File name: Pandora169s1_Egbert_20221028_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241103T175016.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20221028_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20221028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221028T125454.8Z 8336.538134 71 1 49.64 2 80.33 119.31 117.37 100.64 0.00 1 0.00 1 0 25 4.721e-01 2.913e-02 2.090e-01 9.180e-03 6.546314e-01 5.147027e-03 8.394336e-03 -6.000000e+00 2.847136e-01 224.11 -2.00 3.58 -2.00 320.89 0.00e+00 1.773844e-02 2.066624e-03 2.641358e-03 -6.000000e+00 1.294296e-02 278.73 -2.00 20.00 -2.00 320.36 0.00e+00 5.684 0.004 302.00 328.00 3 3.8563e+00 1.5921e-02 6.4918e-02 -6.0000e+00 7.0186e-01 6.1795e-01 1.9888e-02 3.5524e-02 -6.0000e+00 7.6248e-01 -7.1488e-01 1.6940e-02 2.6232e-02 -6.0000e+00 4.5219e-01 3.0504e-01 8.3759e-03 1.8667e-02 -6.0000e+00 1.9390e-01 1.9763e-05 -3.0175e-03 2.7914e-04 2.4794e-04 -6.0000e+00 1.5342e-02 2.3189e-03 -1.0742e-04 12 9 8 11 40 0 96.82 22.91 0.50 0.00232 -0.02036 13 3 1 5 0 3817.580 26.51 19.98 22.91 6.94 36.3 918.91 900000 118717 191590 900000 -136556 105719 900000 -40302 -113179 -100446 -30304 -94347 -136656 57565 75101 7432 114939 54179 -22983 80755 123139 1587 24336 15556 -29136 22020 81315 900000 7461 900000 88590 162403 185400 -15657 129973 10849 -2220 8512 7423 20322 -6684 41597 26141 -946 43949 56614 40652 10749 15549 11656 -2355 19640 21451 16735 12424 -1327 6514 3628 1413 23580 -6520 2294 -1138 17520 7444 18603 -5769 327 -1076 16067 4108 6087 11456 3312 170 -5541 -8939 -7598 2290 -7706 6396 -7941 -3801 -2686 -6040 276 1462 -1163 -432 -496 -2916 1527 -2714 -7020 1133 225 -3293 -2405 -1463 224 -1549 -3200 -3349 -432 -1284 1172 -214 -399 -859 87 3161 433 571 669 1544 600 -45 1968 -1124 -358 -2214 2149 2685 1074 815 1334 -736 3892 -518 762 -270 169 -1201 2287 923 -249 -1100 -944 -632 -76 -151 -998 900000 1062 1713 900000 -8929 945 900000 -1008 -5380 -4246 -721 -4664 -12510 1183 1598 330 2143 1854 -1610 2260 2288 84 1023 694 -1902 900 1931 900000 362 900000 2810 3050 3065 -1560 3423 825 -204 800 795 2130 -954 4028 3021 -143 4561 5392 4599 1652 2390 1979 -492 3622 4128 3505 2748 -334 1508 842 329 4565 -1778 641 -366 5127 2437 5419 -2105 118 -432 6057 1820 2669 4614 1338 65 -2048 -3333 -2973 935 -3998 3316 -5166 -2545 -1878 -4584 208 1127 -928 -337 -371 -2100 1006 -1849 -5298 895 205 -3504 -2787 -1752 260 -1703 -3289 -3306 -426 -1339 1257 -246 -493 -1165 128 4835 695 907 1026 2269 877 -67 3026 -1844 -591 -3654 3321 4013 1577 1161 1845 -1042 5664 -858 1364 -519 339 -2539 4925 2093 -585 -2636 -2266 -1489 -171 -325 -2081 SS 20221028T135100.6Z 8336.577090 105 1 16.42 2 72.11 130.54 108.19 109.14 0.00 1 0.00 1 0 25 2.779e-02 6.350e-03 4.696e-03 6.217e-04 4.155471e-01 3.268360e-04 5.053341e-03 -6.000000e+00 1.662415e-02 224.11 -2.00 3.58 -2.00 318.60 0.00e+00 1.254656e-03 6.919923e-05 3.166363e-04 -6.000000e+00 7.314303e-04 278.73 -2.00 20.00 -2.00 317.97 0.00e+00 3.211 0.001 302.00 328.00 3 8.8540e-01 8.8210e-04 3.7808e-02 -6.0000e+00 4.0973e-02 2.2503e-02 1.0065e-03 2.1628e-02 -6.0000e+00 4.4451e-02 -1.1905e-02 7.0710e-04 1.0891e-02 -6.0000e+00 2.6495e-02 -5.6767e-03 3.7100e-04 3.3355e-03 -6.0000e+00 1.1285e-02 5.9303e-03 -5.2760e-04 1.9543e-05 4.1477e-05 -6.0000e+00 8.6777e-04 1.2023e-04 4.6776e-05 12 1 1 12 1 1 99.91 22.90 0.16 0.00012 -0.00384 290 181 1 5 0 55.650 26.51 20.00 22.90 7.39 36.6 921.41 -4089 -3909 -7107 -11614 -11719 -10894 -7084 -9377 -8322 -9466 -9022 -6703 -4106 -2475 -266 -1029 729 559 1004 843 92 -76 830 18 247 -875 -2537 -2644 -1636 126 156 1887 871 -3890 -3283 -2501 -2312 -849 -148 -1165 -1223 -446 -771 -310 309 -469 -525 -140 -425 836 1031 1028 1252 1156 758 1192 573 38 38 661 1374 2047 2027 1507 -276 -149 -146 592 1676 765 430 330 303 449 -254 -389 -814 -713 -369 -1118 -1269 -1775 -2286 -1034 -807 -402 257 310 361 280 678 -44 13 563 499 268 700 333 -332 -459 -882 -948 142 163 -1416 -1239 -826 -725 300 440 383 66 287 37 274 571 608 332 245 -360 -204 255 409 449 637 -89 635 1190 309 72 -301 -395 -176 157 -341 -306 164 152 -172 152 -190 -569 -156 -149 -282 -454 -471 -441 -303 -425 -408 -494 -495 -405 -288 -204 -23 -101 76 62 117 102 11 -10 109 3 37 -136 -394 -397 -242 19 27 357 167 -788 -648 -512 -535 -231 -44 -403 -461 -175 -313 -127 127 -195 -219 -59 -182 351 469 506 659 607 415 668 326 21 21 373 813 1316 1347 1057 -195 -101 -96 404 1249 607 348 273 256 357 -186 -274 -547 -491 -281 -929 -1133 -1671 -2314 -1051 -873 -440 291 355 405 311 697 -45 12 566 528 307 859 429 -442 -593 -1105 -1151 166 200 -1805 -1599 -1120 -1007 445 676 596 103 447 54 393 795 864 498 374 -570 -321 389 626 657 925 -125 880 1727 474 114 -492 -672 -301 274 -629 -569 310 291 -324 284 -343 -1029 SS 20221028T135606.6Z 8336.580632 108 1 46.45 2 71.42 131.63 107.38 109.91 0.00 1 0.00 1 0 25 2.230e-02 6.335e-03 2.123e-03 3.005e-04 4.028244e-01 1.578012e-04 4.905990e-03 -6.000000e+00 1.334258e-02 224.11 -2.00 3.58 -2.00 318.50 0.00e+00 1.075612e-03 3.231518e-05 2.754872e-04 -6.000000e+00 5.870831e-04 278.73 -2.00 20.00 -2.00 317.86 0.00e+00 3.099 0.001 302.00 328.00 3 5.9968e-01 4.2431e-04 3.6541e-02 -6.0000e+00 3.2885e-02 1.8629e-02 4.8318e-04 2.0951e-02 -6.0000e+00 3.5677e-02 -9.3391e-03 3.3361e-04 1.0520e-02 -6.0000e+00 2.1265e-02 -6.4795e-03 1.7458e-04 3.1703e-03 -6.0000e+00 9.0567e-03 8.9134e-03 -5.4001e-04 9.4808e-06 3.9755e-05 -6.0000e+00 6.9653e-04 3.5321e-04 3.9161e-05 10 0 0 10 0 0 99.85 22.90 0.17 0.00035 -0.00370 1273 272 1 5 0 36.220 26.51 20.01 22.90 7.82 36.8 925.76 -1869 -5803 -5527 -9314 -8132 -8528 -4672 -5758 -5751 -8756 -7229 -5768 -3705 -1444 -591 -569 209 664 548 1082 -452 408 277 557 -365 -699 -2728 -1788 -1671 704 393 2048 6 -2965 -3456 -2266 -2502 -433 -584 -908 -1198 -466 -755 -540 45 -245 -555 -260 -419 930 1096 1043 1274 1052 651 1296 523 87 87 584 1310 1914 2052 1253 -226 -111 -21 512 1724 787 418 325 359 342 -222 -420 -713 -721 -212 -1084 -1294 -1872 -2192 -1221 -685 -364 286 199 397 331 602 14 198 684 484 333 711 295 -349 -447 -866 -950 159 173 -1457 -1217 -918 -693 309 441 322 46 190 95 249 643 500 366 168 -335 -255 248 434 505 680 -1 606 1228 276 109 -333 -391 -169 172 -253 -315 179 156 -217 75 -216 -549 -73 -255 -243 -401 -327 -350 -203 -283 -309 -508 -436 -385 -287 -121 -57 -61 24 80 70 142 -61 56 40 85 -60 -117 -459 -288 -266 116 72 385 1 -632 -727 -491 -616 -124 -187 -332 -477 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