File name: Pandora144s1_Eureka-PEARL_20190710_L2Fit_fout2c3d20190119p1-8.txt File generation date: 20241120T181904.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v2d20180302.txt Instrument calibration file used: Pandora144s1_CF_v3d20190119.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20190710_L1_smca1c3d20190119p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20190710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB data based on session1 First and last pixel inside fitting window: 217 359 Nominal wavelengths inside fitting window [nm]: 305.0387 305.1796 305.3206 305.4616 305.6025 305.7435 305.8844 306.0253 306.1662 306.3071 306.4479 306.5888 306.7297 306.8705 307.0113 307.1521 307.2929 307.4337 307.5745 307.7153 307.8560 307.9968 308.1375 308.2782 308.4189 308.5596 308.7003 308.8410 308.9816 309.1223 309.2629 309.4036 309.5442 309.6848 309.8254 309.9659 310.1065 310.2470 310.3876 310.5281 310.6686 310.8091 310.9496 311.0901 311.2306 311.3710 311.5115 311.6519 311.7923 311.9327 312.0731 312.2135 312.3539 312.4942 312.6346 312.7749 312.9153 313.0556 313.1959 313.3362 313.4764 313.6167 313.7569 313.8972 314.0374 314.1776 314.3178 314.4580 314.5982 314.7384 314.8785 315.0187 315.1588 315.2989 315.4390 315.5791 315.7192 315.8593 315.9993 316.1394 316.2794 316.4194 316.5594 316.6994 316.8394 316.9794 317.1194 317.2593 317.3992 317.5392 317.6791 317.8190 317.9589 318.0987 318.2386 318.3785 318.5183 318.6581 318.7979 318.9377 319.0775 319.2173 319.3571 319.4968 319.6366 319.7763 319.9160 320.0557 320.1954 320.3351 320.4748 320.6144 320.7541 320.8937 321.0333 321.1729 321.3125 321.4521 321.5917 321.7312 321.8708 322.0103 322.1498 322.2893 322.4288 322.5683 322.7078 322.8473 322.9867 323.1261 323.2656 323.4050 323.5444 323.6838 323.8231 323.9625 324.1018 324.2412 324.3805 324.5198 324.6591 324.7984 324.9377 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20190710T063848.0Z 7130.276944 4 1 32.00 2 77.49 11.32 97.43 271.87 0.00 1 0.00 1 0 25 3.374e-01 4.180e-02 3.289e-01 3.306e-02 5.731452e-01 1.894816e-02 1.041662e-02 -6.000000e+00 2.132901e-01 236.63 -2.00 5.57 -2.00 320.46 0.00e+00 3.166615e-03 6.354592e-03 1.160006e-03 -6.000000e+00 1.156572e-02 269.61 -2.00 20.00 -2.00 319.99 0.00e+00 4.486 0.003 302.00 328.00 3 3.3240e+00 5.6442e-02 6.6213e-02 -6.0000e+00 5.4522e-01 4.8057e-01 6.5727e-02 4.9589e-02 -6.0000e+00 5.9255e-01 -3.7638e-01 5.3704e-02 2.4119e-02 -6.0000e+00 3.4352e-01 1.5487e-01 2.7466e-02 6.9505e-03 -6.0000e+00 1.3958e-01 1.3057e-04 -2.6611e-04 1.1019e-03 1.0658e-04 -6.0000e+00 1.1080e-02 5.7621e-02 -1.4998e-04 12 9 8 11 8 0 -63.90 21.47 -0.25 0.05762 0.05562 8 2 1 8 0 4000.000 24.65 15.00 21.47 900000 900000 -97096 -125555 -41555 900000 -113641 900000 115643 900000 900000 900000 900000 83799 5021 -25819 -54426 900000 -36282 101140 900000 12685 -30886 -10026 900000 45072 900000 47239 55274 -35661 14708 157389 -23946 75613 14369 82042 -10047 -56611 17603 49269 -2352 9280 11971 50129 -16145 -1830 23744 -17070 40614 2518 9536 27968 9035 739 17297 15202 3433 18449 4425 33543 -3238 2990 -11295 8499 5643 6604 -1490 31093 19915 9907 -6195 4827 -6017 2288 2937 12295 4922 354 7074 689 -9823 -6738 2298 -595 -4770 -12 -828 -1222 -769 2507 -9510 1490 -16475 7169 -4813 1228 3784 2753 5591 -5973 7408 -1277 3277 -6524 -3062 -3777 -2743 -5380 1580 679 1473 1905 2455 552 -3184 -3213 -738 -2855 -2546 2357 2335 -91 2174 5317 1076 4181 3424 -925 7763 740 2756 235 -2142 -269 -35 -66 600 628 -2123 -1983 -1832 2364 -1163 900000 900000 -4164 -6731 -1337 900000 -5649 900000 3720 900000 900000 900000 900000 2695 191 -1510 -4615 900000 -2864 3253 900000 631 -2438 -674 900000 1845 900000 1796 1939 -3337 946 5062 -2801 3316 1134 3359 -1146 -12084 2110 4898 -426 1574 2030 5863 -3682 -364 3680 -4043 5582 537 2063 5479 2298 216 4451 4089 1044 4747 1281 7258 -1060 1005 -4822 3181 2195 2472 -597 9365 7396 4519 -3550 2527 -3413 1117 1297 4494 1842 143 2979 357 -6434 -4748 1593 -450 -4003 -10 -733 -1101 -677 2031 -8092 1063 -13681 4905 -4123 1127 3839 3116 6425 -7527 7582 -1307 3067 -6906 -3313 -4340 -3296 -7094 2117 1003 2304 3036 3812 832 -4711 -4622 -1051 -4340 -4049 3653 3577 -138 3102 7043 1422 5147 4205 -1252 10600 1187 4641 427 -4166 -542 -75 -144 1336 1403 -4786 -4267 -3718 4382 -2215 SU 20190710T064453.0Z 7130.281169 7 1 32.00 2 77.43 12.76 97.70 273.31 0.00 1 0.00 1 0 25 5.206e-01 3.855e-02 3.831e-01 3.009e-02 5.753600e-01 1.686232e-02 9.731398e-03 -6.000000e+00 3.232123e-01 236.63 -2.00 5.57 -2.00 320.63 0.00e+00 7.227725e-03 5.835414e-03 6.590952e-04 -6.000000e+00 1.405709e-02 269.61 -2.00 20.00 -2.00 320.16 0.00e+00 4.468 0.003 302.00 328.00 3 3.2484e+00 5.0292e-02 6.5763e-02 -6.0000e+00 8.2274e-01 4.5861e-01 5.9453e-02 5.0493e-02 -6.0000e+00 8.9002e-01 -4.9768e-01 4.8152e-02 2.4561e-02 -6.0000e+00 5.2336e-01 2.3655e-01 2.4110e-02 1.1733e-02 -6.0000e+00 2.1243e-01 1.4757e-04 1.7293e-03 9.6949e-04 1.4544e-04 -6.0000e+00 1.6689e-02 5.5798e-02 -6.1463e-05 12 8 8 10 0 0 28.32 21.47 0.68 0.05580 0.06879 8 2 1 8 0 4000.000 24.65 15.00 21.47 -40603 900000 -106467 900000 -95723 84654 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