File name: Pandora169s1_Egbert_20221118_L2Fit_fwvt1c15d20220511p1-8.txt File generation date: 20241103T191105.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20221118_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20221118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1649 1799 Nominal wavelengths inside fitting window [nm]: 492.0224 492.1433 492.2641 492.3850 492.5058 492.6266 492.7474 492.8682 492.9890 493.1097 493.2304 493.3512 493.4718 493.5925 493.7132 493.8338 493.9545 494.0751 494.1957 494.3163 494.4368 494.5574 494.6779 494.7984 494.9189 495.0394 495.1599 495.2803 495.4008 495.5212 495.6416 495.7620 495.8824 496.0027 496.1230 496.2434 496.3637 496.4840 496.6042 496.7245 496.8447 496.9649 497.0851 497.2053 497.3255 497.4457 497.5658 497.6859 497.8060 497.9261 498.0462 498.1662 498.2863 498.4063 498.5263 498.6463 498.7663 498.8862 499.0062 499.1261 499.2460 499.3659 499.4858 499.6056 499.7255 499.8453 499.9651 500.0849 500.2046 500.3244 500.4441 500.5639 500.6836 500.8033 500.9229 501.0426 501.1622 501.2819 501.4015 501.5210 501.6406 501.7602 501.8797 501.9992 502.1187 502.2382 502.3577 502.4772 502.5966 502.7160 502.8354 502.9548 503.0742 503.1935 503.3129 503.4322 503.5515 503.6708 503.7901 503.9093 504.0286 504.1478 504.2670 504.3862 504.5054 504.6245 504.7436 504.8628 504.9819 505.1010 505.2200 505.3391 505.4581 505.5771 505.6961 505.8151 505.9341 506.0530 506.1720 506.2909 506.4098 506.5287 506.6476 506.7664 506.8852 507.0041 507.1229 507.2416 507.3604 507.4792 507.5979 507.7166 507.8353 507.9540 508.0726 508.1913 508.3099 508.4285 508.5471 508.6657 508.7843 508.9028 509.0214 509.1399 509.2584 509.3768 509.4953 509.6137 509.7322 509.8506 509.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221118T132104.5Z 8357.556302 278 1 49.32 2 81.40 127.85 36.79 191.43 0.00 1 0.00 1 0 15 3.676e-03 3.658e-03 5.761e-04 5.757e-04 1.854498e+03 3.357747e+01 1.302830e+02 -6.000000e+00 2.038653e+02 276.07 -2.00 20.00 -2.00 505.31 0.00e+00 8.630225e-04 1.574329e-05 4.755680e-05 -6.000000e+00 1.024227e-04 276.07 -2.00 20.00 -2.00 500.66 0.00e+00 6.649917e-01 1.128796e-02 1.842651e-02 -6.000000e+00 7.309897e-02 222.40 -2.00 3.58 -2.00 502.22 0.00e+00 6.313 0.005 489.00 513.00 1 6.2644e+00 8.6524e-04 8.9978e-03 -6.0000e+00 5.6102e-03 -1.1482e-02 2.1951e-04 6.2103e-04 -6.0000e+00 1.4312e-03 1.4636e-03 -2.3683e-04 6.1998e-05 2.4525e-05 -6.0000e+00 4.0572e-04 -9.2333e-03 2.1479e-04 10 0 0 10 0 0 99.84 23.15 1.33 -0.00923 -0.01088 23 5 1 4 0 2144.020 26.73 20.00 23.15 2.80 36.0 905.10 -750 -547 -337 -29 37 282 609 861 547 448 275 -39 -150 -317 -444 -471 -200 39 372 137 62 343 194 299 556 413 393 271 90 -458 -713 -595 -370 184 244 46 33 9 -159 -162 -76 -37 47 126 325 444 355 181 238 -131 -409 -818 -832 -809 -481 -156 63 50 106 115 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379 409 125 -10 -350 -521 -605 -370 SQ 20221118T133211.2Z 8357.564018 280 1 50.11 2 79.86 130.00 37.29 195.84 0.00 1 0.00 1 0 15 3.372e-03 3.362e-03 8.668e-04 8.659e-04 1.733866e+03 5.064034e+01 1.216091e+02 -6.000000e+00 1.869876e+02 276.06 -2.00 20.00 -2.00 505.29 0.00e+00 7.490140e-04 2.367473e-05 4.052710e-05 -6.000000e+00 9.395151e-05 276.06 -2.00 20.00 -2.00 500.54 0.00e+00 5.948601e-01 1.707844e-02 1.684038e-02 -6.000000e+00 6.708744e-02 222.40 -2.00 3.58 -2.00 502.13 0.00e+00 5.443 0.003 489.00 513.00 1 7.1925e+00 1.3101e-03 7.7599e-03 -6.0000e+00 5.1484e-03 5.0231e-03 3.3270e-04 5.5051e-04 -6.0000e+00 1.3143e-03 6.5677e-04 5.4921e-04 9.3268e-05 2.1371e-05 -6.0000e+00 3.7214e-04 -5.1589e-03 1.4529e-04 11 1 0 11 40 0 98.53 23.11 1.29 -0.00516 -0.00135 14 3 1 4 0 3578.720 26.73 19.99 23.11 3.42 36.2 908.93 -780 -488 -353 113 -49 167 591 615 477 439 182 19 -69 -368 -484 -459 36 25 226 172 -1 164 20 402 545 446 424 179 -3 -392 -492 -421 -395 258 333 211 -198 58 -200 -252 34 -185 25 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147 -89 235 324 254 153 -38 -458 -372 -214 -531 9 -77 11 239 99 180 145 156 423 45 -14 -397 -354 -338 -211 SQ 20221118T133623.3Z 8357.566936 283 1 8.38 2 79.28 130.82 37.52 197.49 0.00 1 0.00 1 0 15 3.585e-03 3.572e-03 7.995e-04 7.989e-04 1.483911e+03 4.609184e+01 1.064933e+02 -6.000000e+00 1.987714e+02 276.06 -2.00 20.00 -2.00 505.30 0.00e+00 8.140499e-04 2.185884e-05 4.316732e-05 -6.000000e+00 9.989048e-05 276.06 -2.00 20.00 -2.00 500.60 0.00e+00 5.293957e-01 1.568627e-02 1.467817e-02 -6.000000e+00 7.135945e-02 222.40 -2.00 3.58 -2.00 502.18 0.00e+00 5.178 0.003 489.00 513.00 1 5.2184e+00 1.2031e-03 7.3754e-03 -6.0000e+00 5.4757e-03 -5.9915e-03 3.0559e-04 5.0142e-04 -6.0000e+00 1.3989e-03 4.9281e-03 1.5265e-03 8.6238e-05 2.1211e-05 -6.0000e+00 3.9562e-04 -9.0551e-03 1.2285e-04 12 1 1 12 1 1 27.01 23.10 1.30 -0.00906 0.00153 10 14 1 4 0 746.320 26.73 19.99 23.10 3.61 36.2 909.64 -777 -623 -234 -177 34 165 609 837 488 383 369 -51 -127 -318 -387 -361 -359 -105 335 130 13 266 271 328 433 531 370 376 109 -408 -509 -479 -378 143 425 227 -134 135 -218 -237 -135 -86 41 165 433 419 218 270 88 -124 -500 -769 -917 -770 -462 -171 76 -86 49 126 261 545 480 417 411 410 225 -57 22 -223 -259 -259 -271 -99 52 -115 -446 -499 -394 -496 -325 -217 -410 -341 -358 -176 -247 -80 -19 -154 -60 198 417 523 316 258 97 -129 -248 -548 -737 -532 -440 -67 -48 -139 -388 -288 -311 -175 -12 11 262 432 425 412 562 760 604 360 300 73 67 252 446 229 340 179 78 362 311 -123 -284 -451 -307 -245 -40 -52 -75 124 146 253 252 325 302 151 -81 -444 -546 -555 -270 -747 -605 -228 -175 34 168 619 857 502 391 378 -52 -127 -315 -388 -356 -359 -105 342 133 14 273 279 339 448 550 382 384 111 -407 -508 -477 -376 145 435 232 -137 139 -223 -241 -137 -87 42 168 444 432 224 274 89 -125 -495 -759 -894 -753 -452 -172 76 -88 49 127 263 550 486 422 414 414 224 -56 22 -219 -252 -252 -266 -98 51 -113 -442 -487 -379 -476 -312 -210 -400 -336 -351 -173 -245 -80 -19 -153 -59 197 421 521 319 257 95 -126 -241 -525 -703 -511 -426 -65 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