File name: Pandora144s1_Eureka-PEARL_20200903_L2Fit_fout2c4d20190120p1-8.txt File generation date: 20241125T231645.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Xiaoyi Zhao Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 144 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora144_of_v4d20180302.txt Instrument calibration file used: Pandora144s1_CF_v4d20190120.txt Level 1 file used: Pandora144s1_Eureka-PEARL_20200903_L1_smca1c4d20190120p1-8.txt Full location name: Polar Environment Atmospheric Research Laboratory (PEARL) Short location name: Eureka-PEARL Country of location: Canada Location latitude [deg]: 80.0533 Location longitude [deg]: -86.4160 Location altitude [m]: 617 Local noon date: 20200903 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 217 359 Nominal wavelengths inside fitting window [nm]: 305.1040 305.2448 305.3856 305.5264 305.6672 305.8079 305.9487 306.0895 306.2302 306.3709 306.5116 306.6524 306.7931 306.9337 307.0744 307.2151 307.3557 307.4964 307.6370 307.7776 307.9182 308.0588 308.1994 308.3399 308.4805 308.6211 308.7616 308.9021 309.0426 309.1831 309.3236 309.4641 309.6046 309.7450 309.8855 310.0259 310.1663 310.3067 310.4471 310.5875 310.7279 310.8683 311.0086 311.1490 311.2893 311.4296 311.5699 311.7102 311.8505 311.9908 312.1311 312.2713 312.4116 312.5518 312.6920 312.8322 312.9724 313.1126 313.2528 313.3929 313.5331 313.6732 313.8134 313.9535 314.0936 314.2337 314.3737 314.5138 314.6539 314.7939 314.9340 315.0740 315.2140 315.3540 315.4940 315.6340 315.7739 315.9139 316.0538 316.1938 316.3337 316.4736 316.6135 316.7534 316.8933 317.0331 317.1730 317.3128 317.4527 317.5925 317.7323 317.8721 318.0119 318.1516 318.2914 318.4312 318.5709 318.7106 318.8503 318.9900 319.1297 319.2694 319.4091 319.5487 319.6884 319.8280 319.9676 320.1073 320.2469 320.3864 320.5260 320.6656 320.8051 320.9447 321.0842 321.2237 321.3632 321.5027 321.6422 321.7817 321.9212 322.0606 322.2000 322.3395 322.4789 322.6183 322.7577 322.8971 323.0364 323.1758 323.3151 323.4545 323.5938 323.7331 323.8724 324.0117 324.1510 324.2902 324.4295 324.5687 324.7080 324.8472 324.9864 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200903T195421.2Z 7551.829413 183 1 50.48 2 74.50 213.48 105.18 14.19 0.00 1 0.00 1 0 25 1.189e-01 7.652e-03 6.934e-02 4.149e-03 4.231660e-01 2.207530e-03 7.695864e-03 -6.000000e+00 7.159924e-02 229.03 -2.00 5.57 -2.00 320.01 0.00e+00 1.259178e-03 6.328459e-04 4.491555e-04 -6.000000e+00 2.977064e-03 265.52 -2.00 20.00 -2.00 319.55 0.00e+00 3.675 0.002 302.00 328.00 3 4.1241e+00 6.2630e-03 4.9365e-02 -6.0000e+00 1.7913e-01 9.7268e-03 7.3090e-03 3.5178e-02 -6.0000e+00 1.9506e-01 -4.2708e-02 6.1452e-03 1.7562e-02 -6.0000e+00 1.1499e-01 2.0161e-02 3.1969e-03 5.1328e-03 -6.0000e+00 4.6735e-02 1.8122e-04 -7.6975e-04 1.4061e-04 6.9688e-05 -6.0000e+00 3.7555e-03 7.0990e-03 -2.1720e-04 11 8 0 10 0 0 93.50 22.18 0.34 0.00710 0.00131 29 6 1 8 0 1740.688 25.39 15.01 22.18 -68540 34885 -45385 37705 -33650 -4111 -67345 15561 26800 -30935 13842 -24039 1360 -11627 15685 -17872 4722 -7306 -92 -10606 -2118 4800 -1767 1892 -4171 1061 -2672 12963 -5119 2233 -5530 1838 1914 -1080 6229 -4562 487 2563 2127 -2443 182 -3708 503 -3882 1459 -1049 4958 -2086 798 3551 1563 6532 -556 369 -867 2149 133 1448 575 1207 1833 3553 1698 -801 1572 -207 2224 804 486 -700 -232 99 -1306 -186 60 948 93 1119 -1179 -764 -1445 213 -1253 -1350 -1588 -488 141 -565 -261 132 908 393 795 -125 1362 173 648 97 -146 -321 -913 -45 256 189 -1394 -828 -489 -62 -284 85 -396 74 245 11 1003 144 1180 30 64 -1117 -383 -181 -324 939 474 913 578 1251 285 571 -391 125 17 710 -524 -447 286 -339 153 -704 27 -309 346 -2219 438 -1286 442 -763 -70 -2344 264 445 -964 291 -827 43 -499 597 -1063 243 -452 -6 -742 -139 299 -123 136 -336 83 -215 866 -406 174 -517 178 201 -118 625 -528 60 369 366 -503 40 -893 120 -982 353 -262 1168 -531 202 920 447 1927 -189 131 -326 807 52 551 218 460 731 1520 808 -413 790 -102 1041 394 263 -427 -151 66 -870 -116 35 490 46 553 -655 -482 -1038 167 -969 -1113 -1404 -453 136 -560 -254 123 778 315 670 -109 1166 168 705 116 -183 -394 -1053 -48 263 201 -1605 -1003 -623 -83 -413 134 -657 123 397 17 1432 201 1652 44 100 -1843 -629 -290 -503 1384 672 1235 772 1731 432 935 -686 227 32 1408 -1112 -989 643 -713 345 -1554 58 -625 694 SU 20200903T200730.0Z 7551.838542 186 1 50.02 2 74.83 216.84 104.99 17.47 0.00 1 0.00 1 0 25 7.840e-02 5.772e-03 3.039e-02 2.039e-03 4.307421e-01 1.069201e-03 7.761787e-03 -6.000000e+00 4.722355e-02 229.02 -2.00 5.57 -2.00 319.93 0.00e+00 1.420612e-03 3.047871e-04 5.365685e-04 -6.000000e+00 1.963353e-03 265.52 -2.00 20.00 -2.00 319.49 0.00e+00 3.750 0.002 302.00 328.00 3 2.7848e+00 3.0139e-03 5.0137e-02 -6.0000e+00 1.1815e-01 2.3073e-02 3.5251e-03 3.5633e-02 -6.0000e+00 1.2864e-01 -3.4430e-02 2.9957e-03 1.7815e-02 -6.0000e+00 7.5837e-02 1.4224e-02 1.5699e-03 5.2796e-03 -6.0000e+00 3.0827e-02 6.3454e-04 -7.1519e-04 6.7768e-05 6.4938e-05 -6.0000e+00 2.4765e-03 6.2150e-03 -2.0379e-04 10 0 0 10 0 0 96.94 22.18 0.24 0.00621 0.00084 105 21 1 8 0 476.358 25.39 15.01 22.18 -49536 714 -36829 884 -39730 -9577 -18777 -13037 -24404 -18954 12648 -22213 -4461 -17287 -1224 -10932 573 -3874 3178 500 -1532 983 -7383 2192 -3343 -1049 -6914 -251 -4224 2568 -1680 4042 -1500 -2822 -592 -3605 -409 -2489 322 -2075 2129 -2361 1169 -1832 -436 -884 -287 257 -44 2139 112 2337 1419 2564 -114 1337 77 631 179 916 1999 1249 2310 -7 1649 -347 1008 565 1450 866 203 -187 -227 59 -443 305 -1232 1025 -929 85 -1205 -1362 -1512 -1133 -620 -664 210 -372 446 26 876 -70 760 349 945 836 600 -2 -312 -342 -685 220 -372 81 -1120 -605 -810 -145 -114 -115 -47 -345 -31 166 601 555 747 -71 -336 -843 -356 -386 123 444 593 1182 750 983 170 404 -109 371 164 50 -195 -134 64 -259 -207 -271 -37 -366 167 -1280 12 -930 15 -932 -168 -392 -288 -660 -513 264 -738 -147 -777 -55 -604 31 -232 187 31 -100 64 -546 157 -269 -85 -586 -19 -336 202 -154 391 -166 -322 -65 -423 -52 -386 58 -436 470 -576 285 -467 -111 -227 -73 66 -12 582 34 746 491 929 -44 526 31 252 71 364 827 568 1034 -3 787 -162 499 290 739 494 125 -119 -142 35 -242 166 -643 531 -540 51 -823 -1030 -1231 -978 -569 -648 212 -386 452 25 787 -59 611 289 852 850 688 -2 -412 -442 -829 244 -403 90 -1348 -766 -1085 -205 -173 -174 -75 -559 -49 245 907 812 1105 -112 -511 -1335 -563 -596 200 690 881 1673 1049 1431 271 639 -185 649 300 96 -399 -285 139 -572 -453 -575 -75 -714 323 SU 20200903T201403.2Z 7551.843093 190 1 50.39 2 75.01 218.52 104.88 19.11 0.00 1 0.00 1 0 25 7.884e-02 5.452e-03 3.592e-02 2.471e-03 4.313238e-01 1.302783e-03 7.839542e-03 -6.000000e+00 4.749384e-02 229.02 -2.00 5.57 -2.00 319.96 0.00e+00 1.090913e-03 3.733175e-04 4.472569e-04 -6.000000e+00 1.974498e-03 265.52 -2.00 20.00 -2.00 319.53 0.00e+00 3.791 0.002 302.00 328.00 3 3.1399e+00 3.6790e-03 5.0619e-02 -6.0000e+00 1.1882e-01 1.5270e-02 4.3070e-03 3.5933e-02 -6.0000e+00 1.2938e-01 -3.6160e-02 3.6849e-03 1.7980e-02 -6.0000e+00 7.6269e-02 1.7020e-02 1.9238e-03 5.2277e-03 -6.0000e+00 3.1005e-02 4.3165e-04 -6.9331e-04 8.2114e-05 6.9579e-05 -6.0000e+00 2.4905e-03 5.8312e-03 -1.9664e-04 10 0 0 10 0 0 97.73 22.18 0.21 0.00583 0.00062 63 12 1 8 0 799.766 25.39 15.00 22.18 -40486 -11893 -28070 -39147 -18111 -24803 -9898 -24568 -17454 -32246 -19051 -16690 -17675 -13308 -2276 -818 -3925 4182 -2333 -1224 -1492 -647 -4632 -2942 -4360 -586 -6459 46 545 -3993 -1323 -1492 744 -921 -1729 -2831 -1510 682 48 -1019 -1596 -390 115 997 -124 164 -1029 1459 -652 294 -903 1839 962 962 1063 575 1111 -163 769 1201 2209 1126 2425 522 800 395 1622 872 776 710 -411 181 -300 325 23 162 249 10 -319 -670 -682 -1159 -1465 -1294 -419 -800 36 -493 -4 -22 253 -42 667 808 831 1122 248 362 -649 -31 -548 5 0 -365 -1087 -943 -879 -334 78 45 176 -1 191 -28 406 151 615 -4 -249 -812 -585 222 -65 562 736 799 847 1219 242 374 -45 -76 315 152 -59 -239 79 -437 -112 -148 -11 -238 -98 -927 -224 -629 -934 -332 -490 -184 -592 -429 -971 -532 -511 -647 -558 -100 -40 -213 224 -141 -76 -95 -41 -324 -216 -345 -46 -531 3 40 -325 -117 -148 78 -100 -187 -320 -190 100 8 -206 -356 -91 28 240 -30 41 -258 360 -168 79 -267 574 325 345 397 222 433 -64 296 464 890 500 1163 270 413 197 779 436 428 436 -249 112 -184 206 14 86 125 5 -180 -433 -454 -857 -1168 -1097 -376 -766 36 -502 -4 -21 225 -34 527 655 737 1117 280 447 -845 -39 -651 6 0 -403 -1287 -1179 -1160 -466 117 72 276 -1 295 -45 606 218 899 -7 -408 -1384 -998 367 -104 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