File name: Pandora169s1_Egbert_20230415_L2Fit_fout2c15d20220511p1-8.txt File generation date: 20241103T231832.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 169 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora169_OF_v5d20200220.txt Instrument calibration file used: Pandora169s1_CF_v15d20220511.txt Level 1 file used: Pandora169s1_Egbert_20230415_L1_smca1c15d20220511p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20230415 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 228 369 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2750 305.4159 305.5568 305.6976 305.8385 305.9793 306.1201 306.2609 306.4017 306.5425 306.6833 306.8241 306.9648 307.1056 307.2463 307.3870 307.5277 307.6684 307.8091 307.9498 308.0904 308.2311 308.3717 308.5123 308.6529 308.7935 308.9341 309.0747 309.2153 309.3558 309.4964 309.6369 309.7774 309.9180 310.0585 310.1989 310.3394 310.4799 310.6203 310.7608 310.9012 311.0416 311.1820 311.3224 311.4628 311.6032 311.7436 311.8839 312.0243 312.1646 312.3049 312.4452 312.5855 312.7258 312.8661 313.0063 313.1466 313.2868 313.4270 313.5672 313.7074 313.8476 313.9878 314.1280 314.2681 314.4083 314.5484 314.6885 314.8286 314.9687 315.1088 315.2489 315.3890 315.5290 315.6691 315.8091 315.9491 316.0891 316.2291 316.3691 316.5091 316.6490 316.7890 316.9289 317.0688 317.2088 317.3487 317.4885 317.6284 317.7683 317.9082 318.0480 318.1878 318.3277 318.4675 318.6073 318.7470 318.8868 319.0266 319.1663 319.3061 319.4458 319.5855 319.7252 319.8649 320.0046 320.1443 320.2839 320.4236 320.5632 320.7029 320.8425 320.9821 321.1217 321.2612 321.4008 321.5404 321.6799 321.8194 321.9590 322.0985 322.2380 322.3775 322.5169 322.6564 322.7959 322.9353 323.0747 323.2141 323.3535 323.4929 323.6323 323.7717 323.9110 324.0504 324.1897 324.3291 324.4684 324.6077 324.7470 324.8862 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230415T111916.8Z 8505.471722 107 1 49.90 2 83.20 82.97 70.83 145.99 0.00 1 0.00 1 0 17 5.725e-01 2.794e-02 3.108e-01 1.204e-02 8.946167e-01 7.385702e-03 1.016067e-02 -6.000000e+00 3.561730e-01 228.06 -2.00 3.58 -2.00 322.05 0.00e+00 1.406636e-02 3.945742e-03 1.439779e-03 -6.000000e+00 1.639178e-02 276.70 -2.00 20.00 -2.00 321.61 0.00e+00 7.722 0.009 302.00 328.00 3 2.0027e+00 2.7059e-02 9.1292e-02 -6.0000e+00 8.8821e-01 9.8662e-01 3.6340e-02 5.6459e-02 -6.0000e+00 9.6708e-01 -1.3205e+00 3.3953e-02 2.9224e-02 -6.0000e+00 5.6585e-01 5.4035e-01 1.6008e-02 1.7222e-02 -6.0000e+00 2.3940e-01 1.5464e-05 -1.6895e-03 3.6498e-04 2.7582e-04 -6.0000e+00 1.8929e-02 4.6840e-03 -1.3517e-04 12 8 8 10 0 0 74.00 22.93 0.48 0.00468 -0.00801 28 6 1 5 0 1780.570 26.51 19.99 22.93 18.30 38.6 1041.17 900000 -76549 900000 900000 277009 900000 900000 -12095 -83284 -120029 6903 -147529 900000 176656 900000 -83251 -66144 41007 -24222 -10364 54569 2889 -57495 -38511 -98825 -56752 -39480 900000 5168 900000 33060 900000 -78238 79704 900000 19070 44387 114364 -57143 210252 24515 118618 52658 73769 116841 23633 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-3104 -56 -4050 -909 282 -1459 -3047 -2439 -1589 -3524 1203 -352 991 -1037 -5266 -4745 -2440 -39 2495 -753 2044 -2813 948 1227 4824 3575 2660 1181 1977 -911 1658 3768 4623 168 -1386 -1799 508 -2100 2201 3529 817 919 -901 -1601 -948 -2723 -2174 SS 20230415T113015.8Z 8505.479350 110 1 49.04 2 81.24 84.86 69.76 148.42 0.00 1 0.00 1 0 17 5.920e-01 1.235e-02 1.809e-01 3.600e-03 7.712166e-01 2.066933e-03 8.995789e-03 -6.000000e+00 3.614090e-01 228.06 -2.00 3.58 -2.00 321.51 0.00e+00 7.525808e-03 1.035735e-03 3.418063e-03 -6.000000e+00 1.571708e-02 276.70 -2.00 20.00 -2.00 321.05 0.00e+00 6.210 0.005 302.00 328.00 3 1.7514e+00 7.1182e-03 7.4705e-02 -6.0000e+00 8.9916e-01 1.8654e-01 1.0124e-02 4.5758e-02 -6.0000e+00 9.7400e-01 -3.0474e-01 1.0700e-02 2.8558e-02 -6.0000e+00 5.7615e-01 1.2326e-01 5.0165e-03 1.2156e-02 -6.0000e+00 2.4197e-01 1.0611e-04 -1.2992e-03 1.0786e-04 1.9639e-04 -6.0000e+00 1.8829e-02 4.5837e-03 -1.2801e-04 12 8 8 10 0 0 30.34 22.92 0.29 0.00458 -0.00518 93 20 1 5 0 527.230 26.51 20.00 22.92 19.49 38.4 1047.74 -159511 -183163 -231120 -62770 -201521 900000 -174324 -211551 -195685 -189889 -169159 -181242 -96542 142911 -97505 -39871 -99474 -11234 -62923 20325 -14268 35258 -76196 -67151 -87554 -10884 -61937 900000 -32953 114601 -4033 30883 -39337 -16718 8628 -12068 -16559 -10744 -15957 -182 8841 4176 3693 4974 13375 -1984 14148 9004 11820 6228 11915 4599 7055 9006 4689 7984 10887 1080 -441 1702 5373 4677 9512 7831 7613 7987 3359 2005 5699 5062 5026 804 1438 1373 900 1473 -1342 -1960 1814 -1752 1527 -1141 -1681 -460 -1664 107 1051 59 421 176 201 -523 -923 -2025 -194 -1400 -287 -212 -787 -391 -1506 -1953 -768 -580 -2885 -905 -1048 -414 -43 304 -161 184 -189 -194 -322 771 -108 804 301 688 651 1261 1599 958 643 -2382 836 1586 125 -104 -295 -191 -300 39 45 -66 215 386 -137 100 -471 -795 -1080 -1749 -3562 -220 -2195 900000 -1618 -3048 -2634 -2604 -2164 -3212 -1026 501 -1688 -478 -2336 -129 -1247 194 -191 303 -1924 -1660 -2725 -174 -1587 900000 -715 740 -96 630 -1659 -592 243 -429 -690 -501 -914 -10 506 265 246 337 868 -153 989 699 962 585 1185 538 879 1180 667 1140 1526 163 -67 257 845 828 1817 1656 1667 1757 794 518 1593 1576 1658 279 480 428 259 394 -368 -588 610 -711 689 -586 -934 -269 -1039 69 697 40 278 112 121 -308 -557 -1344 -144 -1209 -278 -225 -873 -423 -1537 -1850 -694 -539 -2872 -932 -1148 -488 -56 432 -246 290 -298 -299 -482 1136 -165 1264 492 1126 1043 1947 2398 1407 922 -3433 1198 2443 215 -197 -596 -408 -670 91 109 -165 544 979 -344 241 -1087 -1779 SS 20230415T114335.7Z 8505.488608 115 1 48.87 2 78.86 87.15 68.56 151.44 0.00 1 0.00 1 0 17 2.870e-01 6.384e-03 5.608e-02 1.419e-03 6.477832e-01 7.846298e-04 7.476906e-03 -6.000000e+00 1.740478e-01 228.06 -2.00 3.58 -2.00 320.74 0.00e+00 4.070335e-03 3.220600e-04 1.149533e-03 -6.000000e+00 7.493973e-03 276.70 -2.00 20.00 -2.00 320.24 0.00e+00 4.996 0.002 302.00 328.00 3 1.4312e+00 2.4402e-03 5.9872e-02 -6.0000e+00 4.3316e-01 8.2266e-03 3.1948e-03 3.5596e-02 -6.0000e+00 4.6900e-01 -2.9160e-02 3.2250e-03 1.9972e-02 -6.0000e+00 2.7833e-01 6.3259e-04 1.5872e-03 7.9851e-03 -6.0000e+00 1.1721e-01 5.1031e-04 -9.1736e-04 4.3157e-05 1.0110e-04 -6.0000e+00 8.9746e-03 3.9577e-03 -1.0450e-04 10 0 0 10 0 0 -2.66 22.92 0.24 0.00396 -0.00294 233 50 1 5 0 209.690 26.51 19.99 22.92 20.94 38.5 1055.75 -68301 -118501 -107419 -82752 -106973 -92706 -66491 -114534 -75458 -102497 -65406 -82222 -45464 -36782 -16253 -31566 -30038 -28657 -11151 -16135 -9126 -2192 -20401 -17334 -18225 -12779 -20550 7538 -13570 2230 1913 877 -10514 -9073 -6801 -8105 -7668 -2035 -4533 -1850 -2726 1289 75 -679 1719 -746 2401 1176 954 1465 1666 2746 1330 2691 1020 2633 413 -448 -389 1505 1745 2943 3666 2564 1007 1338 769 1025 2094 1495 1073 437 -150 696 -1148 -951 -1160 -624 -107 -1026 -665 -1756 -2278 -1291 -597 -54 501 249 626 376 472 -84 -507 -72 267 -23 870 566 -324 -365 -602 -1075 78 79 -1596 -1178 -697 -568 380 356 249 121 12 -30 -33 603 390 341 332 -89 123 347 629 392 301 -1046 429 1020 239 -110 -483 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