File name: Pandora169s1_Egbert_20210201_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241102T225724.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210201_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210201T135902.4Z 7702.582667 299 1 38.85 2 78.15 128.28 80.05 264.82 0.00 1 0.00 1 0 17 4.022e-01 1.069e-02 1.309e-01 3.211e-03 7.414890e-01 1.760316e-03 8.526875e-03 -6.000000e+00 2.420067e-01 224.02 -2.00 3.58 -2.00 320.89 0.00e+00 4.400835e-03 7.280400e-04 1.945394e-03 -6.000000e+00 1.057369e-02 271.01 -2.00 20.00 -2.00 320.45 0.00e+00 4.723 0.002 302.00 328.00 3 2.9104e+00 5.3638e-03 6.0239e-02 -6.0000e+00 5.9859e-01 1.8653e-01 7.1802e-03 3.9965e-02 -6.0000e+00 6.5315e-01 -1.4449e-01 7.6540e-03 2.3375e-02 -6.0000e+00 3.8434e-01 4.7536e-02 3.7745e-03 9.4178e-03 -6.0000e+00 1.5985e-01 1.2561e-04 -9.5526e-04 9.2991e-05 1.3011e-04 -6.0000e+00 1.2926e-02 1.2772e-03 -4.8439e-05 12 9 9 12 1 1 99.97 22.64 0.36 0.00128 -0.00590 48 13 1 5 0 789.150 26.32 19.99 22.64 -11.57 22.5 960.03 -192069 900000 -94062 900000 -197076 -28645 900000 900000 -195299 -169494 -100537 -78092 -75751 -71824 6621 -10677 -20501 -80986 46429 -69813 -49332 -37924 -28372 -32994 30359 -66671 -4396 -40490 45075 -11532 42104 -16516 12036 -23969 8747 7752 28465 -4780 9128 -3766 10030 -7312 12586 -726 980 -10946 412 -336 14214 1521 10076 4908 9284 2150 9206 -2598 7751 -2476 239 992 4564 -87 3992 3243 4255 2756 3819 815 2882 2260 3667 2253 954 1470 -2101 -140 -306 -1288 -2724 571 -571 -36 -2540 -1795 -1210 -1610 -723 1382 -537 -280 -789 -492 -242 -533 -1206 1132 8 987 -673 -472 -929 -364 -659 1220 -1095 -1738 -682 -855 108 181 -120 152 -199 -126 129 91 765 804 754 44 199 759 1065 684 202 -365 222 394 890 11 -102 -792 -89 -363 -149 -479 24 259 436 -58 50 -440 -191 -2283 900000 -580 900000 -3065 -93 900000 900000 -3853 -2909 -1010 -740 -905 -1057 59 -139 -332 -2486 489 -2220 -1355 -946 -692 -886 494 -2706 -106 -1325 722 -332 903 -692 453 -1323 368 333 1088 -285 576 -313 824 -758 1132 -77 105 -1328 46 -40 1598 207 1403 790 1583 419 1784 -592 1631 -575 53 215 989 -22 1064 977 1324 880 1216 280 1072 936 1640 1042 441 651 -879 -53 -110 -483 -1141 274 -318 -23 -1741 -1282 -914 -1291 -589 1128 -444 -226 -603 -361 -173 -400 -1001 1044 9 1116 -823 -580 -1100 -395 -673 1230 -1161 -1924 -791 -1052 143 259 -184 242 -324 -203 198 137 1149 1252 1207 71 324 1200 1610 1016 295 -518 308 574 1394 20 -188 -1535 -179 -766 -328 -1091 54 596 1005 -128 107 -905 -387 SS 20210201T140408.1Z 7702.586204 302 1 2.11 2 77.44 129.29 80.95 265.67 0.00 1 0.00 1 0 17 4.875e-01 1.923e-02 3.174e-01 1.476e-02 7.091516e-01 8.125240e-03 8.758661e-03 -6.000000e+00 2.917387e-01 224.02 -2.00 3.58 -2.00 320.55 0.00e+00 2.800461e-03 3.064635e-03 4.487742e-03 -6.000000e+00 1.384402e-02 271.01 -2.00 20.00 -2.00 320.10 0.00e+00 4.474 0.002 302.00 328.00 3 2.7915e+00 2.3983e-02 5.9364e-02 -6.0000e+00 7.2344e-01 1.7879e-01 3.0695e-02 4.3093e-02 -6.0000e+00 7.8993e-01 -1.4989e-01 3.1074e-02 2.4643e-02 -6.0000e+00 4.6625e-01 4.5630e-02 1.5637e-02 8.5629e-03 -6.0000e+00 1.9511e-01 1.8604e-04 -5.3812e-04 4.3395e-04 1.5101e-04 -6.0000e+00 1.5585e-02 -1.5437e-04 -1.5368e-04 12 9 9 12 1 1 999.00 22.64 0.30 -0.00015 -0.00420 1 11 1 5 0 965.470 26.41 19.99 22.64 -11.38 22.5 961.46 -197591 900000 -211169 900000 6910 -74384 -161945 900000 -100160 900000 -147139 900000 -91344 900000 -49558 900000 -31760 31695 -6218 276079 -10924 191109 -56917 900000 -31834 -17828 -77574 -10855 -7744 93274 -45415 79187 -22174 6864 10648 -18339 -6071 8995 5082 14426 -5460 12374 8154 5942 14 -7672 -7146 2119 12103 -12960 16890 5655 1573 -700 6905 -10162 7062 5138 4642 -1775 18737 1515 5718 6767 7517 -773 2708 5534 11055 3814 1292 -1610 5860 -2697 -68 -756 -2959 -7011 -1413 -3501 3132 -35 -393 -1187 -1072 -3188 1595 -4377 3518 -1215 -10 -3552 -54 -2816 -1583 1863 2484 -490 -672 -264 -2256 -792 -683 1627 -829 -2030 101 -422 -403 -222 -580 -99 -21 465 -1658 838 717 2967 594 2381 -1573 701 2095 1548 984 579 25 10 34 327 -2046 -325 -357 407 140 214 -1640 559 -410 119 1338 -844 -365 -3691 900000 -5544 900000 99 -1069 -2786 900000 -1440 900000 -3260 900000 -1759 900000 -1029 900000 -759 475 -141 3968 -280 2747 -2344 900000 -1214 -631 -4754 -365 -258 1371 -2698 1825 -1435 365 546 -1238 -400 603 421 1282 -650 1352 971 742 2 -1129 -1077 306 1689 -2442 2683 1100 347 -170 1660 -2950 1804 1330 1185 -475 4319 443 1795 2315 2688 -298 1019 2112 4387 1785 665 -877 2970 -1400 -32 -330 -1259 -3159 -668 -1930 1858 -24 -287 -919 -871 -2748 1375 -4010 3020 -1050 -8 -2856 -41 -2287 -1387 1775 2619 -577 -834 -328 -2728 -886 -722 1683 -905 -2326 119 -524 -536 -319 -887 -157 -34 727 -2547 1238 1062 4444 933 3760 -2532 1085 3128 2265 1409 811 35 14 53 546 -3688 -606 -689 811 291 457 -3589 1215 -890 252 2707 -1667 -707 SS 20210201T143857.0Z 7702.610382 318 1 4.00 2 72.86 136.49 87.09 271.47 0.00 1 0.00 1 0 17 1.772e-01 1.292e-02 2.259e-01 1.003e-02 5.415660e-01 5.253137e-03 6.396835e-03 -6.000000e+00 1.050027e-01 224.02 -2.00 3.58 -2.00 319.45 0.00e+00 5.531778e-03 1.432755e-03 4.380465e-04 -6.000000e+00 4.660755e-03 271.01 -2.00 20.00 -2.00 318.97 0.00e+00 3.345 0.001 302.00 328.00 3 3.9673e+00 1.4520e-02 4.2825e-02 -6.0000e+00 2.5930e-01 1.1553e-01 1.6974e-02 2.8303e-02 -6.0000e+00 2.8252e-01 -5.4481e-02 1.4147e-02 1.5143e-02 -6.0000e+00 1.6774e-01 1.1750e-02 7.4809e-03 7.2294e-03 -6.0000e+00 6.9880e-02 1.9255e-04 -8.0294e-04 3.0309e-04 7.7133e-05 -6.0000e+00 5.5117e-03 -1.6882e-04 -1.3794e-04 12 9 9 12 1 1 999.00 22.61 0.59 -0.00017 -0.00620 1 6 1 5 0 1910.480 26.32 20.00 22.61 -9.71 22.9 976.12 47897 8298 7944 76691 -51373 -17499 36558 50908 -106843 -35329 -72160 900000 -9375 59281 -4549 -2261 -25489 -14280 10687 10274 -27969 21954 -36825 20470 -2431 -5437 -5495 3239 3040 6661 -6218 14691 -18148 -7780 -14724 -1257 -11092 -5158 1367 7519 978 11 -24 625 2153 -1505 -1391 1328 10895 3027 4675 -1119 3815 3199 5073 -612 -1996 -216 3822 -21 4677 -3906 3249 -464 2789 152 2366 679 4689 1278 1434 -1161 463 -2215 3165 -4321 2162 -1723 -504 -479 221 -1714 -2454 -1906 -128 -2144 239 167 1345 71 1205 -1333 454 489 199 -837 152 865 -87 -1199 -1020 -183 -1022 -610 -1185 -555 -1771 -245 631 852 -767 369 -603 440 -81 1043 -102 827 -725 57 562 1541 571 761 226 -146 494 1644 -207 752 -5 -834 -194 742 -238 -158 -130 16 353 81 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