File name: Pandora29s1_Fajardo_20220616_L2Fit_fout2c17d20220426p1-8.txt File generation date: 20260429T095414.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v17d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20220616_L1_smca1c17d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20220616 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0234 305.1644 305.3054 305.4464 305.5874 305.7283 305.8693 306.0102 306.1512 306.2921 306.4330 306.5739 306.7148 306.8557 306.9966 307.1374 307.2783 307.4191 307.5599 307.7007 307.8415 307.9823 308.1231 308.2639 308.4046 308.5454 308.6861 308.8268 308.9676 309.1083 309.2490 309.3896 309.5303 309.6710 309.8116 309.9522 310.0929 310.2335 310.3741 310.5147 310.6552 310.7958 310.9364 311.0769 311.2174 311.3579 311.4985 311.6390 311.7794 311.9199 312.0604 312.2008 312.3413 312.4817 312.6221 312.7625 312.9029 313.0433 313.1837 313.3240 313.4644 313.6047 313.7451 313.8854 314.0257 314.1660 314.3062 314.4465 314.5868 314.7270 314.8673 315.0075 315.1477 315.2879 315.4281 315.5683 315.7084 315.8486 315.9887 316.1288 316.2690 316.4091 316.5492 316.6893 316.8293 316.9694 317.1094 317.2495 317.3895 317.5295 317.6695 317.8095 317.9495 318.0895 318.2294 318.3694 318.5093 318.6492 318.7891 318.9290 319.0689 319.2088 319.3487 319.4885 319.6284 319.7682 319.9080 320.0478 320.1876 320.3274 320.4672 320.6069 320.7467 320.8864 321.0261 321.1659 321.3056 321.4452 321.5849 321.7246 321.8642 322.0039 322.1435 322.2831 322.4228 322.5623 322.7019 322.8415 322.9811 323.1206 323.2602 323.3997 323.5392 323.6787 323.8182 323.9577 324.0971 324.2366 324.3760 324.5155 324.6549 324.7943 324.9337 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220616T141646.0Z 8202.594977 359 1 9.87 2 29.90 74.91 120.91 250.47 0.00 1 0.00 1 0 17 1.518e-02 1.416e-02 4.815e-03 3.563e-03 1.306909e-01 1.827243e-03 1.648663e-03 -6.000000e+00 8.694150e-03 228.70 -2.00 3.11 -2.00 314.45 0.00e+00 2.414814e-04 1.493592e-04 2.767457e-04 -6.000000e+00 4.022357e-04 295.00 -2.00 20.00 -2.00 313.76 0.00e+00 1.153 0.000 302.00 328.00 3 5.2400e+00 4.6746e-03 1.2850e-02 -6.0000e+00 2.1558e-02 -1.0140e-02 5.1714e-03 6.0746e-03 -6.0000e+00 2.3332e-02 3.1774e-02 2.9653e-03 3.0607e-03 -6.0000e+00 1.3999e-02 -2.0616e-02 1.3089e-03 1.2343e-03 -6.0000e+00 6.0096e-03 8.2943e-04 1.9366e-04 9.8415e-05 2.0233e-05 -6.0000e+00 4.0775e-04 7.8033e-03 0.0000e+00 12 9 9 12 41 1 99.96 22.82 0.41 0.00780 0.00926 3 3 1 5 0 2424.730 25.68 20.00 22.82 33.90 13.3 1088.31 -740 -2181 -3240 -2942 -1462 20 1197 3800 288 -947 34 1646 2773 870 469 12 -1075 -339 -482 1574 332 1392 2389 2386 1642 -264 -303 -1128 509 1046 3836 1869 203 -1988 -3249 -1044 -846 574 -118 -1007 -527 -1407 -1074 -1228 12 730 -37 90 -28 -153 764 348 -280 202 1041 16 -67 -801 432 1390 2177 2174 893 813 -1062 -1061 151 832 1714 -894 -472 -991 -1073 -307 -1062 -24 -230 -233 689 -1296 -2242 -2249 -3504 -1849 -1624 12 -1468 -428 -700 203 -281 -607 682 1451 1950 1862 3377 4428 2766 2204 3339 3772 4281 2514 92 -1184 -1639 -2106 -460 -474 -688 -1328 -1811 -481 -686 -378 -267 -472 -803 -1110 -1352 -969 568 -185 940 271 1566 1630 755 -268 -1068 -309 35 566 -206 -775 457 -213 -146 -157 -34 111 1122 -281 -910 -1389 -1183 -506 7 419 1315 115 -404 14 653 1160 411 228 6 -586 -186 -271 889 194 795 1355 1407 945 -160 -183 -697 282 547 1979 1027 120 -1233 -1902 -570 -493 352 -87 -813 -434 -1214 -946 -1092 10 627 -31 77 -23 -123 627 284 -240 180 943 15 -63 -757 397 1256 2003 2127 894 857 -1130 -1029 139 719 1520 -861 -498 -1042 -1138 -333 -1093 -23 -201 -200 591 -1172 -2143 -2354 -3727 -2016 -1888 14 -1840 -550 -910 253 -325 -675 712 1413 1944 1909 3754 5070 3236 2552 3786 4172 4485 2775 107 -1482 -2035 -2728 -608 -658 -949 -1852 -2543 -646 -838 -452 -315 -581 -1013 -1517 -1827 -1302 775 -244 1155 336 1812 1862 912 -327 -1366 -400 46 753 -278 -1108 665 -304 -210 -223 -49 156 1531 SS 20220616T142510.3Z 8202.600814 365 1 4.45 2 27.98 74.63 122.69 250.73 0.00 1 0.00 1 0 17 1.469e-02 1.452e-02 1.657e-03 1.334e-03 1.250960e-01 6.872288e-04 1.617062e-03 -6.000000e+00 8.409486e-03 228.70 -2.00 3.11 -2.00 313.96 0.00e+00 3.673685e-04 5.157385e-05 2.474635e-04 -6.000000e+00 3.890915e-04 295.00 -2.00 20.00 -2.00 313.33 0.00e+00 1.132 0.000 302.00 328.00 3 2.8705e+00 1.7480e-03 1.2565e-02 -6.0000e+00 2.0852e-02 -2.5841e-02 1.9291e-03 5.8524e-03 -6.0000e+00 2.2569e-02 3.1088e-02 1.1127e-03 3.0062e-03 -6.0000e+00 1.3541e-02 -2.0006e-02 4.8517e-04 1.2735e-03 -6.0000e+00 5.8122e-03 9.2159e-03 1.5517e-04 3.6611e-05 2.1188e-05 -6.0000e+00 3.9446e-04 8.7078e-03 0.0000e+00 12 9 9 12 9 1 44.43 22.80 0.36 0.00871 0.00987 12 25 1 5 0 328.850 25.68 20.00 22.80 34.34 13.3 1091.74 -773 -1795 -1506 -3470 -1087 511 2517 2016 343 -692 -399 1314 1101 485 8 -904 -788 668 274 929 159 795 2322 1659 771 -84 -633 299 621 2357 2595 1268 821 -2670 -2071 272 170 538 -567 -1089 -1464 -1073 -1024 -763 130 -554 -301 -90 -269 901 1129 508 225 427 282 531 -93 -14 654 1525 1793 1625 1211 592 -1620 -1011 -31 671 1717 -1238 -1455 -1101 -1165 -205 -788 -320 546 1053 1384 -1031 -1626 -2429 -3068 -1574 -1241 -1506 -1514 -1316 -684 -709 -625 -697 830 2416 2550 2723 3755 4267 2682 2194 2766 3544 4491 3373 68 -1270 -1620 -1847 -885 -616 -1147 -1546 -1282 -1035 -598 20 181 -37 -301 -1250 -1480 -613 -51 47 784 183 1540 2420 604 -159 -1083 -382 -142 224 -527 -784 -510 -208 -142 -366 85 681 1524 -345 -877 -746 -1645 -468 213 1060 884 160 -344 -193 610 546 253 4 -542 -482 407 172 564 99 487 1406 1051 514 -55 -420 194 385 1363 1517 783 511 -1768 -1337 164 109 359 -434 -896 -1268 -961 -903 -677 118 -503 -265 -79 -226 730 937 431 200 395 257 488 -88 -14 599 1376 1657 1541 1237 617 -1709 -1001 -28 603 1579 -1221 -1526 -1166 -1245 -219 -797 -313 491 906 1196 -966 -1577 -2508 -3270 -1722 -1399 -1774 -1830 -1646 -857 -860 -723 -781 853 2381 2584 2789 4048 4866 3184 2575 3136 3827 4736 3602 79 -1537 -2046 -2355 -1159 -820 -1598 -2107 -1712 -1348 -728 24 208 -44 -377 -1603 -1978 -811 -65 60 965 223 1806 2779 716 -194 -1385 -479 -179 290 -704 -1075 -719 -291 -201 -511 118 944 2053 SS 20220616T143009.2Z 8202.604273 368 1 52.14 2 26.84 74.41 123.74 250.88 0.00 1 0.00 1 0 17 1.459e-02 1.416e-02 1.127e-03 8.542e-04 1.258190e-01 4.393667e-04 1.613429e-03 -6.000000e+00 8.355168e-03 228.70 -2.00 3.11 -2.00 314.31 0.00e+00 3.617769e-04 3.500131e-05 2.681967e-04 -6.000000e+00 3.865793e-04 295.00 -2.00 20.00 -2.00 313.63 0.00e+00 1.120 0.000 302.00 328.00 3 4.4485e+00 1.1217e-03 1.2476e-02 -6.0000e+00 2.0717e-02 -1.4397e-02 1.2406e-03 5.8950e-03 -6.0000e+00 2.2424e-02 3.0456e-02 7.1282e-04 2.9913e-03 -6.0000e+00 1.3454e-02 -2.0484e-02 3.1304e-04 1.2738e-03 -6.0000e+00 5.7746e-03 1.9131e-03 2.2064e-04 2.3616e-05 2.0766e-05 -6.0000e+00 3.9191e-04 8.7358e-03 0.0000e+00 12 9 8 11 8 0 99.99 22.78 0.45 0.00874 0.01039 76 12 1 5 0 685.920 25.68 20.02 22.78 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