File name: Pandora169s1_Egbert_20210527_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T021423.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210527_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210527 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210527T101725.9Z 7817.428772 179 1 49.79 2 85.15 64.68 88.87 232.97 0.00 1 0.00 1 0 25 8.660e-01 5.881e-02 3.237e-01 2.406e-02 1.089973e+00 1.505494e-02 1.177547e-02 -6.000000e+00 5.402817e-01 231.61 -2.00 3.58 -2.00 322.16 0.00e+00 8.408974e-03 6.243008e-03 5.143563e-03 -6.000000e+00 2.570174e-02 281.45 -2.00 20.00 -2.00 321.57 0.00e+00 10.042 0.020 302.00 328.00 3 1.2366e-01 5.0136e-02 1.2165e-01 -6.0000e+00 1.3551e+00 2.5475e+00 5.9865e-02 8.3804e-02 -6.0000e+00 1.4720e+00 -2.6903e+00 3.6946e-02 3.1777e-02 -6.0000e+00 8.6817e-01 9.4942e-01 2.0105e-02 1.3459e-02 -6.0000e+00 3.6364e-01 6.4461e-06 -2.7277e-04 6.6205e-04 1.9476e-04 -6.0000e+00 2.9745e-02 2.5147e-03 -1.0327e-04 12 8 8 10 0 0 -95.09 22.62 1.09 0.00251 0.00047 25 5 1 5 0 1990.390 26.32 20.00 22.62 13.06 28.7 966.93 236617 437536 900000 900000 900000 271121 162679 -57924 23284 37580 36432 91893 -27885 111159 900000 -31672 63880 138508 32124 72508 295204 87572 411701 84077 -29491 86597 40113 900000 900000 900000 149640 900000 900000 -36537 7631 900000 7239 900000 46943 900000 -1677 137153 51786 -24469 -582 27176 91050 900000 900000 42737 -398 -30367 6177 900000 900000 34630 89234 98907 183699 47734 46961 8686 58383 39082 137180 98982 116460 -37740 96526 7800 98460 8979 -2032 60545 43445 -26019 80042 21326 12980 28440 12734 39484 13098 -16928 26788 -14104 8464 1226 3317 -2855 29914 32570 75195 475 -9690 36658 4408 -12281 -5317 -11 6647 375 -17458 -4543 7467 -8114 233 -8490 3552 -2154 -1337 -4438 -9607 615 -1081 1924 2993 -1324 2267 934 -2179 3561 255 6715 5397 -3904 2234 8987 7542 824 -7192 1973 560 479 1040 -311 -595 1588 1611 495 657 -1831 -4434 6916 10231 900000 900000 900000 6340 4121 -11253 1996 2563 2414 3760 -4163 5415 900000 -7577 6597 6748 4319 5934 6903 4778 9627 4096 -4195 3544 2345 900000 900000 900000 3499 900000 900000 -6123 743 900000 649 900000 3692 900000 -222 4956 4293 -3815 -68 2542 4452 900000 900000 3816 -54 -6036 903 900000 900000 4343 6260 5887 4296 4059 3993 1163 5337 4819 6707 7154 7179 -10516 8413 1672 9837 2012 -479 7465 5541 -5863 5955 3037 2345 5320 3027 8981 3905 -7224 7726 -6349 3117 487 1260 -1096 8458 8585 13108 176 -4664 13358 2646 -10099 -4465 -9 4689 251 -12621 -2806 4249 -5708 161 -7097 3018 -2092 -1482 -5580 -13306 773 -1361 2329 3661 -1770 3050 1286 -2995 4368 308 7982 6331 -4551 2686 11086 10243 1410 -15239 4231 1329 1234 2658 -844 -1656 4335 4314 1364 1668 -4400 -10568 SS 20210527T102903.0Z 7817.436840 182 1 49.95 2 83.26 66.61 90.50 234.93 0.00 1 0.00 1 0 17 6.386e-01 2.179e-02 2.778e-01 5.274e-03 9.708003e-01 3.172570e-03 1.061732e-02 -6.000000e+00 3.900437e-01 231.61 -2.00 3.58 -2.00 322.16 0.00e+00 1.200240e-02 1.941588e-03 3.948206e-03 -6.000000e+00 1.777340e-02 281.45 -2.00 20.00 -2.00 321.70 0.00e+00 7.765 0.009 302.00 328.00 3 5.5244e-01 1.2680e-02 1.0087e-01 -6.0000e+00 9.7688e-01 8.4086e-01 1.8191e-02 8.0006e-02 -6.0000e+00 1.0571e+00 -1.1202e+00 1.7609e-02 3.1051e-02 -6.0000e+00 6.2769e-01 4.5348e-01 7.8891e-03 1.6230e-02 -6.0000e+00 2.6084e-01 6.0951e-05 -1.9925e-03 1.4769e-04 2.1088e-04 -6.0000e+00 2.0328e-02 1.2769e-04 -1.1875e-04 12 8 8 10 0 0 7.27 22.61 0.31 0.00013 -0.01485 102 22 1 5 0 484.810 26.32 20.00 22.61 13.35 28.6 968.54 -86084 -71260 900000 -137778 900000 -110876 -24738 -275052 -166233 -176863 -58778 -124809 -46203 -130237 900000 -158837 32780 -116879 23116 -61245 900000 -82842 188321 -89013 -74545 -109694 -8700 -91133 900000 -25145 256357 -10756 242478 -59621 26578 91632 13660 21311 99884 23970 31706 41145 36630 756 46098 23734 46778 87533 62079 56921 20524 32325 31101 74751 53711 32168 38061 47788 23455 37050 2514 30196 16515 37341 19645 36304 17622 2777 12166 17998 17278 18355 514 15028 3241 2160 -1952 3933 -1746 7812 -1734 4580 -357 -1893 1373 155 389 -208 -70 975 780 2896 4783 -1499 -2824 -76 -1311 -2140 -2153 -2476 -176 -2415 -1341 -1699 -1817 -4317 -1309 -4294 -104 -1907 -786 -1695 -1319 -1896 -411 -130 1262 113 974 502 1468 960 2390 2180 1857 138 1948 1222 2344 -259 -59 236 348 85 204 -68 -41 670 55 -240 -23 -838 -2000 -516 -466 900000 -1593 900000 -881 -127 -9459 -2136 -2575 -302 -1458 -324 -2621 900000 -6279 260 -4204 238 -1364 900000 -2164 968 -2478 -1820 -3805 -118 -2537 900000 -470 1317 -271 1246 -2783 559 985 338 558 1400 760 1032 1304 1271 39 1520 1006 1643 2372 2153 2291 1336 2104 2264 3809 3565 2518 2829 3418 1901 2777 253 2554 1848 3882 2656 4291 2584 468 2081 3290 3475 3780 124 2902 634 385 -348 699 -383 1892 -517 1491 -136 -789 589 71 186 -102 -34 455 345 1200 1947 -701 -1552 -46 -952 -1826 -2030 -2394 -158 -2002 -999 -1237 -1381 -3570 -1124 -4164 -110 -2225 -1034 -2464 -1988 -2873 -600 -186 1808 171 1532 810 2296 1437 3367 2975 2465 181 2516 1707 3732 -465 -120 498 792 210 536 -179 -110 1807 146 -647 -56 -1959 -4559 SS 20210527T103858.0Z 7817.443726 185 1 49.90 2 81.61 68.25 91.92 236.57 0.00 1 0.00 1 0 17 7.384e-01 1.246e-02 1.052e-01 2.198e-03 8.482285e-01 1.260016e-03 9.681690e-03 -6.000000e+00 4.500158e-01 231.61 -2.00 3.58 -2.00 321.67 0.00e+00 8.729166e-03 6.957767e-04 3.042379e-03 -6.000000e+00 1.957259e-02 281.45 -2.00 20.00 -2.00 321.17 0.00e+00 6.447 0.005 302.00 328.00 3 5.3070e-01 4.5886e-03 7.9079e-02 -6.0000e+00 1.1276e+00 2.6395e-01 6.6711e-03 4.9222e-02 -6.0000e+00 1.2195e+00 -3.2856e-01 6.9162e-03 2.9314e-02 -6.0000e+00 7.2408e-01 1.2638e-01 3.1584e-03 1.3129e-02 -6.0000e+00 2.9947e-01 2.5441e-04 -1.2355e-03 6.2094e-05 2.1082e-04 -6.0000e+00 2.3008e-02 -2.5279e-04 -1.0586e-04 12 8 8 10 0 0 -14.94 22.62 0.23 -0.00025 -0.00954 228 49 1 5 0 216.930 26.32 20.01 22.62 13.57 28.7 969.71 -294684 -180591 -194839 -255791 -230002 -191131 -204480 -285722 -238494 -204400 -159078 -223602 -178920 -145952 -10965 -135593 -57138 -120470 -54655 -60332 -5843 -91944 11451 -71570 -43770 -72858 -25828 -79650 -3412 -47467 1606 -24041 9981 -36273 -9664 -8368 -2138 -18309 5470 2776 5039 647 10882 -5187 11712 1070 7588 18847 12404 10930 9395 9343 10167 16672 15543 9368 8878 6551 4991 6871 4292 9965 7754 11339 8094 9081 7310 4003 4686 7599 3544 4408 -709 4645 471 1388 -700 150 -1588 1495 -899 812 -2122 -2659 -962 -954 -254 -125 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