File name: Pandora169s1_Egbert_20230202_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241103T205007.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v3d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20230202_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230202T155150.4Z 8433.660999 347 1 49.71 2 65.20 153.27 108.61 9.14 0.00 1 0.00 1 0 17 2.063e-02 6.893e-03 9.098e-03 1.708e-03 3.601645e-01 8.952982e-04 4.412927e-03 -6.000000e+00 1.233802e-02 224.06 -2.00 3.58 -2.00 318.04 0.00e+00 8.409762e-04 1.559686e-04 1.751910e-04 -6.000000e+00 5.261943e-04 271.01 -2.00 20.00 -2.00 317.54 0.00e+00 2.369 0.000 302.00 328.00 3 4.7559e+00 2.3699e-03 2.9522e-02 -6.0000e+00 3.0487e-02 5.1821e-02 2.6716e-03 1.8606e-02 -6.0000e+00 3.3117e-02 4.5570e-03 1.7638e-03 9.3741e-03 -6.0000e+00 1.9648e-02 -1.1546e-02 9.1461e-04 2.8239e-03 -6.0000e+00 8.3156e-03 2.8462e-04 -3.4947e-04 5.4066e-05 3.5311e-05 -6.0000e+00 6.4383e-04 -3.1445e-03 2.8428e-05 11 8 0 10 0 0 99.97 23.12 0.03 -0.00314 -0.00577 45 10 1 5 0 1104.510 26.73 20.00 23.12 1.18 36.4 942.37 9506 -6922 -2 1455 1731 1467 4429 -6838 -69 -9590 -4734 -7646 1216 3499 3054 -2977 -968 -2130 1093 213 2001 399 1801 -977 -1967 -932 -1304 3220 232 2426 2688 1692 -1997 -4191 -1903 -3785 -1349 -868 -820 -2157 -1147 -14 -693 -1360 682 -574 -170 -546 -437 815 954 1124 1258 1637 165 1076 367 557 -343 495 1289 1995 1832 1664 -731 584 -427 -494 1282 937 362 532 355 265 -268 -372 -1319 -1004 -366 -1391 -1253 -1987 -2095 -1065 -561 19 447 384 378 490 705 336 -7 624 776 170 690 568 -380 -452 -976 -1259 -258 92 -1724 -905 -490 -623 300 559 298 325 221 174 57 548 184 39 293 -212 -59 97 259 441 555 -238 531 1299 328 -112 -214 -467 -20 269 -173 -265 285 227 -68 30 -161 -874 496 -446 0 83 93 80 254 -480 -5 -776 -382 -693 117 382 380 -426 -145 -338 176 36 334 69 319 -188 -399 -191 -264 604 44 470 566 391 -505 -1081 -473 -988 -383 -285 -310 -916 -516 -6 -330 -656 325 -276 -81 -261 -211 404 500 624 733 989 103 683 236 354 -218 316 852 1397 1363 1279 -564 429 -309 -366 1006 794 322 480 316 226 -216 -280 -956 -733 -285 -1195 -1165 -1977 -2181 -1148 -629 22 532 461 449 561 766 346 -7 636 839 199 864 749 -513 -597 -1235 -1523 -306 113 -2218 -1198 -669 -882 442 855 468 510 338 256 80 756 258 57 440 -326 -91 146 383 634 774 -324 714 1788 477 -170 -336 -749 -32 453 -303 -473 514 412 -123 53 -279 -1488 SS 20230202T155832.3Z 8433.665651 352 1 50.56 2 64.67 154.94 108.41 10.63 0.00 1 0.00 1 0 25 3.103e-02 8.584e-03 1.193e-02 2.362e-03 3.550398e-01 1.239275e-03 4.367722e-03 -6.000000e+00 1.855347e-02 224.06 -2.00 3.58 -2.00 317.92 0.00e+00 1.139795e-03 2.085606e-04 2.437232e-04 -6.000000e+00 7.913936e-04 271.01 -2.00 20.00 -2.00 317.43 0.00e+00 2.323 0.000 302.00 328.00 3 5.4459e+00 3.2722e-03 2.9019e-02 -6.0000e+00 4.5844e-02 7.6574e-02 3.6836e-03 1.8338e-02 -6.0000e+00 4.9804e-02 -1.4489e-03 2.3994e-03 9.2553e-03 -6.0000e+00 2.9549e-02 -8.6953e-03 1.2386e-03 2.8254e-03 -6.0000e+00 1.2503e-02 1.4804e-04 -7.1148e-04 7.4582e-05 3.5132e-05 -6.0000e+00 9.6852e-04 -2.6151e-03 -1.8943e-05 11 8 0 10 0 0 99.98 23.13 0.13 -0.00262 -0.00796 18 4 1 5 0 2808.210 26.73 20.00 23.13 1.48 36.5 944.32 7017 -11119 1221 1240 -144 15541 10832 -12248 549 -11856 -2476 -9438 2748 3086 1949 -5683 2796 -4123 100 -1852 5272 1788 1074 -2909 -3500 -2259 -1083 8121 630 2799 1646 3650 -3121 -4764 -2090 -2631 -1451 -2410 -924 -2469 -841 -347 -575 -732 917 655 476 -511 -953 881 438 -247 1375 2921 390 1710 634 270 -479 500 929 1865 2550 2289 -806 634 -1131 -69 1022 1613 823 843 445 514 -957 -331 -1616 -1330 -986 -1851 -1152 -2325 -2408 -1543 -554 -91 787 178 747 136 627 507 -344 -271 894 327 859 503 -302 -151 -1243 -1567 -358 -58 -1619 -1069 -784 -356 857 839 590 491 347 209 -305 134 -72 56 38 -55 163 299 601 738 537 -414 259 1157 67 -201 -368 -417 -246 630 111 -158 487 367 -270 86 -704 -859 402 -802 79 76 -8 795 625 -963 41 -1042 -208 -925 278 360 261 -888 430 -710 17 -336 908 322 203 -600 -759 -493 -230 1531 125 566 366 869 -834 -1291 -543 -709 -430 -833 -363 -1091 -391 -167 -283 -363 451 322 234 -252 -476 450 237 -143 821 1793 250 1107 416 176 -311 326 629 1335 1926 1787 -634 474 -837 -52 816 1380 740 770 401 445 -786 -252 -1189 -985 -779 -1610 -1080 -2339 -2533 -1682 -626 -107 943 216 890 157 685 525 -348 -279 969 383 1076 666 -408 -200 -1578 -1903 -425 -71 -2084 -1417 -1073 -502 1255 1279 924 769 529 305 -429 184 -101 80 57 -84 249 448 883 1053 744 -561 346 1581 97 -304 -573 -663 -399 1050 192 -279 868 660 -484 151 -1206 -1445 SS 20230202T160331.4Z 8433.669113 355 1 34.57 2 64.30 156.19 108.25 11.74 0.00 1 0.00 1 0 17 1.686e-02 6.982e-03 5.561e-03 1.346e-03 3.450406e-01 7.066003e-04 4.254638e-03 -6.000000e+00 1.008625e-02 224.06 -2.00 3.58 -2.00 317.64 0.00e+00 8.377795e-04 1.100963e-04 1.617823e-04 -6.000000e+00 4.301453e-04 271.01 -2.00 20.00 -2.00 317.15 0.00e+00 2.292 0.000 302.00 328.00 3 4.1108e+00 1.8574e-03 2.8445e-02 -6.0000e+00 2.4923e-02 4.1115e-02 2.0849e-03 1.7808e-02 -6.0000e+00 2.7072e-02 -5.7140e-03 1.3176e-03 8.9482e-03 -6.0000e+00 1.6062e-02 -5.0883e-03 6.6970e-04 2.6759e-03 -6.0000e+00 6.7983e-03 6.0152e-04 -3.9197e-04 4.2467e-05 3.4015e-05 -6.0000e+00 5.2627e-04 -3.3505e-03 3.9134e-05 12 9 1 12 9 1 99.95 23.15 0.13 -0.00335 -0.00630 43 13 1 5 0 781.630 26.73 20.00 23.15 1.61 36.4 944.99 3916 -4198 -5337 -3069 -2902 -4787 -3996 -4457 -4982 -7086 -5663 -3985 -1682 399 185 -359 -2297 399 484 2014 952 1691 906 576 -537 -291 -487 1136 -1368 2377 2236 2065 -552 -3089 -2898 -2161 -1512 -683 -613 -1174 -969 -301 -287 -729 452 -741 48 -89 -338 1174 1073 900 1276 1210 602 1270 541 -299 -8 254 988 1671 1882 1185 -469 -229 -281 28 1548 1192 394 286 506 401 -147 -321 -924 -1086 -338 -1334 -1273 -2014 -2447 -1097 -913 -186 303 94 408 293 538 272 231 648 448 545 733 524 -402 -526 -1066 -1219 -50 176 -1564 -1173 -807 -583 327 583 551 195 291 144 395 405 269 324 175 -182 -290 239 394 720 660 -48 593 1246 325 293 -339 -257 -229 99 -206 -253 182 137 -284 12 -392 -568 279 -343 -440 -234 -209 -354 -317 -393 -476 -716 -586 -443 -210 56 29 -62 -429 76 96 406 196 351 197 132 -130 -71 -118 261 -316 549 560 560 -161 -922 -848 -648 -497 -256 -263 -556 -487 -156 -151 -389 240 -396 26 -47 -180 638 614 544 803 790 403 863 371 -205 -5 174 699 1245 1477 961 -379 -178 -214 22 1265 1045 363 267 466 356 -124 -253 -702 -832 -274 -1182 -1214 -2044 -2593 -1199 -1038 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