File name: Pandora280s1_Eureka-0PAL_20240904_L2Fit_fout2c2d20240201p1-8.txt File generation date: 20240905T055114.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Kimberly Strong Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 280 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora280_OF_v3d20230919.txt Instrument calibration file used: Pandora280s1_CF_v2d20240201.txt Level 1 file used: Pandora280s1_Eureka-0PAL_20240904_L1_smca1c2d20240201p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) 0PAL facility Short location name: Eureka-0PAL Country of location: Canada Location latitude [deg]: 79.9903 Location longitude [deg]: -85.9389 Location altitude [m]: 14 Local noon date: 20240904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0551 305.1959 305.3368 305.4776 305.6183 305.7591 305.8999 306.0406 306.1814 306.3221 306.4629 306.6036 306.7443 306.8850 307.0256 307.1663 307.3070 307.4476 307.5882 307.7288 307.8695 308.0101 308.1506 308.2912 308.4318 308.5723 308.7129 308.8534 308.9939 309.1344 309.2749 309.4154 309.5559 309.6963 309.8368 309.9772 310.1177 310.2581 310.3985 310.5389 310.6793 310.8196 310.9600 311.1003 311.2407 311.3810 311.5213 311.6616 311.8019 311.9422 312.0824 312.2227 312.3629 312.5032 312.6434 312.7836 312.9238 313.0640 313.2042 313.3443 313.4845 313.6246 313.7647 313.9049 314.0450 314.1851 314.3251 314.4652 314.6053 314.7453 314.8854 315.0254 315.1654 315.3054 315.4454 315.5854 315.7253 315.8653 316.0052 316.1452 316.2851 316.4250 316.5649 316.7048 316.8447 316.9845 317.1244 317.2642 317.4040 317.5439 317.6837 317.8235 317.9632 318.1030 318.2428 318.3825 318.5223 318.6620 318.8017 318.9414 319.0811 319.2208 319.3604 319.5001 319.6397 319.7793 319.9190 320.0586 320.1982 320.3378 320.4773 320.6169 320.7564 320.8960 321.0355 321.1750 321.3145 321.4540 321.5935 321.7329 321.8724 322.0118 322.1513 322.2907 322.4301 322.5695 322.7089 322.8483 322.9876 323.1270 323.2663 323.4056 323.5449 323.6843 323.8235 323.9628 324.1021 324.2413 324.3806 324.5198 324.6590 324.7982 324.9374 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240904T132915.9Z 9013.561990 360 1 53.20 2 78.75 115.22 87.74 101.10 0.00 1 0.00 1 0 25 4.213e-01 1.232e-02 3.728e-02 1.434e-03 6.633006e-01 7.419022e-04 1.195882e-02 -6.000000e+00 2.402702e-01 229.07 -2.00 5.56 -2.00 320.43 0.00e+00 2.974797e-03 2.553678e-04 9.074289e-04 -6.000000e+00 9.985674e-03 268.19 -2.00 20.00 -2.00 320.00 0.00e+00 4.948 0.004 302.00 328.00 3 1.4479e+00 2.1721e-03 7.5124e-02 -6.0000e+00 6.0178e-01 1.1793e-01 2.7157e-03 5.5677e-02 -6.0000e+00 6.5446e-01 -1.8470e-01 2.7051e-03 2.8897e-02 -6.0000e+00 3.8616e-01 7.8640e-02 1.3829e-03 9.1128e-03 -6.0000e+00 1.6186e-01 4.5014e-04 -1.1048e-03 3.7915e-05 9.9850e-05 -6.0000e+00 1.1233e-02 -3.2268e-03 -2.7729e-04 12 8 8 10 0 0 99.61 26.01 0.37 -0.00323 -0.01153 133 17 1 5 0 399.920 33.75 20.00 26.01 11.41 0.0 922.67 -151890 -147567 -54997 -167378 -154238 -173822 -163222 -116727 -117949 -94910 5446 -136582 -93867 -47428 -73135 -43831 -20913 -30425 12340 -17509 -20596 -44826 -19653 -26909 -16530 -17680 -41874 -10933 -41470 5147 -14552 -18786 6445 18370 -6636 -1373 -5196 -9234 -452 2552 3423 4595 4823 2741 7795 1773 2585 5488 7455 5939 7409 5836 8512 8076 4522 2208 3761 1339 2399 3683 1477 2991 3456 5065 3114 2498 1078 2314 223 1729 2041 386 -931 1868 -57 305 -1679 -2392 -3159 -1885 -806 -747 -1166 -1729 -1060 -1311 -1096 -469 181 164 191 946 -778 -414 -671 -704 -195 -454 234 320 -434 -1657 -1114 -997 -1171 -814 -1184 -870 -255 216 343 429 569 181 31 337 66 3 35 156 -72 330 357 630 1179 923 654 767 558 962 660 279 -113 -37 -451 -262 -27 69 -195 -60 -368 -610 -446 -2464 -2703 -431 -3932 -2912 -3889 -3538 -1812 -2095 -1447 32 -3762 -2139 -882 -2229 -1201 -518 -919 264 -534 -665 -1843 -654 -1050 -631 -722 -2213 -413 -2099 176 -724 -1179 367 999 -447 -86 -372 -821 -45 298 448 642 708 422 1159 287 425 909 1270 1101 1370 1234 1929 2002 1235 644 1115 406 699 1039 439 963 1265 1891 1259 997 428 935 102 899 1173 218 -528 1056 -30 143 -748 -1083 -1611 -1130 -519 -552 -883 -1400 -911 -1206 -990 -434 167 146 170 778 -623 -339 -616 -701 -210 -531 299 411 -527 -1942 -1181 -1056 -1339 -984 -1424 -1115 -355 318 531 707 942 291 47 515 102 4 57 264 -121 531 554 994 1777 1343 918 1111 865 1601 1212 522 -222 -74 -926 -567 -60 156 -437 -131 -784 -1219 -898 SS 20240904T134037.1Z 9013.569873 363 1 53.91 2 78.31 118.06 87.32 103.83 0.00 1 0.00 1 0 25 4.452e-01 2.884e-02 1.389e-01 4.652e-03 6.193035e-01 2.428666e-03 1.150903e-02 -6.000000e+00 2.546388e-01 229.07 -2.00 5.56 -2.00 320.74 0.00e+00 5.347437e-03 8.622753e-04 3.920481e-03 -6.000000e+00 1.115487e-02 268.19 -2.00 20.00 -2.00 320.31 0.00e+00 4.777 0.003 302.00 328.00 3 3.5444e+00 7.2662e-03 7.2494e-02 -6.0000e+00 6.3866e-01 3.1445e-01 8.9021e-03 5.4492e-02 -6.0000e+00 6.9572e-01 -5.4595e-01 8.0142e-03 2.9188e-02 -6.0000e+00 4.1004e-01 2.5631e-01 4.0732e-03 9.6264e-03 -6.0000e+00 1.7141e-01 6.6705e-05 -1.9205e-03 1.2944e-04 1.3731e-04 -6.0000e+00 1.1964e-02 -1.7923e-03 -4.0121e-04 12 8 8 10 0 0 99.80 26.05 -0.17 -0.00179 -0.01622 31 4 1 5 0 1738.730 33.75 19.99 26.05 12.14 0.0 926.89 -45263 -53936 51169 -138470 -122343 -152306 -123194 90530 -109086 31497 900000 -143201 -53916 62198 -14040 -34458 31810 17967 900000 96509 69542 -59753 -5479 883 -2336 -17309 -58732 80470 -46229 -1141 5232 -37052 75556 277794 25064 26089 37992 -26876 12143 49789 22483 42886 40905 16948 32346 10729 23433 20675 35729 29175 26804 10857 32227 32126 10941 -2299 18770 -2003 5549 18635 -394 13778 12071 8507 1944 7507 8005 16313 -1030 5879 5635 -4280 -6636 7381 1937 8832 4016 -9177 -9472 -9089 -1163 2738 7 -1194 1856 -863 -5569 -2315 -1185 -3379 62 2460 -3947 -3076 -3047 -3669 -1314 1055 -484 148 -1274 -3883 -1064 -3026 -1541 36 -3265 -1306 158 -25 -98 -485 615 -1199 468 1052 830 -26 490 1181 502 2747 2783 1087 2382 2408 301 986 482 2198 774 906 -555 230 -1275 -389 627 578 -216 -526 -1925 -1181 -619 -877 -1290 443 -7478 -4943 -7723 -4774 493 -4272 343 900000 -8915 -1858 846 -503 -1766 923 644 900000 1707 1608 -4878 -261 41 -118 -1036 -5274 1715 -3396 -56 282 -3596 2707 1386 1478 1467 2033 -3206 1178 3884 2549 4201 4248 2275 3741 1562 3039 2813 4310 3956 4072 2142 5568 5959 2625 -648 4358 -566 1404 4048 -106 3530 3558 2909 746 2645 2719 5186 -426 2610 2514 -2198 -3450 3464 876 3336 1472 -3841 -4411 -4538 -628 1620 5 -852 1370 -700 -4991 -2073 -1050 -2957 49 1764 -2868 -2258 -2487 -3489 -1296 1165 -595 182 -1496 -4213 -1117 -3251 -1613 39 -3894 -1631 212 -38 -152 -796 1000 -1916 694 1600 1268 -38 773 1941 831 4287 4182 1607 3617 3519 432 1442 733 3710 1452 1802 -1086 472 -2839 -905 1475 1289 -485 -1225 -4271 -2435 -1218 SS 20240904T143538.4Z 9013.608084 392 1 13.86 2 76.37 131.92 85.35 117.13 0.00 1 0.00 1 0 17 5.504e-01 2.554e-02 2.235e-01 8.549e-03 5.448892e-01 4.427917e-03 1.013415e-02 -6.000000e+00 3.147233e-01 229.06 -2.00 5.56 -2.00 320.21 0.00e+00 4.076359e-03 1.403604e-03 3.379975e-03 -6.000000e+00 1.435275e-02 268.18 -2.00 20.00 -2.00 319.78 0.00e+00 4.143 0.002 302.00 328.00 3 3.9823e+00 1.2752e-02 6.2766e-02 -6.0000e+00 7.8995e-01 1.3760e-01 1.5344e-02 4.6836e-02 -6.0000e+00 8.5944e-01 -2.6027e-01 1.3701e-02 2.5714e-02 -6.0000e+00 5.0547e-01 1.2752e-01 7.0862e-03 9.1297e-03 -6.0000e+00 2.1458e-01 8.6331e-05 9.7716e-04 2.4022e-04 1.1495e-04 -6.0000e+00 1.4894e-02 -1.7199e-02 -2.4026e-04 12 9 9 12 9 1 31.54 26.02 0.30 -0.01720 -0.00986 3 2 1 5 0 3464.720 33.75 20.00 26.02 9.46 0.1 914.44 900000 -71734 125004 -137755 -110396 25298 -155192 170274 -78994 900000 900000 -129135 -46189 139812 -16841 -30625 43774 12013 407487 56073 30305 -67077 35084 -36002 -1058 41909 -36079 26489 -60383 122655 25154 -32322 32683 197951 2023 4029 46407 -4635 11866 24409 25737 24560 17399 2832 25556 2956 14303 15460 11876 21323 18768 7896 10739 15724 3038 -2893 8433 -3006 -2849 8898 -2336 1662 10687 5261 1219 2329 1003 8052 980 2225 3637 -3186 -6222 3882 1611 6355 -750 -5668 -8081 -8910 -564 2145 795 -3291 1143 -1319 -2702 -867 -723 -5011 1334 2739 -1060 -2800 36 -2421 344 4294 -431 -1080 -1250 -2985 -38 -2238 -1222 -472 -1907 -680 -288 136 -4 -34 904 -86 -76 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