File name: Pandora169s1_Egbert_20211115_L2Fit_fwvt1c16d20210920p1-8.txt File generation date: 20241103T111700.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c16p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v16d20210920.txt Level 1 file used: Pandora169s1_Egbert_20211115_L1_smca1c16d20210920p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20211115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1649 1798 Nominal wavelengths inside fitting window [nm]: 492.0971 492.2180 492.3388 492.4597 492.5805 492.7013 492.8221 492.9428 493.0636 493.1843 493.3050 493.4257 493.5464 493.6671 493.7878 493.9084 494.0290 494.1496 494.2702 494.3908 494.5113 494.6319 494.7524 494.8729 494.9934 495.1139 495.2343 495.3548 495.4752 495.5956 495.7160 495.8364 495.9568 496.0771 496.1974 496.3177 496.4380 496.5583 496.6786 496.7988 496.9191 497.0393 497.1595 497.2797 497.3998 497.5200 497.6401 497.7602 497.8803 498.0004 498.1205 498.2405 498.3606 498.4806 498.6006 498.7206 498.8405 498.9605 499.0804 499.2004 499.3203 499.4401 499.5600 499.6799 499.7997 499.9195 500.0393 500.1591 500.2789 500.3987 500.5184 500.6381 500.7578 500.8775 500.9972 501.1169 501.2365 501.3561 501.4757 501.5953 501.7149 501.8345 501.9540 502.0735 502.1930 502.3125 502.4320 502.5515 502.6709 502.7904 502.9098 503.0292 503.1485 503.2679 503.3872 503.5066 503.6259 503.7452 503.8645 503.9837 504.1030 504.2222 504.3414 504.4606 504.5798 504.6990 504.8181 504.9373 505.0564 505.1755 505.2946 505.4136 505.5327 505.6517 505.7707 505.8897 506.0087 506.1277 506.2466 506.3656 506.4845 506.6034 506.7223 506.8412 506.9600 507.0788 507.1977 507.3165 507.4353 507.5540 507.6728 507.7915 507.9102 508.0289 508.1476 508.2663 508.3850 508.5036 508.6222 508.7408 508.8594 508.9780 509.0965 509.2151 509.3336 509.4521 509.5706 509.6891 509.8075 509.9260 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211115T123702.6Z 7989.525725 172 1 22.90 2 87.36 119.40 129.83 323.83 0.00 1 0.00 1 0 22 4.233e-03 4.206e-03 7.055e-04 7.047e-04 6.442118e+03 4.541537e+01 4.490761e+02 -6.000000e+00 2.350610e+02 276.41 -2.00 20.00 -2.00 505.36 0.00e+00 1.117244e-03 1.942955e-05 6.618119e-05 -6.000000e+00 1.181376e-04 276.41 -2.00 20.00 -2.00 500.80 0.00e+00 1.501253e+00 1.384142e-02 5.094615e-02 -6.000000e+00 8.466135e-02 222.44 -2.00 3.58 -2.00 502.34 0.00e+00 14.460 0.059 489.00 513.00 1 4.4655e+00 1.0599e-03 2.2191e-02 -6.0000e+00 6.4894e-03 -8.9859e-03 2.6708e-04 1.6926e-03 -6.0000e+00 1.6721e-03 2.6664e-03 2.8328e-03 7.3987e-05 6.1098e-05 -6.0000e+00 4.6842e-04 1.1281e-03 1.0712e-04 12 9 1 12 1 1 57.53 22.63 1.49 0.00113 0.02078 16 8 1 4 0 1336.720 26.41 20.01 22.63 5.75 33.2 906.39 -826 -319 -64 148 355 601 601 772 487 284 230 -63 -344 -407 -563 -465 -35 359 196 38 169 301 359 400 518 475 339 35 -444 -723 -534 -485 -85 222 199 105 24 -33 -208 -230 47 102 169 405 599 214 232 202 -73 -484 -744 -920 -983 -501 -165 -163 78 5 213 361 380 621 637 573 457 167 91 -103 -288 -458 -315 -270 -138 -90 -127 -500 -555 -680 -718 -615 -646 -599 -562 -324 -152 -163 -301 -61 -93 -183 129 462 405 407 416 249 -254 -200 -647 -972 -750 -535 -88 -68 -162 -368 -375 -419 -345 -6 34 221 444 704 647 881 977 839 582 380 237 229 311 423 164 272 290 149 315 274 -93 -345 -386 -515 -301 -197 -11 -12 143 172 162 427 257 292 288 -2 -235 -498 -520 -542 -774 -299 -60 144 347 599 596 767 483 279 228 -62 -334 -392 -545 -456 -34 358 195 38 171 305 365 408 530 486 344 35 -444 -710 -522 -480 -85 222 203 107 25 -34 -208 -230 47 103 173 411 609 219 235 205 -73 -481 -725 -900 -964 -489 -165 -164 79 5 215 364 385 630 647 580 458 169 91 -102 -281 -445 -311 -263 -136 -89 -127 -494 -541 -668 -701 -599 -633 -581 -550 -320 -152 -160 -297 -60 -91 -182 129 466 403 409 412 245 -245 -191 -612 -916 -712 -511 -86 -69 -163 -371 -376 -417 -343 -6 34 223 452 721 667 898 1001 862 595 391 241 231 312 427 166 277 295 152 321 279 -94 -345 -382 -510 -301 -200 -11 -12 148 180 168 445 270 307 302 -2 -245 -511 -530 -554 SQ 20211115T123956.1Z 7989.527732 174 1 49.33 2 86.91 119.92 130.11 324.66 0.00 1 0.00 1 0 22 4.044e-03 4.018e-03 1.749e-04 1.747e-04 6.253942e+03 1.121654e+01 4.383757e+02 -6.000000e+00 2.245499e+02 276.41 -2.00 20.00 -2.00 505.35 0.00e+00 1.103528e-03 4.820145e-06 6.725529e-05 -6.000000e+00 1.128600e-04 276.41 -2.00 20.00 -2.00 500.79 0.00e+00 1.411324e+00 3.433766e-03 4.955495e-02 -6.000000e+00 8.083085e-02 222.44 -2.00 3.58 -2.00 502.34 0.00e+00 13.378 0.047 489.00 513.00 1 2.6853e+00 2.6296e-04 2.0199e-02 -6.0000e+00 6.1965e-03 -1.3510e-02 6.6280e-05 1.5941e-03 -6.0000e+00 1.5954e-03 1.8497e-02 1.9182e-03 1.8362e-05 6.0662e-05 -6.0000e+00 4.4718e-04 -3.7589e-03 1.8058e-04 11 8 0 10 0 0 82.61 22.63 1.46 -0.00376 0.00955 259 55 1 4 0 190.390 26.32 20.01 22.63 6.01 33.0 906.56 -591 -332 28 155 416 692 770 725 594 387 197 -57 -275 -406 -474 -390 -135 137 246 72 145 280 327 474 526 384 318 90 -326 -672 -529 -466 -32 325 184 -41 -12 -76 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930 815 567 354 251 193 351 428 268 250 307 252 320 278 19 -274 -331 -423 -305 -19 -74 -78 147 270 269 310 415 318 238 -5 -261 -513 -546 -462 SQ 20211115T125229.7Z 7989.536455 177 1 30.21 2 84.98 122.19 131.26 328.34 0.00 1 0.00 1 0 22 3.697e-03 3.680e-03 2.845e-04 2.843e-04 4.310619e+03 1.768874e+01 3.044331e+02 -6.000000e+00 2.053074e+02 276.41 -2.00 20.00 -2.00 505.33 0.00e+00 8.385886e-04 7.814381e-06 5.018155e-05 -6.000000e+00 1.031881e-04 276.41 -2.00 20.00 -2.00 500.70 0.00e+00 1.113618e+00 5.604834e-03 3.552752e-02 -6.000000e+00 7.390101e-02 222.44 -2.00 3.58 -2.00 502.26 0.00e+00 9.816 0.018 489.00 513.00 1 3.6737e+00 4.2929e-04 1.4244e-02 -6.0000e+00 5.6653e-03 -8.2752e-03 1.0886e-04 1.1246e-03 -6.0000e+00 1.4586e-03 1.1593e-02 1.8244e-03 3.0255e-05 4.2359e-05 -6.0000e+00 4.0884e-04 5.4228e-03 1.2688e-04 12 1 1 12 1 1 36.54 22.67 1.27 0.00542 0.01808 83 29 1 4 0 357.510 26.41 20.00 22.67 6.30 32.8 908.29 -677 -308 -52 107 315 592 657 658 477 342 141 -97 -259 -372 -466 -398 -131 138 193 41 156 291 301 494 505 341 287 115 -339 -572 -526 -455 53 324 174 -49 26 -74 -225 -230 -16 75 174 318 394 340 245 149 -113 -453 -696 -885 -790 -544 -240 -98 -5 81 122 200 338 444 420 431 424 199 21 -15 -187 -371 -356 -278 -132 39 -67 -414 -525 -452 -507 -593 -499 -567 -439 -206 -185 -218 -183 -184 -172 -83 171 384 459 344 226 190 -96 -281 -516 -735 -735 -476 -138 -79 -216 -391 -363 -311 -219 -1 7 181 335 546 640 763 808 721 517 345 207 179 314 347 209 243 269 248 214 268 -22 -267 -322 -429 -319 -8 -104 -98 150 254 262 246 360 286 251 -58 -260 -493 -514 -411 -646 -295 -50 105 311 596 669 662 486 344 141 -96 -257 -366 -460 -391 -131 138 197 41 159 296 308 506 519 350 292 117 -338 -569 -520 -449 53 330 177 -50 26 -76 -228 -233 -17 76 177 327 407 351 250 151 -113 -452 -680 -866 -774 -532 -236 -99 -5 82 123 203 344 453 428 438 426 198 21 -15 -182 -365 -350 -271 -130 39 -66 -408 -510 -440 -492 -575 -486 -548 -429 -203 -183 -215 -180 -182 -170 -83 171 382 459 343 225 185 -94 -271 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