7.571982e-04 2.711690e-03 1.392437e-05 -6.000000e+00 1.654603e-03 279.77 -2.00 20.00 -2.00 499.85 0.00e+00 2.317959e+00 2.048863e+00 7.549128e-03 -6.000000e+00 1.182104e+00 224.86 -2.00 3.58 -2.00 501.55 0.00e+00 18.725 0.129 489.00 513.00 1 1.0124e+01 1.5700e-01 3.1578e-02 -6.0000e+00 9.0618e-02 1.1998e-01 3.9616e-02 1.7532e-03 -6.0000e+00 2.3465e-02 4.8724e-06 2.4120e-03 1.0349e-02 2.9941e-05 -6.0000e+00 6.5017e-03 -1.4220e-02 2.5627e-04 12 8 8 10 0 0 -955.78 19.89 2.41 -0.01422 0.00251 8 2 1 4 0 4000.000 24.75 14.99 19.89 -4275 601 -4173 1533 -3820 -6918 8922 -3009 -1686 -408 -1037 4810 -3937 -11151 -3148 -177 3821 -477 -4474 -3219 -5664 426 1314 3909 -396 -1961 -4077 4472 1288 1057 10791 4868 931 7117 -1683 -3106 4002 -1721 191 12802 164 -4659 -1485 3385 -1320 11582 3515 -4016 4225 20 11165 -5070 2398 -3746 11686 5255 -1032 -2432 10935 -123 8987 1678 -9642 -11374 4672 -6341 -3292 4382 -1294 -2526 4607 -629 -4087 -3148 -4352 -3372 4632 12536 7503 -383 10105 -4882 2839 -5039 3609 5144 3572 11927 1752 2015 -762 11000 5492 -6124 240 4517 3128 627 159 -3297 5961 -302 5303 -4937 8600 159 -12652 2661 -643 13670 837 3993 -767 7072 -4835 -16888 1761 -1522 -2204 -7435 860 10471 13839 -8118 -2035 1611 -5072 1545 -2074 -1524 299 763 4849 7809 -2230 10076 5271 -12793 -4276 -4732 13338 -4934 2030 4038 -1854 -3480 2327 -4660 -4602 -2521 900000 -4362 592 -4439 1591 -4298 -8205 9180 -3516 -1941 -459 -1157 4992 -4394 -13225 -3432 -188 3966 -529 -5267 -3789 -6865 487 1490 4329 -459 -2308 -4870 4836 1404 1124 10257 4925 998 7386 -1952 -3684 4397 -1981 213 12503 182 -5444 -1696 3719 -1530 11816 3862 -4693 4458 21 10418 -5438 2363 -3953 10802 5315 -1134 -2508 10775 -124 9012 1663 -10714 -12820 4444 -6640 -3289 3993 -1231 -2403 4051 -583 -3953 -3045 -4279 -3261 4073 10021 6237 -343 8158 -4605 2497 -4833 3202 4523 3198 9820 1597 1836 -718 9320 4961 -6217 227 4008 2750 551 137 -2899 4765 -260 4451 -4736 7356 148 -13350 2382 -591 10927 769 3606 -736 6332 -4909 -19440 1689 -1509 -2184 -7667 805 8788 11173 -8176 -1935 1481 -4987 1420 -1973 -1438 275 689 4147 6430 -2033 8215 4592 -13601 -4238 -4766 11301 -5048 1947 3809 -1853 -3505 2176 -4582 -4451 -2378 900000 SO 20191020T115459.0Z 7232.496516 226 1 32.01 2 88.26 106.27 28.64 228.36 0.00 1 0.00 1 0 15 1.083e-01 1.024e-01 7.512e-02 7.269e-02 1.336974e+03 4.538773e+03 1.261451e+02 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