File name: Pandora169s1_Egbert_20221210_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241103T191501.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20221210_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20221210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221210T132020.0Z 8379.555787 289 1 49.07 2 85.48 128.50 74.31 292.02 0.00 1 0.00 1 0 17 6.166e-01 5.394e-02 2.627e-01 2.710e-02 9.482615e-01 1.589911e-02 1.111290e-02 -6.000000e+00 3.668080e-01 222.13 -2.00 3.58 -2.00 321.47 0.00e+00 -1.057134e-02 4.582941e-03 4.102667e-03 -6.000000e+00 1.657371e-02 273.56 -2.00 20.00 -2.00 320.89 0.00e+00 10.591 0.023 302.00 328.00 3 9.0411e-03 4.6932e-02 1.1839e-01 -6.0000e+00 9.0212e-01 2.1380e+00 5.4670e-02 6.6446e-02 -6.0000e+00 9.8296e-01 -2.0507e+00 3.5957e-02 2.6011e-02 -6.0000e+00 5.8370e-01 6.9713e-01 1.9214e-02 1.1772e-02 -6.0000e+00 2.5072e-01 6.0459e-06 -1.3843e-03 7.6279e-04 1.5635e-04 -6.0000e+00 1.9736e-02 3.6119e-03 -1.5761e-04 12 8 8 10 0 0 4.66 23.08 1.20 0.00361 -0.00679 21 4 1 5 0 2336.090 26.73 20.00 23.08 0.13 35.8 904.90 900000 12726 37335 900000 2063 106953 72131 37949 170896 -43279 29544 -41618 7246 55512 59281 27123 -13022 57150 38189 84719 261956 93129 -23376 -21508 5357 -33692 103525 900000 -1598 900000 17608 900000 -46957 -6473 412097 -41020 67306 22117 10086 37698 12817 58758 30661 -2914 101605 -9402 300190 -2763 55517 2004 16574 14391 23033 143657 1705 32775 50676 4594 -29425 29431 -1741 -30133 -22651 6108 25259 64457 -9541 -38114 9627 45120 11104 17429 14078 6742 -11741 -22151 -19275 -14510 -4802 1285 8949 15335 2454 -4984 -10502 17090 7184 -18603 -68 6963 -4253 29083 10044 -5044 23452 3360 1736 -1561 -2251 -1824 139 -9246 -17197 -3424 -4146 3728 2574 7968 4301 62 -146 218 808 1854 4361 3190 -5286 1628 1305 11511 1715 -9362 383 -1430 -4045 5821 854 3876 26 -5356 1539 -401 -4101 1038 1561 -664 -600 -546 -20 1096 1351 637 900000 1575 3351 900000 185 3200 3173 2471 4511 -6474 2184 -6811 816 4298 4799 3150 -2269 4827 3696 5112 6915 4565 -3538 -3369 650 -5751 4294 900000 -160 900000 1726 900000 -9255 -867 10878 -6641 4315 2586 1540 4833 2199 6315 4162 -516 5939 -1595 7924 -438 5129 340 2656 2551 3996 8459 399 5685 7166 962 -7934 4162 -341 -8522 -6577 1428 4953 8507 -2716 -14555 2723 9784 3517 5094 3955 1818 -3343 -6348 -5306 -4158 -1458 434 3240 5841 1071 -2473 -5766 7895 3477 -11524 -34 3230 -2077 9925 4318 -2636 11541 2217 1347 -1396 -2111 -1647 112 -7371 -14012 -2483 -3195 2814 2120 6913 4436 76 -200 316 1179 2627 5864 4318 -8009 2403 1994 15760 2484 -14416 517 -1905 -5381 6904 1105 5477 44 -10364 3084 -889 -10197 2638 4192 -1886 -1726 -1561 -56 2791 3179 1430 SS 20221210T133140.5Z 8379.563663 292 1 49.25 2 83.92 130.60 76.13 293.71 0.00 1 0.00 1 0 17 5.132e-01 2.204e-02 2.552e-01 7.140e-03 9.103615e-01 4.224464e-03 1.031739e-02 -6.000000e+00 3.086131e-01 222.13 -2.00 3.58 -2.00 322.05 0.00e+00 1.035407e-02 2.268452e-03 2.322470e-03 -6.000000e+00 1.373723e-02 273.56 -2.00 20.00 -2.00 321.64 0.00e+00 8.462 0.012 302.00 328.00 3 4.7997e-01 1.5270e-02 9.6342e-02 -6.0000e+00 7.5913e-01 8.8664e-01 2.1334e-02 5.2809e-02 -6.0000e+00 8.2784e-01 -1.1460e+00 2.1372e-02 3.1132e-02 -6.0000e+00 4.8958e-01 4.6637e-01 1.0038e-02 1.3615e-02 -6.0000e+00 2.0741e-01 3.8512e-05 -2.5296e-03 2.0960e-04 2.2910e-04 -6.0000e+00 1.6493e-02 2.4015e-03 -1.0159e-04 12 8 8 10 0 0 27.83 23.09 0.27 0.00240 -0.01661 76 16 1 5 0 647.870 26.73 20.00 23.09 0.60 35.8 908.33 -65198 -102500 -127077 900000 -94218 900000 -111691 -178974 -108257 -212532 -371 -189614 -114102 84953 900000 -48399 -105473 19807 88592 71040 171828 -34063 -46382 -78466 -46022 -35133 71844 900000 14179 900000 101002 61683 4851 -7751 900000 2062 92451 -10574 64746 30958 65403 41538 68893 26840 50367 30079 77259 1358 48570 11621 37971 30389 44888 66055 5867 26463 43164 19156 -1182 8288 15517 14079 10439 27650 14961 40033 11621 3108 6767 24496 12911 10797 9965 15211 193 2129 -1369 7276 -1615 1988 298 5439 -3296 959 -2445 3810 -199 -3591 -1046 -491 -4886 6151 -4814 -4839 1428 -2764 -1993 -1509 -2932 -1458 -2445 -2500 -3042 -2073 -3763 -1294 -1384 -1018 -123 -1276 -749 -725 -978 -854 134 39 204 612 1573 1901 2736 287 3047 411 1395 636 1730 948 304 -862 1035 -11 -189 99 31 390 281 -91 170 -622 -399 -1667 -695 -1711 -2651 900000 -1217 900000 -1609 -4812 -1559 -7759 -3 -7416 -2962 591 900000 -1234 -4950 325 748 706 1195 -837 -1290 -3055 -1301 -942 692 900000 239 900000 1134 1134 162 -295 900000 69 1469 -510 1833 1292 2241 1771 2464 1381 2078 1562 2801 98 2522 904 2541 2430 3375 4562 677 2680 3658 1990 -136 922 1713 1681 1486 3687 2374 5027 2015 601 1422 4798 3008 2573 2271 2997 39 418 -279 1431 -414 594 101 1980 -1426 423 -1182 1815 -102 -1919 -533 -237 -2330 2557 -2313 -2605 810 -1952 -1642 -1335 -2785 -1335 -2185 -2011 -2311 -1587 -3099 -1106 -1281 -994 -136 -1643 -1021 -1048 -1435 -1229 185 54 290 910 2402 2893 3978 427 4253 571 1867 843 2340 1446 517 -1701 2126 -24 -457 246 80 1059 774 -252 453 -1573 -974 -3891 SS 20221210T134226.4Z 8379.571138 295 1 48.93 2 82.48 132.63 77.83 295.32 0.00 1 0.00 1 0 17 6.449e-01 1.219e-02 1.632e-01 2.920e-03 8.090784e-01 1.646413e-03 9.257384e-03 -6.000000e+00 3.826559e-01 222.13 -2.00 3.58 -2.00 321.62 0.00e+00 7.243907e-03 8.308541e-04 2.441128e-03 -6.000000e+00 1.662250e-02 273.56 -2.00 20.00 -2.00 321.20 0.00e+00 7.092 0.007 302.00 328.00 3 5.0382e-01 5.6559e-03 8.1527e-02 -6.0000e+00 9.4066e-01 2.6470e-01 8.3055e-03 4.6225e-02 -6.0000e+00 1.0230e+00 -3.2636e-01 9.1556e-03 2.9026e-02 -6.0000e+00 6.0876e-01 1.2624e-01 4.2978e-03 1.3069e-02 -6.0000e+00 2.5899e-01 1.6082e-04 -1.2423e-03 8.5705e-05 1.9803e-04 -6.0000e+00 2.0129e-02 1.3582e-03 -5.9795e-05 12 8 8 10 0 0 0.09 23.10 0.22 0.00136 -0.00798 172 37 1 5 0 284.400 26.73 20.00 23.10 0.96 35.5 908.85 -150455 -238116 -240017 -91685 -152051 -171795 -209425 -235870 -180633 -254552 -215363 -184984 -110104 -54881 -91038 -68784 -112092 -45890 -45998 -21195 3839 -4387 -71703 -45305 -53044 -25981 -53982 142478 -32268 18512 -11360 24172 -41291 -16864 -4837 10620 -6568 -5210 -10535 6013 43 1080 -3594 5947 6758 9563 13927 11207 12436 12759 10783 12073 6255 16818 6607 12291 8352 2747 503 4149 6675 5996 8511 9363 7407 8092 4315 2172 6377 6795 4980 2282 2850 1682 1268 -2399 -1669 -1630 1163 -568 645 -1523 -2189 -1690 -1093 -464 554 -1854 781 -353 -500 -247 -617 -1932 190 -940 191 -607 -174 -619 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