File name: Pandora280s1_Eureka-0PAL_20250308_L2Fit_fwvt1c3d20240808p1-8.txt File generation date: 20250718T121304.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Kimberly Strong Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 280 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora280_OF_v3d20230919.txt Instrument calibration file used: Pandora280s1_CF_v3d20240808.txt Level 1 file used: Pandora280s1_Eureka-0PAL_20250308_L1_smca1c3d20240808p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) 0PAL facility Short location name: Eureka-0PAL Country of location: Canada Location latitude [deg]: 79.9903 Location longitude [deg]: -85.9389 Location altitude [m]: 14 Local noon date: 20250308 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1623 1773 Nominal wavelengths inside fitting window [nm]: 492.0536 492.1743 492.2950 492.4157 492.5364 492.6570 492.7776 492.8983 493.0189 493.1394 493.2600 493.3806 493.5011 493.6216 493.7421 493.8626 493.9830 494.1035 494.2239 494.3443 494.4647 494.5851 494.7055 494.8258 494.9461 495.0664 495.1867 495.3070 495.4273 495.5475 495.6678 495.7880 495.9082 496.0283 496.1485 496.2686 496.3888 496.5089 496.6290 496.7490 496.8691 496.9891 497.1092 497.2292 497.3492 497.4691 497.5891 497.7090 497.8289 497.9489 498.0687 498.1886 498.3085 498.4283 498.5481 498.6679 498.7877 498.9075 499.0272 499.1470 499.2667 499.3864 499.5061 499.6257 499.7454 499.8650 499.9846 500.1042 500.2238 500.3434 500.4629 500.5825 500.7020 500.8215 500.9410 501.0604 501.1799 501.2993 501.4187 501.5381 501.6575 501.7768 501.8962 502.0155 502.1348 502.2541 502.3734 502.4926 502.6119 502.7311 502.8503 502.9695 503.0887 503.2078 503.3270 503.4461 503.5652 503.6843 503.8033 503.9224 504.0414 504.1604 504.2794 504.3984 504.5174 504.6363 504.7553 504.8742 504.9931 505.1120 505.2308 505.3497 505.4685 505.5873 505.7061 505.8249 505.9437 506.0624 506.1811 506.2998 506.4185 506.5372 506.6558 506.7745 506.8931 507.0117 507.1303 507.2489 507.3674 507.4860 507.6045 507.7230 507.8415 507.9599 508.0784 508.1968 508.3152 508.4336 508.5520 508.6704 508.7887 508.9070 509.0254 509.1436 509.2619 509.3802 509.4984 509.6167 509.7349 509.8530 509.9712 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250308T143951.1Z 9198.611008 369 1 8.22 2 88.00 131.52 72.59 15.41 0.00 1 0.00 1 0 15 3.868e-03 3.885e-03 1.209e-03 1.207e-03 2.547722e+03 6.394718e+01 1.800900e+02 -6.000000e+00 1.907305e+02 250.08 -2.00 20.00 -2.00 505.37 0.00e+00 8.335612e-04 3.100984e-05 5.016722e-05 -6.000000e+00 1.007600e-04 250.08 -2.00 20.00 -2.00 500.96 0.00e+00 1.372989e+00 2.362993e-02 3.374463e-02 -6.000000e+00 7.761698e-02 220.32 -2.00 5.56 -2.00 502.48 0.00e+00 16.273 0.143 489.00 513.00 1 3.6118e+00 1.7926e-03 3.1207e-02 -6.0000e+00 5.9019e-03 -2.7492e-02 4.5659e-04 1.8376e-03 -6.0000e+00 1.5257e-03 4.6403e-03 -1.4339e-03 1.2421e-04 3.8760e-05 -6.0000e+00 4.0835e-04 3.8388e-02 -1.5812e-04 12 9 1 12 1 1 67.04 25.56 2.24 0.03839 0.02844 6 6 1 4 0 1173.010 33.50 19.99 25.56 -24.05 2.4 1041.19 475 22 -31 -349 377 640 235 188 60 86 122 100 -125 93 336 33 389 95 -308 -348 -292 200 533 294 25 77 60 -564 -523 492 607 691 603 -250 -880 -710 -79 81 15 304 93 270 -37 175 -85 -65 117 3 -210 -492 -81 -298 153 378 30 -509 -541 -420 -275 389 426 229 148 -312 -6 -46 450 54 -302 -198 16 214 41 -736 -851 -600 -213 143 -29 -105 -95 -430 -432 15 -233 -361 -488 -90 -58 83 406 266 -444 -419 -310 -141 -200 -204 -175 -70 217 207 128 -935 -1568 -590 -416 169 548 554 127 83 -38 289 472 687 549 253 47 352 682 641 679 329 25 -10 317 195 257 50 -433 -259 150 311 727 510 -89 -296 -173 -108 45 219 432 15 -235 -630 -760 -175 290 345 -248 430 20 -29 -329 357 620 229 186 58 84 118 95 -120 89 318 31 370 91 -305 -345 -292 199 531 296 25 77 59 -559 -516 475 577 658 587 -246 -882 -719 -79 80 15 302 93 270 -37 177 -86 -66 118 3 -210 -483 -78 -288 145 360 29 -502 -539 -424 -278 391 430 233 149 -316 -6 -46 445 54 -298 -194 16 207 40 -726 -849 -596 -208 139 -28 -102 -92 -421 -421 14 -232 -358 -487 -90 -58 83 402 268 -450 -428 -314 -143 -198 -201 -171 -68 206 200 125 -931 -1593 -601 -421 171 549 556 128 85 -39 300 493 711 573 267 49 366 707 657 692 337 26 -10 325 201 265 52 -448 -264 153 313 728 518 -91 -307 -180 -114 48 232 460 16 -254 -673 -814 -186 300 359 -258 SQ 20250308T144407.6Z 9198.613977 374 1 53.26 2 87.86 132.58 72.54 16.37 0.00 1 0.00 1 0 15 3.538e-03 3.556e-03 1.608e-04 1.605e-04 2.524536e+03 8.500969e+00 1.779017e+02 -6.000000e+00 1.744816e+02 250.08 -2.00 20.00 -2.00 505.36 0.00e+00 7.930434e-04 4.125043e-06 4.740341e-05 -6.000000e+00 9.218318e-05 250.08 -2.00 20.00 -2.00 500.94 0.00e+00 1.368957e+00 3.143933e-03 3.285275e-02 -6.000000e+00 7.103983e-02 220.32 -2.00 5.56 -2.00 502.46 0.00e+00 15.886 0.133 489.00 513.00 1 1.6835e+00 2.3849e-04 2.9852e-02 -6.0000e+00 5.4016e-03 -2.7897e-02 6.0763e-05 1.7648e-03 -6.0000e+00 1.3971e-03 3.3748e-02 2.5390e-04 1.6517e-05 3.7859e-05 -6.0000e+00 3.7366e-04 -1.3225e-03 4.1914e-05 10 0 0 10 0 0 84.26 25.56 2.18 -0.00132 0.00044 332 42 1 4 0 160.400 33.50 20.00 25.56 -23.38 2.3 1042.53 476 117 -234 -301 127 397 263 42 -17 218 251 54 1 44 136 278 372 38 -400 -291 69 245 357 298 110 111 3 -430 -435 359 636 609 491 -218 -849 -639 -112 82 119 213 231 146 146 91 -80 -125 -53 -70 -311 -454 -294 -45 259 358 -42 -527 -656 -426 -22 318 465 265 -18 -135 -153 44 289 109 -189 -145 132 119 28 -349 -759 -710 -190 216 118 -25 -187 -347 -368 -66 -259 -397 -331 -144 -6 75 269 125 -318 -534 -278 -125 -170 -274 -297 -22 226 363 -22 -746 -1276 -873 -366 177 584 507 181 -6 47 190 507 657 519 174 108 239 412 614 755 425 11 74 230 274 342 -11 -430 -155 190 310 521 480 -42 -299 -192 -45 -21 214 274 57 -217 -639 -703 -341 243 315 -48 431 107 -216 -284 121 383 256 41 -16 213 242 53 1 42 130 263 358 37 -393 -290 68 242 355 298 109 110 3 -431 -426 348 612 582 474 -217 -854 -649 -113 82 119 211 229 147 146 92 -81 -126 -54 -70 -313 -448 -289 -44 247 344 -41 -522 -659 -428 -22 319 467 268 -18 -136 -154 44 288 107 -187 -142 128 116 28 -345 -753 -702 -187 211 114 -24 -182 -336 -361 -64 -257 -393 -330 -143 -6 75 268 125 -324 -543 -281 -126 -169 -269 -289 -21 216 351 -22 -747 -1293 -891 -370 178 587 507 182 -6 49 196 526 685 541 183 113 248 425 631 771 432 11 76 238 281 350 -11 -442 -159 194 313 524 483 -43 -310 -201 -48 -22 226 291 61 -231 -684 -751 -360 253 325 -50 SQ 20250308T144718.7Z 9198.616189 378 1 53.19 2 87.76 133.37 72.51 17.08 0.00 1 0.00 1 0 15 3.537e-03 3.556e-03 1.355e-04 1.352e-04 2.473086e+03 7.163203e+00 1.729618e+02 -6.000000e+00 1.744542e+02 250.08 -2.00 20.00 -2.00 505.36 0.00e+00 7.807189e-04 3.473289e-06 4.658265e-05 -6.000000e+00 9.216626e-05 250.08 -2.00 20.00 -2.00 500.93 0.00e+00 1.361447e+00 2.649950e-03 3.261205e-02 -6.000000e+00 7.101583e-02 220.32 -2.00 5.56 -2.00 502.46 0.00e+00 15.606 0.126 489.00 513.00 1 1.3821e+00 2.0100e-04 2.8913e-02 -6.0000e+00 5.3999e-03 -2.8963e-02 5.1223e-05 1.7149e-03 -6.0000e+00 1.3964e-03 4.7515e-02 -6.8010e-05 1.3940e-05 3.6630e-05 -6.0000e+00 3.7358e-04 -5.6266e-03 8.3024e-05 10 0 0 10 0 0 93.97 25.56 2.13 -0.00563 -0.00610 505 64 1 4 0 105.320 33.50 20.00 25.56 -23.47 2.3 1043.37 477 142 -230 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