File name: Pandora169s1_Egbert_20210713_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T040515.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210713_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210713 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210713T155003.4Z 7864.659762 270 1 0.61 2 29.83 131.26 65.15 94.17 0.00 1 0.00 1 0 17 1.055e-02 8.659e-03 6.434e-03 4.779e-03 1.653564e-01 2.618587e-03 2.072502e-03 -6.000000e+00 6.468257e-03 233.04 -2.00 3.58 -2.00 314.52 0.00e+00 3.620116e-04 2.055753e-04 1.469260e-05 -6.000000e+00 2.849686e-04 286.03 -2.00 20.00 -2.00 313.91 0.00e+00 1.152 0.000 302.00 328.00 3 1.9298e+00 6.7520e-03 1.4418e-02 -6.0000e+00 1.6240e-02 2.7709e-02 7.4443e-03 8.9086e-03 -6.0000e+00 1.7526e-02 -7.6588e-03 4.2526e-03 4.3181e-03 -6.0000e+00 1.0423e-02 -4.2926e-03 1.7999e-03 1.1911e-03 -6.0000e+00 4.3221e-03 2.1350e-02 -7.2394e-04 1.5112e-04 1.9093e-05 -6.0000e+00 3.2877e-04 -4.6204e-03 -4.7584e-05 12 9 1 12 1 1 999.00 22.57 0.32 -0.00462 -0.01006 1 49 2 5 0 213.670 26.32 20.01 22.57 30.75 31.2 1035.96 2637 555 -223 -2094 -1795 -3123 148 1712 284 -801 -2310 -1152 2171 595 35 529 -147 -1431 197 1274 -369 -230 824 1446 1872 1172 -1244 -670 778 1103 956 2060 1288 -701 -3009 -618 -2114 334 -348 -1208 -1100 -570 -1116 -1815 -545 741 -1171 -1221 -380 585 725 1461 164 753 823 437 632 75 1066 869 1071 750 1517 1220 -491 -885 1107 -180 2427 1004 -394 222 710 380 0 -481 -311 -15 336 -312 -1105 -1311 -1578 -2573 -1153 -934 118 -555 193 -338 602 342 -369 697 838 408 454 1244 -797 -301 -296 -1038 225 291 -420 -1283 -694 -1291 -295 595 371 271 284 212 32 1054 935 -253 225 91 -1136 -203 90 444 308 1811 85 1731 1488 201 120 -565 -458 562 -419 -394 -98 515 -684 -81 -449 -210 -444 983 220 -89 -819 -656 -1110 53 639 114 -332 -969 -483 932 277 17 275 -79 -784 109 708 -210 -131 468 837 1107 707 -756 -393 435 601 526 1162 752 -417 -1774 -356 -1279 217 -250 -942 -903 -479 -954 -1565 -466 626 -985 -1008 -307 467 588 1216 141 662 734 394 574 69 959 783 980 710 1482 1221 -493 -858 1015 -163 2216 974 -404 233 745 393 0 -459 -281 -13 295 -288 -1085 -1352 -1689 -2852 -1314 -1101 143 -684 237 -410 701 380 -392 718 875 446 521 1489 -989 -371 -355 -1208 255 334 -501 -1589 -878 -1676 -389 802 510 374 383 276 40 1266 1116 -310 285 119 -1527 -272 119 573 387 2200 101 2047 1800 252 154 -735 -602 748 -575 -555 -140 743 -998 -117 -642 -294 -619 SS 20210713T155903.5Z 7864.666013 276 1 26.82 2 28.65 134.80 63.61 95.78 0.00 1 0.00 1 0 17 9.423e-03 7.445e-03 7.171e-04 5.158e-04 1.606573e-01 2.820731e-04 1.978497e-03 -6.000000e+00 5.782825e-03 233.04 -2.00 3.58 -2.00 314.67 0.00e+00 3.399115e-04 2.279747e-05 2.280153e-05 -6.000000e+00 2.545344e-04 286.03 -2.00 20.00 -2.00 314.05 0.00e+00 1.139 0.000 302.00 328.00 3 3.4236e+00 7.2882e-04 1.4106e-02 -6.0000e+00 1.4520e-02 2.5761e-02 8.0425e-04 8.5741e-03 -6.0000e+00 1.5665e-02 -4.4478e-03 4.5907e-04 4.1456e-03 -6.0000e+00 9.3171e-03 -3.0415e-03 1.9483e-04 1.1399e-03 -6.0000e+00 3.8664e-03 4.8993e-03 2.2498e-04 1.6319e-05 1.7853e-05 -6.0000e+00 2.9366e-04 -5.1112e-03 1.3710e-04 12 9 1 12 1 1 99.99 22.59 0.23 -0.00511 -0.00342 173 69 1 5 0 153.120 26.32 20.00 22.59 31.09 31.3 1039.28 878 -284 -1022 -2712 -2922 -815 235 1676 705 -1042 -2350 -860 20 79 471 -34 -498 569 672 963 827 492 1395 1407 1382 1075 -57 -808 370 1003 1763 1781 2030 -848 -3127 -1346 -1479 -983 -150 -769 -1271 -957 -749 -859 -504 -448 -1032 -739 -560 40 938 862 818 1063 564 824 1004 233 252 487 923 1432 1377 1137 -17 -805 -126 -1 1422 1179 151 150 67 367 191 -179 16 -301 166 -201 -1304 -1660 -2361 -1735 -808 -857 -316 84 -7 63 195 243 -89 828 922 464 562 559 -389 -714 -497 -777 -238 467 -584 -1486 -837 -758 -238 519 390 276 126 235 181 687 693 354 320 33 -415 -21 289 312 899 728 452 1355 963 313 117 -435 -79 200 126 -446 -223 100 -276 -316 -46 -634 -562 310 -109 -396 -1006 -984 -272 79 569 263 -412 -938 -341 8 34 225 -17 -250 288 348 509 444 265 750 781 798 637 -34 -456 205 529 935 988 1107 -481 -1742 -769 -849 -643 -108 -603 -1037 -814 -651 -717 -438 -385 -868 -597 -437 33 771 708 704 949 494 731 898 209 224 431 837 1366 1336 1150 -17 -763 -115 -1 1272 1162 156 156 70 387 189 -169 14 -255 143 -188 -1297 -1725 -2520 -1939 -913 -1035 -385 105 -9 76 229 272 -95 839 958 500 634 686 -486 -887 -608 -891 -273 546 -705 -1844 -1080 -979 -319 696 542 384 176 304 223 825 822 437 405 43 -560 -28 378 408 1156 890 529 1629 1156 399 148 -569 -105 263 174 -625 -323 147 -411 -463 -66 -882 -800 SS 20210713T181825.9Z 7864.762800 372 1 11.48 2 25.08 210.43 41.31 127.08 0.00 1 0.00 1 0 17 9.490e-03 7.606e-03 6.482e-04 4.881e-04 1.549603e-01 2.675229e-04 1.916372e-03 -6.000000e+00 5.823654e-03 233.04 -2.00 3.58 -2.00 314.43 0.00e+00 3.166896e-04 2.064870e-05 1.496463e-05 -6.000000e+00 2.563548e-04 286.04 -2.00 20.00 -2.00 313.83 0.00e+00 1.104 0.000 302.00 328.00 3 2.5632e+00 6.8961e-04 1.3652e-02 -6.0000e+00 1.4622e-02 1.3314e-02 7.6015e-04 8.2852e-03 -6.0000e+00 1.5776e-02 -3.0325e-03 4.3443e-04 4.0095e-03 -6.0000e+00 9.3830e-03 -3.2086e-03 1.8335e-04 1.1047e-03 -6.0000e+00 3.8936e-03 1.2177e-02 1.5746e-04 1.5436e-05 1.7452e-05 -6.0000e+00 2.9575e-04 -5.1591e-03 1.2298e-04 12 9 1 12 1 1 99.63 22.55 0.19 -0.00516 -0.00398 117 110 1 5 0 95.770 26.32 20.00 22.55 28.28 31.1 1021.41 800 -350 -1035 -2691 -3052 -865 -106 1514 728 -1043 -2378 -969 -47 283 655 19 -580 768 784 1104 867 391 1472 1378 1136 1200 55 -665 151 1274 1760 2033 1886 -715 -2971 -1380 -1373 -792 -91 -754 -1424 -1021 -736 -929 -528 -440 -1013 -681 -576 18 1039 903 870 982 484 798 989 84 270 489 964 1357 1456 1061 -156 -755 19 -76 1459 1135 56 -26 50 257 200 -187 54 -120 271 -309 -1235 -1575 -2328 -1825 -864 -959 -301 -52 -57 16 123 324 103 1010 1003 506 482 503 -438 -717 -471 -773 -247 578 -439 -1420 -837 -800 -338 527 203 176 92 276 319 771 751 512 335 -7 -449 -106 276 429 922 817 419 1449 929 291 125 -355 -129 186 64 -464 -280 143 -280 -347 -51 -641 -561 318 -141 -423 -1117 -1152 -321 -37 575 304 -434 -998 -428 -21 137 328 10 -325 433 429 615 491 222 834 807 693 749 35 -395 88 701 974 1174 1080 -424 -1731 -820 -824 -514 -66 -597 -1183 -885 -623 -793 -448 -385 -866 -559 -477 14 859 751 758 851 432 721 900 77 244 441 890 1267 1446 1057 -155 -732 17 -68 1325 1091 57 -28 53 267 203 -181 49 -102 234 -279 -1196 -1604 -2545 -2015 -971 -1112 -366 -65 -69 19 143 358 108 1042 1061 558 561 612 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