File name: Pandora280s1_Eureka-0PAL_20241004_L2Fit_fwvt1c2d20240201p1-8.txt File generation date: 20241005T054134.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Kimberly Strong Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 280 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora280_OF_v3d20230919.txt Instrument calibration file used: Pandora280s1_CF_v2d20240201.txt Level 1 file used: Pandora280s1_Eureka-0PAL_20241004_L1_smca1c2d20240201p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) 0PAL facility Short location name: Eureka-0PAL Country of location: Canada Location latitude [deg]: 79.9903 Location longitude [deg]: -85.9389 Location altitude [m]: 14 Local noon date: 20241004 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1623 1772 Nominal wavelengths inside fitting window [nm]: 492.1190 492.2398 492.3605 492.4813 492.6020 492.7227 492.8434 492.9641 493.0847 493.2054 493.3260 493.4466 493.5672 493.6878 493.8084 493.9289 494.0494 494.1699 494.2904 494.4109 494.5314 494.6518 494.7722 494.8926 495.0130 495.1334 495.2538 495.3741 495.4944 495.6147 495.7350 495.8553 495.9756 496.0958 496.2160 496.3362 496.4564 496.5766 496.6967 496.8169 496.9370 497.0571 497.1772 497.2973 497.4173 497.5374 497.6574 497.7774 497.8974 498.0173 498.1373 498.2572 498.3771 498.4970 498.6169 498.7368 498.8566 498.9765 499.0963 499.2161 499.3359 499.4556 499.5754 499.6951 499.8148 499.9345 500.0542 500.1739 500.2935 500.4132 500.5328 500.6524 500.7719 500.8915 501.0110 501.1306 501.2501 501.3696 501.4890 501.6085 501.7279 501.8474 501.9668 502.0862 502.2055 502.3249 502.4442 502.5636 502.6829 502.8022 502.9214 503.0407 503.1599 503.2791 503.3983 503.5175 503.6367 503.7558 503.8750 503.9941 504.1132 504.2323 504.3513 504.4704 504.5894 504.7084 504.8274 504.9464 505.0654 505.1843 505.3032 505.4221 505.5410 505.6599 505.7788 505.8976 506.0164 506.1352 506.2540 506.3728 506.4916 506.6103 506.7290 506.8477 506.9664 507.0851 507.2037 507.3224 507.4410 507.5596 507.6782 507.7967 507.9153 508.0338 508.1523 508.2708 508.3893 508.5077 508.6262 508.7446 508.8630 508.9814 509.0998 509.2181 509.3365 509.4548 509.5731 509.6914 509.8097 509.9279 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241004T141617.3Z 9043.594644 210 1 13.93 2 88.10 131.18 100.79 115.35 0.00 1 0.00 1 0 22 4.275e-03 4.297e-03 1.568e-03 1.564e-03 9.114512e+03 9.824812e+01 6.517904e+02 -6.000000e+00 2.211314e+02 261.35 -2.00 20.00 -2.00 505.36 0.00e+00 8.038046e-04 4.147505e-05 6.552317e-05 -6.000000e+00 1.146791e-04 261.35 -2.00 20.00 -2.00 500.86 0.00e+00 1.129743e+00 3.086983e-02 7.484641e-02 -6.000000e+00 8.634682e-02 221.60 -2.00 5.56 -2.00 502.40 0.00e+00 16.413 0.146 489.00 513.00 1 4.9721e+00 2.3435e-03 3.2069e-02 -6.0000e+00 6.5723e-03 -3.1357e-02 5.9779e-04 2.5180e-03 -6.0000e+00 1.7234e-03 1.1857e-03 2.2239e-03 1.5406e-04 1.0579e-04 -6.0000e+00 4.5381e-04 -2.1487e-02 -3.2723e-04 12 9 1 12 1 1 -56.32 26.06 2.17 -0.02149 -0.00606 4 2 1 4 0 2785.420 34.00 20.00 26.06 3.46 0.5 885.73 419 267 -44 -135 565 143 475 262 240 281 835 168 -21 -202 192 395 434 -172 -362 -84 -349 290 433 392 171 68 -184 -236 -13 341 588 462 254 -325 -795 -302 -56 -3 -89 183 -351 -76 297 234 -79 -91 -268 -305 -959 -708 -328 -271 68 426 -341 -709 -611 -102 -19 310 760 273 -149 4 -176 51 184 128 15 -184 68 325 -216 -250 -839 -819 -239 398 -364 447 -193 -257 -401 -7 -313 -784 -323 -393 266 279 165 -186 -344 -641 -310 282 163 -416 -320 -418 -188 72 131 -574 -1626 -632 -689 237 432 562 -153 -210 -156 1019 1110 853 502 25 140 -147 674 597 1163 477 39 -16 432 454 375 -219 -361 -469 184 96 163 541 -102 -139 -118 220 -31 -53 183 192 -105 -728 -498 -5 368 387 379 240 -40 -127 535 139 460 257 236 273 798 160 -20 -193 182 376 412 -169 -357 -84 -351 291 435 388 171 68 -184 -234 -13 328 566 447 247 -321 -796 -304 -56 -3 -89 183 -353 -75 296 237 -81 -92 -271 -311 -968 -697 -320 -264 66 412 -334 -704 -621 -103 -19 312 762 276 -152 4 -179 51 182 128 15 -180 66 316 -214 -246 -836 -814 -237 387 -353 429 -187 -251 -396 -7 -310 -788 -325 -388 266 280 164 -187 -351 -655 -311 280 157 -401 -301 -397 -178 68 125 -566 -1648 -646 -705 239 432 563 -157 -214 -160 1044 1144 888 520 27 147 -154 689 612 1177 486 40 -16 440 463 383 -225 -370 -475 186 97 165 553 -106 -144 -124 231 -33 -57 197 205 -113 -783 -538 -6 389 407 SQ 20241004T141854.5Z 9043.596464 214 1 37.51 2 88.02 131.83 100.70 115.97 0.00 1 0.00 1 0 22 3.709e-03 3.719e-03 1.920e-04 1.917e-04 9.177159e+03 1.205212e+01 6.529986e+02 -6.000000e+00 1.918312e+02 261.35 -2.00 20.00 -2.00 505.36 0.00e+00 7.276782e-04 5.083087e-06 6.428049e-05 -6.000000e+00 9.945100e-05 261.35 -2.00 20.00 -2.00 500.83 0.00e+00 1.131514e+00 3.793595e-03 7.632799e-02 -6.000000e+00 7.484997e-02 221.60 -2.00 5.56 -2.00 502.36 0.00e+00 16.181 0.140 489.00 513.00 1 2.0850e+00 2.8807e-04 3.1283e-02 -6.0000e+00 5.6979e-03 -2.5150e-02 7.3581e-05 2.5054e-03 -6.0000e+00 1.4926e-03 2.1996e-02 3.5094e-04 1.8862e-05 1.0623e-04 -6.0000e+00 3.9376e-04 1.2520e-02 -4.5870e-04 12 1 1 12 1 1 90.78 26.06 1.93 0.01252 0.01495 224 40 1 4 0 166.680 33.75 20.00 26.06 3.50 0.5 885.48 626 279 -87 -251 239 439 253 29 -16 185 268 81 0 74 186 325 403 9 -421 -221 79 262 379 248 76 96 -65 -492 -358 429 648 652 485 -312 -922 -572 -152 38 84 194 152 95 95 14 -165 -222 -131 -160 -385 -546 -274 3 321 440 -48 -560 -714 -416 -9 338 419 212 -98 -244 -242 4 272 102 -225 -110 174 117 45 -358 -790 -693 -121 229 104 46 -73 -222 -213 -50 -256 -402 -346 -113 88 262 407 98 -473 -636 -300 -5 84 -138 -359 -260 119 325 -76 -827 -1335 -981 -441 248 700 489 77 -110 -13 223 614 853 567 88 -101 -41 287 645 874 494 36 56 117 178 275 -62 -414 -56 318 374 568 367 -104 -174 1 8 -57 88 122 58 -168 -481 -577 -217 243 312 566 255 -81 -237 229 425 248 28 -16 181 262 79 0 71 178 312 389 8 -417 -222 79 261 379 249 77 96 -65 -495 -356 417 626 633 472 -313 -935 -584 -154 39 85 193 152 95 96 14 -169 -227 -133 -162 -386 -541 -270 3 308 425 -47 -559 -723 -421 -9 341 423 216 -100 -248 -244 4 272 101 -222 -108 170 114 44 -357 -789 -689 -119 224 101 45 -70 -217 -209 -50 -254 -399 -345 -112 87 259 406 99 -477 -642 -301 -5 82 -132 -342 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216 -125 -223 240 437 275 13 -20 187 252 75 21 97 193 362 411 20 -402 -228 100 240 358 252 84 66 -95 -515 -384 381 664 617 424 -300 -873 -612 -119 51 126 214 177 105 102 -6 -182 -191 -106 -118 -347 -501 -282 -9 295 375 -103 -572 -670 -415 -16 338 430 231 -56 -186 -226 55 237 67 -215 -132 136 122 13 -351 -762 -688 -117 254 107 -12 -105 -276 -207 -23 -232 -396 -320 -110 102 262 411 83 -466 -644 -297 -14 30 -140 -374 -204 176 325 -59 -812 -1355 -959 -404 245 693 500 66 -121 -28 196 627 843 583 102 -101 -6 260 622 856 486 60 73 110 173 304 -98 -430 -78 313 383 553 393 -98 -198 -3 22 -33 115 93 58 -175 -458 -569 -262 252 287 510 199 -116 -213 232 427 271 13 -20 183 246 73 20 92 184 347 395 20 -401 -228 100 241 357 252 85 67 -96 -516 -380 369 639 597 416 -300 -882 -624 -120 51 126 213 176 105 103 -6 -186 -196 -109 -119 -350 -500 -276 -9 285 361 -101 -569 -676 -419 -16 340 433 234 -57 -189 -230 55 237 66 -213 -129 134 119 13 -348 -757 -681 -115 248 105 -12 -101 -269 -201 -23 -229 -395 -317 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