File name: Pandora169s1_Egbert_20210717_L2Fit_fwvt1c14d20201119p1-8.txt File generation date: 20241103T041945.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210717_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1648 1798 Nominal wavelengths inside fitting window [nm]: 492.0247 492.1456 492.2665 492.3873 492.5082 492.6290 492.7499 492.8707 492.9914 493.1122 493.2330 493.3537 493.4744 493.5952 493.7159 493.8365 493.9572 494.0778 494.1985 494.3191 494.4397 494.5602 494.6808 494.8013 494.9219 495.0424 495.1629 495.2834 495.4038 495.5243 495.6447 495.7651 495.8855 496.0059 496.1263 496.2466 496.3669 496.4873 496.6075 496.7278 496.8481 496.9683 497.0886 497.2088 497.3290 497.4492 497.5693 497.6895 497.8096 497.9297 498.0498 498.1699 498.2900 498.4101 498.5301 498.6501 498.7701 498.8901 499.0101 499.1300 499.2500 499.3699 499.4898 499.6097 499.7295 499.8494 499.9692 500.0890 500.2088 500.3286 500.4484 500.5682 500.6879 500.8076 500.9273 501.0470 501.1667 501.2863 501.4060 501.5256 501.6452 501.7648 501.8844 502.0039 502.1235 502.2430 502.3625 502.4820 502.6015 502.7209 502.8404 502.9598 503.0792 503.1986 503.3179 503.4373 503.5566 503.6760 503.7953 503.9146 504.0338 504.1531 504.2723 504.3916 504.5108 504.6300 504.7491 504.8683 504.9874 505.1066 505.2257 505.3448 505.4638 505.5829 505.7019 505.8210 505.9400 506.0590 506.1780 506.2969 506.4159 506.5348 506.6537 506.7726 506.8915 507.0103 507.1292 507.2480 507.3668 507.4856 507.6044 507.7231 507.8419 507.9606 508.0793 508.1980 508.3167 508.4353 508.5540 508.6726 508.7912 508.9098 509.0284 509.1469 509.2655 509.3840 509.5025 509.6210 509.7395 509.8580 509.9764 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210717T133436.7Z 7868.565702 178 1 50.92 2 52.53 96.51 133.76 47.85 0.00 1 0.00 1 0 15 2.896e-03 2.892e-03 7.639e-04 7.627e-04 3.069036e+03 4.820488e+01 2.087098e+02 -6.000000e+00 1.673665e+02 286.28 -2.00 20.00 -2.00 505.27 0.00e+00 4.550138e-04 2.131245e-05 3.005647e-05 -6.000000e+00 8.267729e-05 286.28 -2.00 20.00 -2.00 500.46 0.00e+00 -2.775339e-02 1.522663e-02 2.359900e-02 -6.000000e+00 5.805014e-02 232.99 -2.00 3.58 -2.00 502.05 0.00e+00 1.640 0.000 489.00 513.00 1 7.5049e+00 1.1705e-03 3.0994e-03 -6.0000e+00 4.4666e-03 2.7943e-03 2.9771e-04 5.5372e-04 -6.0000e+00 1.1400e-03 8.5193e-04 5.7386e-04 8.1571e-05 2.3279e-05 -6.0000e+00 3.1991e-04 -3.5002e-03 4.5596e-05 11 1 0 11 32 0 99.77 22.55 1.35 -0.00350 0.00048 14 3 1 4 0 3636.160 26.32 20.00 22.55 26.65 31.3 1010.97 -600 -521 -98 -95 197 454 613 562 667 241 355 102 -101 -301 -143 -419 -210 218 123 241 -86 -26 414 277 282 351 163 357 30 -290 -498 -318 -302 -15 261 14 -47 -63 -53 -285 28 -170 90 140 17 481 43 31 119 -167 -547 -484 -606 -650 -252 -139 -478 2 -58 389 179 -16 451 390 412 169 75 174 31 -230 -376 75 -55 -170 -108 -94 -341 -363 -284 -357 -441 -429 -383 -147 -52 -171 -220 -145 60 -165 -45 189 322 -94 83 107 303 -218 -122 -443 -558 -512 -137 -98 -87 -226 -329 -319 -216 -34 0 -43 114 209 422 486 312 471 395 434 256 482 214 254 304 54 347 116 132 194 160 1 -69 -152 -190 3 -252 -73 33 152 153 77 199 293 7 94 106 -31 -512 -238 -313 -584 -510 -98 -96 203 468 642 582 691 248 369 104 -103 -302 -145 -428 -212 223 126 251 -90 -28 434 291 298 370 172 370 30 -296 -498 -317 -305 -15 271 15 -50 -65 -55 -292 29 -175 93 146 17 505 44 33 122 -167 -547 -472 -597 -643 -247 -140 -483 2 -59 396 183 -17 462 400 420 171 74 175 31 -226 -367 73 -54 -169 -108 -94 -337 -354 -273 -342 -423 -414 -373 -144 -51 -167 -216 -143 59 -163 -45 189 326 -94 82 106 294 -212 -116 -416 -521 -484 -132 -96 -87 -224 -324 -318 -213 -33 0 -43 114 211 428 485 313 472 395 438 255 472 208 247 297 52 339 114 128 188 155 1 -66 -144 -180 3 -246 -71 33 151 150 76 198 291 7 93 104 -30 -494 -227 -300 SQ 20210717T133906.9Z 7868.568830 181 1 42.43 2 51.73 97.38 133.20 49.11 0.00 1 0.00 1 0 15 2.560e-03 2.558e-03 8.158e-04 8.146e-04 3.081908e+03 5.155679e+01 2.077572e+02 -6.000000e+00 1.479239e+02 286.28 -2.00 20.00 -2.00 505.28 0.00e+00 4.272544e-04 2.282666e-05 2.854485e-05 -6.000000e+00 7.307252e-05 286.28 -2.00 20.00 -2.00 500.46 0.00e+00 -1.825104e-02 1.627847e-02 2.405526e-02 -6.000000e+00 5.130476e-02 232.99 -2.00 3.58 -2.00 502.06 0.00e+00 1.611 0.000 489.00 513.00 1 7.3861e+00 1.2526e-03 3.0840e-03 -6.0000e+00 3.9476e-03 2.7585e-03 3.1751e-04 5.6072e-04 -6.0000e+00 1.0074e-03 9.6295e-04 6.2773e-04 8.6982e-05 2.2232e-05 -6.0000e+00 2.8274e-04 -3.8183e-03 5.0599e-05 12 1 1 12 1 1 99.60 22.56 1.43 -0.00382 0.00054 14 4 1 4 0 2816.920 26.32 20.00 22.56 26.84 31.3 1011.81 -694 -443 -175 151 136 345 602 597 538 357 157 116 -30 -410 -272 -421 -233 91 239 173 -183 11 152 73 354 365 282 162 80 -132 -344 -307 -180 208 210 -44 -47 -75 -36 -206 -64 -68 7 160 101 369 149 36 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-188 85 -269 46 -229 79 165 112 15 294 82 239 -197 -140 -342 -99 -130 SQ 20210717T134340.6Z 7868.571997 184 1 43.11 2 50.92 98.26 132.62 50.35 0.00 1 0.00 1 0 15 2.803e-03 2.800e-03 9.595e-04 9.580e-04 3.156287e+03 6.075552e+01 2.145431e+02 -6.000000e+00 1.619894e+02 286.28 -2.00 20.00 -2.00 505.27 0.00e+00 4.435146e-04 2.682600e-05 2.940843e-05 -6.000000e+00 8.002093e-05 286.28 -2.00 20.00 -2.00 500.45 0.00e+00 1.629629e-02 1.915146e-02 2.411225e-02 -6.000000e+00 5.618430e-02 232.99 -2.00 3.58 -2.00 502.04 0.00e+00 1.583 0.000 489.00 513.00 1 7.6963e+00 1.4730e-03 3.0664e-03 -6.0000e+00 4.3230e-03 4.7071e-03 3.7386e-04 5.6546e-04 -6.0000e+00 1.1033e-03 7.0677e-04 8.4203e-04 1.0238e-04 2.3512e-05 -6.0000e+00 3.0963e-04 -4.0151e-03 4.9909e-05 12 1 1 12 1 1 99.92 22.56 1.35 -0.00402 0.00183 11 3 1 4 0 3577.560 26.32 20.00 22.56 27.02 31.3 1013.23 -329 -448 78 -99 371 338 487 433 606 307 -17 337 -1 -297 -207 -213 -311 274 25 295 -52 117 188 179 232 369 266 385 -126 -226 -488 -197 -246 131 247 -216 -44 -149 -252 -113 -153 -145 -110 305 217 277 112 119 115 -125 -629 -332 -567 -685 -225 -305 -231 45 -206 201 58 11 607 209 447 207 80 192 129 1 -261 -56 -168 -257 -179 -108 -357 -417 -227 -498 -429 -416 -343 -262 -113 -144 -103 -28 -116 -293 123 247 268 -45 -10 24 245 -127 -133 -205 -523 -405 -318 -163 -178 -297 -368 -314 -242 16 205 -30 118 261 430 321 482 575 399 536 33 571 389 254 80 1 471 128 139 169 -31 -44 -45 -97 -393 -233 -92 -6 19 97 130 181 112 220 109 254 -77 -101 -339 -71 -213 -321 -441 78 -100 378 349 509 453 633 322 -17 349 -1 -301 -208 -215 -317 281 26 308 -55 122 197 187 243 387 278 402 -130 -229 -493 -198 -247 135 258 -227 -46 -155 -262 -117 -157 -149 -115 314 226 289 117 122 118 -127 -626 -326 -557 -667 -223 -306 -234 46 -210 204 59 11 616 213 452 210 80 192 127 1 -253 -55 -164 -254 -178 -107 -351 -403 -220 -481 -414 -404 -332 -256 -111 -141 -102 -28 -115 -290 122 245 268 -45 -10 23 239 -122 -128 -193 -491 -384 -305 -160 -176 -294 -367 -309 -237 16 202 -30 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