File name: Pandora169s1_Egbert_20210528_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T024454.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210528_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210528 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210528T191638.5Z 7818.803224 526 1 49.03 2 33.55 237.38 161.18 344.50 0.00 1 0.00 1 0 17 1.009e-02 7.610e-03 1.529e-03 1.040e-03 1.774169e-01 5.636381e-04 2.177901e-03 -6.000000e+00 6.157564e-03 231.70 -2.00 3.58 -2.00 314.96 0.00e+00 3.769681e-04 4.763447e-05 1.934752e-05 -6.000000e+00 2.674875e-04 281.60 -2.00 20.00 -2.00 314.38 0.00e+00 1.199 0.000 302.00 328.00 3 5.3612e+00 1.4555e-03 1.5066e-02 -6.0000e+00 1.5432e-02 1.9350e-02 1.6103e-03 9.3844e-03 -6.0000e+00 1.6681e-02 -3.0372e-03 9.1837e-04 4.5590e-03 -6.0000e+00 9.9055e-03 -3.1413e-03 3.9337e-04 1.2705e-03 -6.0000e+00 4.1022e-03 6.4477e-04 8.0892e-05 3.2930e-05 1.9127e-05 -6.0000e+00 3.1420e-04 -5.2845e-03 5.4581e-05 11 8 0 10 0 0 99.88 22.65 0.14 -0.00528 -0.00468 26 6 1 5 0 1885.540 26.41 20.00 22.65 13.50 28.8 970.12 988 308 -1085 -2218 -3181 -1073 -245 -549 511 -943 -3139 -1066 -924 -483 646 -1197 -613 1123 674 1218 837 236 1777 1888 1142 1080 63 -1080 1037 1126 2480 2424 2158 -1361 -3187 -832 -1680 -624 127 -857 -1141 -544 -699 -1308 -505 -359 -977 -456 -410 151 743 257 700 1226 981 884 1227 187 416 647 957 1577 1553 1078 -223 -637 51 -478 1237 1060 -21 -145 -136 409 159 -293 -297 -215 -13 -103 -1465 -1581 -2560 -1783 -639 -942 -335 86 77 65 140 383 -129 832 760 522 473 329 -410 -685 -552 -664 -120 556 -460 -1250 -507 -858 -125 394 239 93 149 324 194 674 878 310 490 -79 -408 -133 225 385 978 461 519 1500 1066 192 79 -258 -23 245 128 -406 -182 64 -260 -365 106 -831 -703 313 104 -372 -736 -989 -315 -73 -177 175 -337 -1142 -386 -353 -199 285 -564 -295 545 335 614 428 121 912 994 622 599 35 -583 528 560 1238 1256 1159 -755 -1745 -445 -945 -382 86 -638 -899 -440 -575 -1085 -416 -294 -792 -361 -319 117 584 209 585 1048 855 778 1087 167 368 571 859 1462 1496 1067 -221 -609 46 -427 1124 1020 -22 -151 -143 421 158 -276 -265 -185 -11 -94 -1438 -1634 -2764 -1977 -730 -1120 -410 106 95 79 164 426 -137 858 797 575 549 402 -515 -860 -673 -779 -138 643 -557 -1568 -650 -1130 -168 543 336 131 206 430 247 825 1066 386 631 -106 -557 -182 302 506 1247 572 628 1802 1313 244 103 -342 -31 334 180 -585 -267 94 -388 -541 154 -1195 -1003 SS 20210528T192646.9Z 7818.810265 532 1 49.81 2 35.10 240.52 161.55 351.14 0.00 1 0.00 1 0 17 1.122e-02 8.106e-03 2.694e-03 1.700e-03 1.853034e-01 9.180706e-04 2.264293e-03 -6.000000e+00 6.849785e-03 231.70 -2.00 3.58 -2.00 315.29 0.00e+00 5.487575e-04 8.273815e-05 2.307465e-05 -6.000000e+00 2.975773e-04 281.60 -2.00 20.00 -2.00 314.67 0.00e+00 1.221 0.000 302.00 328.00 3 6.2298e+00 2.3778e-03 1.5508e-02 -6.0000e+00 1.7167e-02 3.5256e-02 2.6351e-03 9.8034e-03 -6.0000e+00 1.8557e-02 -3.6253e-03 1.5022e-03 4.7552e-03 -6.0000e+00 1.1019e-02 -4.1631e-03 6.5053e-04 1.3472e-03 -6.0000e+00 4.5631e-03 2.5866e-04 1.8901e-05 5.3975e-05 1.9414e-05 -6.0000e+00 3.4954e-04 -5.2591e-03 3.7214e-05 11 9 0 11 32 0 99.25 22.66 0.28 -0.00526 -0.00512 13 3 1 5 0 3830.490 26.41 20.00 22.66 13.70 28.8 971.38 245 -207 -816 -1478 -3379 -1073 300 -2177 434 -2593 -3609 -864 -1089 -479 924 1582 -1327 983 -242 961 1397 777 851 1950 415 1365 -284 209 946 1679 2490 2680 2952 -2325 -3931 -317 -1758 68 202 -658 -1343 -783 -723 -1202 -416 -575 -960 -299 -204 -406 233 -272 -8 1404 1764 1060 927 49 814 317 939 1575 1618 1245 87 -702 118 -633 1430 936 572 493 128 784 76 -903 -693 -949 -354 -438 -1219 -1481 -2696 -2226 -576 -771 -24 256 292 243 314 26 24 102 271 864 421 494 -384 -714 -297 -779 -392 543 -537 -1201 -572 -944 -121 675 286 261 132 225 146 297 557 190 302 -245 -311 48 456 257 1445 593 761 1256 967 -58 -272 -342 72 390 188 -192 -71 128 -150 -230 206 -1090 -949 68 -62 -247 -429 -924 -276 78 -625 131 -832 -1171 -278 -373 -178 370 669 -592 441 -112 449 660 369 408 954 212 705 -147 104 447 771 1155 1294 1478 -1223 -2036 -158 -933 40 131 -472 -1028 -617 -579 -971 -334 -459 -758 -230 -154 -306 179 -217 -7 1176 1502 917 810 43 706 276 829 1440 1542 1222 86 -665 106 -559 1282 895 578 513 133 802 75 -845 -609 -806 -303 -398 -1188 -1527 -2917 -2481 -661 -921 -30 320 365 299 370 29 25 105 285 952 492 608 -488 -906 -365 -921 -452 632 -653 -1521 -741 -1258 -165 941 407 374 185 302 187 368 684 239 395 -333 -430 66 619 342 1854 742 927 1520 1202 -75 -361 -460 98 540 268 -282 -106 193 -229 -346 305 -1596 -1378 SS 20210528T195512.7Z 7818.830008 545 1 49.33 2 39.69 248.36 161.49 10.26 0.00 1 0.00 1 0 17 1.032e-02 7.526e-03 2.220e-03 1.334e-03 1.931097e-01 7.187979e-04 2.364677e-03 -6.000000e+00 6.298178e-03 231.70 -2.00 3.58 -2.00 315.49 0.00e+00 2.912209e-04 6.749026e-05 3.790947e-05 -6.000000e+00 2.736135e-04 281.60 -2.00 20.00 -2.00 314.86 0.00e+00 1.298 0.000 302.00 328.00 3 5.6490e+00 1.8652e-03 1.6351e-02 -6.0000e+00 1.5785e-02 2.7400e-02 2.0686e-03 1.0212e-02 -6.0000e+00 1.7062e-02 -4.3728e-03 1.1803e-03 4.9640e-03 -6.0000e+00 1.0132e-02 -3.7869e-03 5.1522e-04 1.3661e-03 -6.0000e+00 4.1956e-03 4.2515e-04 -1.9455e-05 4.2395e-05 2.0034e-05 -6.0000e+00 3.2139e-04 -5.2299e-03 3.9409e-05 11 8 0 10 0 0 99.99 22.66 0.01 -0.00523 -0.00538 30 6 1 5 0 1643.960 26.41 20.00 22.66 14.16 28.8 973.86 717 1133 -392 -944 -2298 -827 656 -1313 -266 -1912 -2957 -1224 -1061 -171 1359 -2554 -485 728 72 986 730 -127 2064 1490 1310 1055 -18 -718 1114 786 2624 1933 2840 -2163 -3026 -2286 -1362 -622 137 -649 -1235 -676 -572 -1247 -289 -485 -1067 -536 -130 -303 1015 30 854 1430 978 821 1250 224 163 648 828 1405 1689 1176 -103 -577 -16 -373 1354 1198 303 424 -250 756 -116 -327 -216 -371 -98 -182 -1550 -1536 -2277 -2112 -744 -867 -143 131 51 52 243 500 88 600 701 690 257 572 -323 -795 -435 -766 -343 375 -430 -1430 -728 -672 -41 400 298 183 82 198 141 642 788 243 350 29 -326 -74 325 78 885 293 590 1515 1067 180 9 -386 86 228 16 -377 -182 193 -112 -268 51 -729 -711 184 308 -109 -253 -576 -196 158 -348 -76 -571 -894 -371 -342 -60 511 -1054 -204 310 31 438 330 -58 934 698 635 523 -9 -345 504 348 1166 902 1370 -1095 -1502 -1118 -696 -350 86 -453 -920 -519 -446 -983 -226 -378 -822 -404 -96 -223 759 23 686 1177 823 699 1073 193 140 554 721 1267 1587 1139 -100 -540 -15 -325 1203 1134 304 438 -260 768 -114 -302 -188 -311 -83 -164 -1507 -1579 -2451 -2348 -854 -1035 -177 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