File name: Pandora169s1_Egbert_20210830_L2Fit_fout2c14d20201119p1-8.txt File generation date: 20241103T082233.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v14d20201119.txt Level 1 file used: Pandora169s1_Egbert_20210830_L1_smca1c14d20201119p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20210830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1978 305.3386 305.4795 305.6203 305.7612 305.9020 306.0428 306.1836 306.3244 306.4651 306.6059 306.7467 306.8874 307.0281 307.1689 307.3096 307.4503 307.5910 307.7316 307.8723 308.0130 308.1536 308.2942 308.4349 308.5755 308.7161 308.8566 308.9972 309.1378 309.2783 309.4189 309.5594 309.6999 309.8404 309.9809 310.1214 310.2619 310.4024 310.5428 310.6833 310.8237 310.9641 311.1045 311.2449 311.3853 311.5257 311.6660 311.8064 311.9467 312.0871 312.2274 312.3677 312.5080 312.6483 312.7885 312.9288 313.0691 313.2093 313.3495 313.4897 313.6299 313.7701 313.9103 314.0505 314.1907 314.3308 314.4710 314.6111 314.7512 314.8913 315.0314 315.1715 315.3115 315.4516 315.5917 315.7317 315.8717 316.0117 316.1517 316.2917 316.4317 316.5717 316.7116 316.8516 316.9915 317.1315 317.2714 317.4113 317.5512 317.6910 317.8309 317.9708 318.1106 318.2504 318.3903 318.5301 318.6699 318.8097 318.9494 319.0892 319.2290 319.3687 319.5084 319.6482 319.7879 319.9276 320.0673 320.2069 320.3466 320.4863 320.6259 320.7655 320.9051 321.0448 321.1843 321.3239 321.4635 321.6031 321.7426 321.8822 322.0217 322.1612 322.3007 322.4402 322.5797 322.7192 322.8586 322.9981 323.1375 323.2769 323.4163 323.5557 323.6951 323.8345 323.9739 324.1132 324.2526 324.3919 324.5312 324.6705 324.8098 324.9491 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210830T111325.3Z 7912.467654 214 1 47.98 2 84.98 82.57 22.50 180.17 0.00 1 0.00 1 0 25 6.951e-01 6.303e-02 3.120e-01 2.509e-02 9.099290e-01 1.477353e-02 1.028316e-02 -6.000000e+00 4.267109e-01 230.51 -2.00 3.58 -2.00 321.76 0.00e+00 -1.089730e-02 4.990265e-03 7.187804e-04 -6.000000e+00 2.024196e-02 285.58 -2.00 20.00 -2.00 321.11 0.00e+00 9.777 0.018 302.00 328.00 3 8.3649e-01 4.6279e-02 1.0669e-01 -6.0000e+00 1.0650e+00 1.9640e+00 5.4840e-02 4.8088e-02 -6.0000e+00 1.1530e+00 -2.0909e+00 3.2084e-02 2.2941e-02 -6.0000e+00 6.8339e-01 7.4549e-01 1.7033e-02 1.0522e-02 -6.0000e+00 2.8646e-01 6.0027e-06 4.6293e-04 7.3757e-04 1.6223e-04 -6.0000e+00 2.1929e-02 -6.9769e-03 1.3229e-05 12 9 8 11 32 0 36.00 22.53 1.26 -0.00698 -0.00350 16 3 1 5 0 2997.670 26.21 19.99 22.53 24.91 32.2 981.21 111173 900000 -16685 136863 45269 900000 89367 113939 -53258 76539 -26757 900000 -54164 170254 74235 141041 30835 66900 60807 130998 39675 900000 900000 900000 81454 61646 217275 -12052 900000 64822 16283 900000 250038 -59896 -35620 41460 57089 135389 84629 41937 228404 140641 73270 23712 58099 91786 205044 193531 161918 19820 27636 -15433 82706 86115 900000 55656 95407 107160 99630 -5605 92346 -18589 5513 -18484 90954 40609 124467 -41500 7113 30609 44756 10406 61012 72623 17768 -7891 8210 -33309 -19639 22002 -6670 36774 -4419 -18478 12115 -11211 -5600 28907 12313 -7233 -7554 34640 12999 11263 -17155 36316 -2752 240 -5005 -3536 1870 -2388 -8735 -9328 3762 -8683 5538 -9044 10538 -5732 -1075 1557 -1307 2572 -1205 3873 1611 -9389 509 -3454 5402 7074 365 5847 3892 -4004 1430 -2114 5448 -2067 -305 4098 573 931 -357 -1282 -176 2046 1421 -1844 -1823 -2241 422 7467 900000 -3291 5293 3593 900000 4002 4174 -9906 4206 -3770 900000 -11296 4505 5591 5741 3828 5719 5322 5333 3715 900000 900000 900000 4974 4517 5307 -1496 900000 3598 1458 900000 6107 -13410 -5800 3222 3930 4810 5825 4609 5579 6870 6833 3137 5547 5910 5008 4727 5033 2684 3743 -3204 7529 8031 900000 7538 8686 8328 7743 -1061 6972 -4086 1044 -4853 9088 6672 8844 -14867 1723 6542 9739 2986 11109 10804 4064 -1895 1714 -9898 -5716 5423 -2349 9581 -1916 -9854 5030 -6161 -3009 11120 5489 -3739 -3674 10505 4868 4585 -10580 15375 -2011 194 -4645 -3267 1545 -1867 -6685 -7082 2626 -7281 4295 -8836 9502 -6966 -1300 1992 -1780 3354 -1590 4759 2049 -13901 715 -5165 7267 9718 515 7569 4991 -5420 1831 -3004 8217 -3577 -583 8208 1284 2243 -935 -3564 -498 5698 3929 -5031 -4639 -5342 950 SS 20210830T112456.4Z 7912.475653 217 1 49.30 2 82.93 84.56 22.61 187.00 0.00 1 0.00 1 0 25 6.188e-01 2.565e-02 2.334e-01 5.710e-03 8.291564e-01 3.390357e-03 9.519464e-03 -6.000000e+00 3.820803e-01 230.51 -2.00 3.58 -2.00 321.86 0.00e+00 4.731399e-03 1.961884e-03 4.308712e-03 -6.000000e+00 1.857684e-02 285.58 -2.00 20.00 -2.00 321.34 0.00e+00 7.461 0.008 302.00 328.00 3 1.2675e+00 1.3130e-02 8.8154e-02 -6.0000e+00 9.5700e-01 6.2237e-01 1.8000e-02 5.3375e-02 -6.0000e+00 1.0370e+00 -8.9600e-01 1.5643e-02 2.7477e-02 -6.0000e+00 6.1172e-01 3.7429e-01 7.0609e-03 7.8869e-03 -6.0000e+00 2.5535e-01 4.8986e-05 -1.8192e-03 1.7071e-04 1.5581e-04 -6.0000e+00 1.9777e-02 -8.1751e-03 -1.5813e-05 12 8 8 10 0 0 45.08 22.53 0.23 -0.00818 -0.02185 66 14 1 5 0 746.750 26.21 19.99 22.53 25.20 32.2 982.97 -162486 900000 -173679 24438 -98706 900000 -91254 900000 -236252 900000 -203815 900000 -171352 109771 -71067 900000 -54961 -25681 -57521 248039 -19912 900000 20926 84487 -16000 19598 105729 -41397 900000 289363 42328 157364 44158 -29658 -12257 95888 60288 36919 72852 8178 70360 36071 59640 31767 42701 32373 48621 46450 84316 21951 54325 718 50358 30054 78094 18173 40406 38663 27425 19164 33570 10554 27612 6994 33080 15841 28520 239 12620 10978 14809 7291 10446 9190 7640 1168 5274 -638 -5775 4422 -371 4408 -80 -3033 -551 -3765 -4397 1759 -1421 -1535 -1980 1210 -561 -2129 -5186 1392 -1975 -1046 -3412 -2128 -3079 -2294 -3309 -401 -3306 -2964 -2461 -2187 -1494 -748 -1207 383 -857 147 -137 1278 573 -637 423 654 656 2175 1976 2603 2010 1363 1182 1331 2008 35 563 -614 804 184 488 -767 130 143 459 -319 -172 -1557 -1359 -3678 900000 -5242 136 -1309 900000 -1054 900000 -11384 900000 -8337 900000 -7077 610 -1854 900000 -1645 -626 -1896 1379 -494 900000 368 822 -411 360 882 -1346 900000 1609 824 1167 1076 -1496 -511 1555 1367 1216 1994 464 2588 1862 2534 1817 2204 1877 2452 2490 3534 1611 3430 81 3808 3019 5520 2128 4119 3969 3050 2259 3496 1412 3531 1239 4862 2818 4519 50 2555 2560 3657 2029 2788 2338 1799 265 1151 -143 -1539 1268 -132 1638 -34 -1459 -276 -2067 -2549 986 -822 -862 -1057 594 -275 -1119 -3181 940 -1538 -932 -3426 -2161 -3015 -2034 -2720 -314 -2789 -2651 -2336 -2247 -1615 -913 -1666 565 -1257 222 -202 1807 822 -963 666 1010 1005 3319 2902 3675 2763 1831 1572 1863 3151 62 1096 -1258 1740 429 1161 -1948 336 374 1189 -800 -424 -3630 -3053 SS 20210830T113553.3Z 7912.483255 220 1 49.51 2 80.98 86.45 22.93 193.39 0.00 1 0.00 1 0 17 5.156e-01 9.978e-03 1.048e-01 1.990e-03 7.087892e-01 1.118651e-03 8.286943e-03 -6.000000e+00 3.135077e-01 230.51 -2.00 3.58 -2.00 321.22 0.00e+00 5.033020e-03 5.614306e-04 2.801031e-03 -6.000000e+00 1.390288e-02 285.58 -2.00 20.00 -2.00 320.63 0.00e+00 6.041 0.004 302.00 328.00 3 1.0176e+00 3.8700e-03 7.0965e-02 -6.0000e+00 7.8235e-01 9.5726e-02 5.3051e-03 4.1229e-02 -6.0000e+00 8.4576e-01 -1.2402e-01 5.1651e-03 2.2768e-02 -6.0000e+00 5.0396e-01 4.2342e-02 2.4284e-03 7.9966e-03 -6.0000e+00 2.1010e-01 2.7545e-04 -9.4420e-04 5.9067e-05 1.3037e-04 -6.0000e+00 1.6059e-02 -8.0317e-03 -6.3527e-06 12 8 8 10 0 0 59.21 22.52 0.27 -0.00803 -0.01513 176 38 1 5 0 281.250 26.21 20.00 22.52 25.39 32.1 983.87 -191556 -72674 -208343 -175409 -177636 -41750 -170366 -160649 -231088 -94600 -186481 -83381 -157340 -59604 -86148 -19166 -56458 -60618 -54451 -6815 -30938 -4360 -21109 -19318 -14296 -21485 -31821 -42984 -11951 -488 -19072 8593 -7399 -19938 -13102 -98 -6386 -3657 245 1035 4374 3779 5093 1028 6723 1571 4126 7722 7972 2646 6599 3527 7037 4859 6650 2235 4569 3119 2477 -275 3148 2609 6372 3712 5863 2698 4399 -598 2798 2996 3287 634 1445 1373 168 -975 -264 -2232 -792 58 -938 -652 -1730 -2225 -707 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