File name: Pandora144s1_Eureka-PEARL_20190404_L2Fit_fwvt1c4d20190120p1-8.txt File generation date: 20241125T211537.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20190404_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20190404 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1639 1789 Nominal wavelengths inside fitting window [nm]: 492.0500 492.1708 492.2917 492.4125 492.5333 492.6541 492.7748 492.8956 493.0163 493.1371 493.2578 493.3784 493.4991 493.6198 493.7404 493.8610 493.9816 494.1022 494.2228 494.3433 494.4639 494.5844 494.7049 494.8254 494.9458 495.0663 495.1867 495.3072 495.4276 495.5479 495.6683 495.7887 495.9090 496.0293 496.1496 496.2699 496.3902 496.5104 496.6306 496.7508 496.8710 496.9912 497.1114 497.2315 497.3517 497.4718 497.5919 497.7120 497.8320 497.9521 498.0721 498.1921 498.3121 498.4321 498.5520 498.6720 498.7919 498.9118 499.0317 499.1516 499.2714 499.3913 499.5111 499.6309 499.7507 499.8705 499.9902 500.1100 500.2297 500.3494 500.4691 500.5887 500.7084 500.8280 500.9476 501.0672 501.1868 501.3064 501.4259 501.5455 501.6650 501.7845 501.9040 502.0234 502.1429 502.2623 502.3817 502.5011 502.6205 502.7398 502.8592 502.9785 503.0978 503.2171 503.3364 503.4556 503.5749 503.6941 503.8133 503.9325 504.0516 504.1708 504.2899 504.4090 504.5281 504.6472 504.7663 504.8853 505.0044 505.1234 505.2424 505.3614 505.4803 505.5993 505.7182 505.8371 505.9560 506.0748 506.1937 506.3125 506.4314 506.5502 506.6689 506.7877 506.9065 507.0252 507.1439 507.2626 507.3813 507.5000 507.6186 507.7372 507.8558 507.9744 508.0930 508.2116 508.3301 508.4486 508.5671 508.6856 508.8041 508.9225 509.0410 509.1594 509.2778 509.3962 509.5145 509.6329 509.7512 509.8695 509.9878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190404T175145.0Z 7033.744271 1487 1 32.00 2 74.27 180.79 82.42 185.46 0.00 1 0.00 1 0 43 7.863e-02 7.625e-02 6.646e-02 6.554e-02 -3.103327e+03 3.170542e+03 3.077015e+02 -6.000000e+00 3.772157e+03 250.32 -2.00 20.00 -2.00 505.25 0.00e+00 2.709755e-03 1.670653e-03 1.646015e-04 -6.000000e+00 2.027973e-03 250.32 -2.00 20.00 -2.00 500.44 0.00e+00 -2.744365e-01 1.328161e+00 3.936771e-02 -6.000000e+00 1.577383e+00 225.65 -2.00 5.57 -2.00 502.05 0.00e+00 3.626 0.001 489.00 513.00 1 1.1845e+01 1.0072e-01 6.9317e-03 -6.0000e+00 1.1952e-01 1.8668e-02 2.6840e-02 8.6664e-04 -6.0000e+00 3.1564e-02 8.5945e-06 -1.7220e-02 6.2703e-03 8.3258e-05 -6.0000e+00 7.6060e-03 2.9815e-02 9.3192e-05 12 8 8 10 0 0 98.22 20.54 3.93 0.02981 -0.08963 8 2 1 7 0 4000.000 23.93 14.99 20.54 -1052 -3702 8376 9271 9122 -6481 622 -3382 1289 -217 -6728 -6286 15292 8013 6283 -12811 15809 10198 -5221 -5995 -1841 -1305 421 1378 3579 6741 5845 -1283 14001 -8759 -1546 -12679 -13980 -10688 3960 13466 1054 -2418 3244 7192 -1843 1580 3930 18198 -2071 -1166 4063 -5368 -990 13548 38 8427 -4150 -661 -2502 -5684 -1305 -2603 8806 -13626 17844 9311 7610 -6471 6829 -268 -2599 5128 2422 -5901 -8454 2081 -5064 -6914 2751 9049 -1017 -3590 272 -3684 -7265 -13708 3352 -7647 -786 5257 8302 2392 1559 -8445 13897 13951 -15413 2692 1931 -1902 -928 1927 10584 -308 -19338 11696 2 -4024 -5125 3895 7441 5176 6277 -6302 2070 5845 -4412 3484 3725 7637 131 2577 -170 -5917 -10224 5261 7519 8409 2349 -7899 -5492 2795 10730 7392 7294 -13419 6002 22924 -4492 1284 22711 10267 -6399 2389 5293 -3789 -8368 11649 -6253 -8187 2139 2019 -3438 -6816 900000 -989 -3566 7300 8292 8452 -7194 656 -3769 1377 -234 -7623 -6978 13467 7461 5879 -14455 13487 9356 -5724 -6764 -2009 -1419 450 1460 3727 6833 5978 -1401 12908 -9844 -1567 -14190 -15967 -12109 4014 12724 1132 -2661 3333 7026 -1961 1631 4002 16277 -2299 -1294 4287 -6180 -1076 12491 39 7731 -4226 -646 -2525 -5694 -1290 -2663 8105 -15692 16043 8530 7135 -7009 6462 -270 -2637 4742 2270 -5937 -8613 1898 -4986 -7015 2568 7980 -984 -3505 251 -3517 -7185 -14554 3028 -7759 -750 4771 7357 2253 1482 -8893 11780 11945 -18013 2674 1951 -1995 -958 1906 9380 -297 -22104 9764 2 -4083 -5397 3785 6912 4830 5697 -6449 1967 5455 -4665 3476 3764 7487 139 2670 -180 -6536 -11599 5045 6985 7740 2313 -8657 -5878 2752 9738 6931 6839 -15339 5550 17567 -4461 1199 17306 9054 -6794 2353 5099 -4007 -8698 10622 -6425 -8576 2133 1847 -3229 -6484 900000 SO 20190404T175943.0Z 7033.749803 1490 1 32.00 2 74.28 182.85 82.43 187.42 0.00 1 0.00 1 0 66 6.609e-02 6.557e-02 6.228e-02 6.144e-02 1.504467e+03 3.144211e+03 3.241229e+02 -6.000000e+00 3.168110e+03 250.32 -2.00 20.00 -2.00 505.26 0.00e+00 -1.392018e-03 1.547947e-03 2.171979e-05 -6.000000e+00 1.702573e-03 250.32 -2.00 20.00 -2.00 500.35 0.00e+00 -7.020447e-01 1.227100e+00 2.969804e-02 -6.000000e+00 1.320783e+00 225.65 -2.00 5.57 -2.00 501.99 0.00e+00 3.628 0.001 489.00 513.00 1 1.1857e+01 9.2869e-02 5.1926e-03 -6.0000e+00 1.0016e-01 1.3077e-02 2.4562e-02 3.2379e-04 -6.0000e+00 2.6297e-02 9.1986e-06 -7.6294e-04 5.7450e-03 5.6201e-05 -6.0000e+00 6.3715e-03 1.1628e-01 -1.0943e-03 12 8 8 10 0 0 -144.77 20.54 7.79 0.11628 0.11099 8 2 1 7 0 4000.000 23.93 15.00 20.54 -1979 -642 7014 4004 8933 -9499 -65 1367 -208 -3211 4746 6871 -9624 2134 3364 3376 8058 3967 33 8732 3264 -4313 5909 4726 3429 -11970 -17950 -11373 -2972 -6435 7638 4737 3239 -3024 4926 6109 -2616 4547 8695 -3172 11787 9273 3178 4192 -1190 2909 2311 150 1810 -2368 3510 12091 -6584 -1859 -133 -5020 -5679 -4264 -5654 4143 -1807 -724 -8238 489 -3779 -891 4264 -2638 -3044 5205 -2011 13821 1160 1665 4367 580 20431 -3441 2800 -9276 18648 -8742 -3594 -1410 -6662 -2929 -8666 9307 -1564 769 -5744 -52 -11351 2498 5163 13817 -3548 13891 -4476 1223 1217 -8820 5884 -10008 -7368 -5103 -14 -225 13913 1894 1779 2395 4247 9963 -948 8196 -809 7020 -4980 2597 -1363 -11796 9643 6288 3012 916 6663 -10274 2850 -3744 5329 5150 -6772 7088 -4555 13258 -7100 8944 1525 1718 1107 4471 -3215 1194 -2150 6753 -11462 -763 -2919 -1921 4128 -1872 -601 6244 3805 8336 -10906 -69 1458 -226 -3576 4816 6737 -10967 2129 3284 3295 7589 3975 35 8749 3481 -4971 6149 4980 3672 -14979 -23775 -13987 -3297 -7168 7193 4563 3204 -3277 5105 6383 -2981 4771 8638 -3505 11152 9012 3307 4363 -1233 2907 2319 153 1780 -2376 3226 10607 -6368 -1709 -122 -4997 -5858 -4415 -5968 3957 -1828 -727 -8961 489 -3928 -890 3988 -2604 -2981 4638 -1904 11150 1071 1551 4014 556 15908 -3342 2518 -9344 14221 -8842 -3491 -1353 -6819 -2927 -9251 8330 -1563 753 -6041 -53 -12938 2506 5036 12201 -3659 11764 -4437 1119 1099 -8850 5219 -10805 -8044 -5550 -14 -229 12118 1847 1749 2374 4194 9397 -1004 7960 -864 6960 -5557 2657 -1428 -13494 8785 5906 2938 915 6284 -11463 2779 -3892 5047 4837 -7040 6315 -4516 11015 -6892 8077 1417 1616 1058 4155 -3242 1159 -2168 6226 -12550 -735 -2801 -1793 3619 SO 20190404T180715.0Z 7033.755035 1493 1 32.00 2 74.30 184.80 82.45 189.27 0.00 1 0.00 1 0 15 5.761e-02 5.575e-02 5.314e-02 5.248e-02 -3.180364e+03 2.593010e+03 3.222703e+02 -6.000000e+00 2.764333e+03 250.32 -2.00 20.00 -2.00 505.29 0.00e+00 -1.049232e-03 1.334047e-03 1.917354e-05 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