File name: Pandora169s1_Egbert_20230106_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241103T201429.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20230106_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230106T154303.3Z 8406.654900 369 1 49.44 2 70.66 155.09 106.54 339.49 0.00 1 0.00 1 0 17 1.385e-01 8.835e-03 5.296e-02 3.338e-03 4.633592e-01 1.754633e-03 5.574573e-03 -6.000000e+00 8.244747e-02 222.96 -2.00 3.58 -2.00 319.27 0.00e+00 1.296887e-03 4.450378e-04 2.649451e-04 -6.000000e+00 3.541558e-03 271.58 -2.00 20.00 -2.00 318.79 0.00e+00 2.986 0.000 302.00 328.00 3 5.1017e+00 4.8052e-03 3.7498e-02 -6.0000e+00 2.0318e-01 8.3414e-02 5.5819e-03 2.4008e-02 -6.0000e+00 2.2091e-01 6.2623e-03 4.4822e-03 1.2315e-02 -6.0000e+00 1.3122e-01 -1.8072e-02 2.3799e-03 3.8646e-03 -6.0000e+00 5.5647e-02 9.6540e-05 -9.4625e-04 1.0486e-04 4.8302e-05 -6.0000e+00 4.3233e-03 -2.9202e-04 -7.0703e-05 11 8 0 10 0 0 99.96 23.06 -0.00 -0.00029 -0.00740 31 7 1 5 0 1594.560 26.73 20.00 23.06 8.64 37.3 969.93 86954 -43048 35472 40090 5036 74512 48224 -15658 5868 -29568 -24162 10179 -1249 29858 17050 -6870 -10058 -12186 -2309 5275 14941 2254 606 -1533 -11680 2758 4868 34539 2964 8723 5441 13638 -16632 -5572 2516 1706 -1109 -3180 -2151 -2871 -3640 -1551 -2548 -3 -260 -42 1251 -38 -1455 2114 2016 1162 2577 3370 -1410 1288 821 -381 -2307 1409 1242 2178 2050 1465 -1044 1590 -1245 -120 358 1007 602 36 -203 -246 -1125 506 -1463 -45 -597 -1652 -241 -1377 -2588 -2096 -506 -389 1289 281 1077 9 1183 1165 490 381 1670 334 717 365 -221 -270 -829 -1466 -239 343 -1384 -1151 -735 -584 822 634 -64 -129 253 91 460 743 495 396 -113 19 -350 -33 187 419 63 -319 352 1302 -280 -469 -638 -575 -533 116 123 -308 476 624 -56 239 -179 -449 998 -1437 646 679 108 961 815 -479 163 -1150 -953 339 -54 1160 847 -464 -754 -991 -181 401 1062 183 53 -144 -1270 270 464 2479 282 843 606 1572 -2703 -828 343 244 -183 -628 -494 -749 -1034 -454 -774 -1 -79 -13 381 -12 -474 705 726 454 1061 1451 -654 600 387 -180 -1093 654 608 1144 1167 878 -636 918 -728 -72 234 714 451 27 -152 -175 -748 307 -869 -27 -397 -1239 -197 -1229 -2461 -2085 -522 -419 1412 313 1171 9 1166 1087 450 363 1705 378 883 480 -298 -357 -1037 -1738 -275 405 -1733 -1496 -991 -825 1217 993 -105 -212 406 140 676 1071 726 601 -179 30 -561 -51 285 619 90 -446 487 1868 -432 -769 -1089 -1010 -964 216 238 -612 954 1258 -112 466 -337 -829 SS 20230106T170750.5Z 8406.713779 416 1 1.57 2 66.81 175.70 109.41 358.29 0.00 1 0.00 1 0 17 2.625e-02 6.941e-03 1.066e-02 1.938e-03 4.146255e-01 1.015310e-03 5.062030e-03 -6.000000e+00 1.563227e-02 222.97 -2.00 3.58 -2.00 318.06 0.00e+00 1.262555e-03 1.792815e-04 1.721717e-04 -6.000000e+00 6.711003e-04 271.58 -2.00 20.00 -2.00 317.55 0.00e+00 2.520 0.000 302.00 328.00 3 1.3650e+00 2.6872e-03 3.2376e-02 -6.0000e+00 3.8525e-02 5.8948e-02 3.0338e-03 2.1257e-02 -6.0000e+00 4.1880e-02 -2.8453e-02 2.0179e-03 1.0757e-02 -6.0000e+00 2.4876e-02 3.9381e-04 1.0513e-03 3.3329e-03 -6.0000e+00 1.0554e-02 6.8105e-03 -6.1976e-04 5.9988e-05 4.1072e-05 -6.0000e+00 8.1919e-04 -1.4566e-03 1.5010e-05 12 9 1 12 1 1 98.45 23.08 0.21 -0.00146 -0.00611 18 139 1 5 0 73.320 26.73 20.01 23.08 9.16 37.1 971.88 -7821 -722 -11555 -10659 -9546 -7251 -6072 -5436 -5499 -9005 -9766 -3770 -4485 1512 -1030 466 -2335 1536 694 3119 -611 3767 683 1821 -940 -51 -3331 -1293 -2350 2146 925 2912 639 -2656 -3985 -1402 -2517 821 -220 -527 -1822 -666 -532 -1009 -93 -71 -71 -197 -710 662 1656 1026 1142 1625 813 1532 483 -101 -132 825 1427 1706 1936 747 -438 -338 -140 369 2094 647 196 361 98 421 309 -593 -681 -356 -19 -1513 -1226 -2073 -2271 -1642 -539 -539 294 61 264 192 668 129 267 703 406 321 481 227 -423 -322 -673 -665 246 528 -1344 -1297 -1023 -656 458 431 431 -92 -174 230 326 663 741 321 262 -220 -80 219 504 397 432 241 663 1221 105 153 -521 -457 -166 276 -465 -69 303 26 -152 20 -287 -598 -430 -40 -715 -615 -513 -386 -349 -347 -382 -631 -726 -297 -421 159 -129 64 -331 223 107 483 -99 596 117 328 -184 -10 -669 -245 -447 413 201 690 156 -672 -1000 -356 -731 274 -83 -214 -811 -307 -252 -485 -45 -34 -34 -95 -351 341 863 582 656 979 512 981 315 -66 -84 527 956 1185 1394 571 -334 -246 -104 271 1661 552 171 321 85 357 251 -442 -504 -269 -15 -1328 -1157 -2077 -2342 -1784 -594 -629 340 72 304 216 722 136 271 734 449 383 598 297 -574 -422 -847 -804 288 642 -1709 -1679 -1391 -914 657 645 675 -146 -266 337 464 914 1040 474 396 -333 -121 331 732 571 612 328 890 1714 156 239 -835 -738 -279 471 -818 -122 546 48 -273 36 -501 -1012 SS 20230106T171621.3Z 8406.719691 419 1 17.74 2 66.72 177.83 109.43 0.22 0.00 1 0.00 1 0 17 1.421e-01 1.108e-02 6.982e-02 6.011e-03 4.236650e-01 3.143217e-03 5.207852e-03 -6.000000e+00 8.442235e-02 222.97 -2.00 3.58 -2.00 318.66 0.00e+00 5.934006e-04 6.653377e-04 2.218892e-04 -6.000000e+00 3.635198e-03 271.58 -2.00 20.00 -2.00 318.17 0.00e+00 2.512 0.000 302.00 328.00 3 5.6573e+00 8.4300e-03 3.2770e-02 -6.0000e+00 2.0803e-01 8.9403e-02 9.6201e-03 2.1968e-02 -6.0000e+00 2.2631e-01 -5.6890e-03 7.0171e-03 1.1134e-02 -6.0000e+00 1.3442e-01 -8.0159e-03 3.7294e-03 3.2595e-03 -6.0000e+00 5.6916e-02 9.0093e-05 -2.5617e-03 1.8833e-04 4.2064e-05 -6.0000e+00 4.4366e-03 2.0907e-03 -4.2926e-04 12 9 9 12 33 1 99.99 23.10 0.31 0.00209 -0.01716 4 3 1 5 0 3512.760 26.73 20.01 23.10 9.19 37.3 972.92 111386 653 31593 49335 -694 64707 -54860 -14309 11166 -22480 -1302 -2198 7467 14861 -25541 -9270 17445 -7991 5901 -8769 22689 -398 17816 2160 -720 -10097 4686 19614 5398 -3660 3036 6785 -13400 -3908 836 1535 6603 -2350 1817 -3669 -2048 -606 -1503 -746 1862 1201 4134 -3770 -289 339 3879 -674 2417 3120 -77 1618 -45 1207 -2684 955 -1019 768 2170 -909 392 1190 -2613 -1327 -489 3310 520 124 -125 1663 -1055 445 -1328 -481 -586 -757 -474 -181 -2895 -2176 -354 -444 751 912 92 497 1028 658 -791 265 1157 552 1353 1250 -446 342 -2466 -546 -970 -488 -945 -468 -805 -335 -272 -236 46 158 490 -184 -54 1176 793 940 573 -269 -230 -425 566 770 412 15 -353 1406 476 -255 286 -648 -751 -204 -337 -782 510 -23 -42 542 -49 -251 1388 23 850 1079 -23 1209 -3238 -652 439 -1255 -63 -121 440 960 -2739 -944 1495 -915 623 -1094 2155 -48 1901 284 -102 -1594 637 2250 703 -548 474 1131 -2861 -768 155 295 1360 -615 534 -1269 -750 -229 -585 -291 714 464 1558 -1533 -117 143 1693 -327 1209 1624 -42 899 -26 671 -1521 531 -603 482 1439 -642 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