File name: Pandora29s1_Fajardo_20220628_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240212T204104.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20220628_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20220628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220628T102928.3Z 8214.437133 58 1 52.96 2 82.04 68.05 74.96 66.72 0.00 1 0.00 1 0 25 7.515e-01 2.903e-02 2.809e-01 7.455e-03 7.422293e-01 4.074480e-03 7.892068e-03 -6.000000e+00 4.325480e-01 228.26 -2.00 3.11 -2.00 321.51 0.00e+00 -4.000387e-03 2.253351e-03 6.263359e-03 -6.000000e+00 2.213266e-02 294.96 -2.00 20.00 -2.00 320.84 0.00e+00 6.735 0.001 302.00 328.00 3 2.3062e+00 1.5941e-02 8.2665e-02 -6.0000e+00 1.0731e+00 5.3642e-01 2.1788e-02 5.9611e-02 -6.0000e+00 1.1679e+00 -7.0815e-01 1.8792e-02 2.1324e-02 -6.0000e+00 6.9333e-01 2.8855e-01 8.8026e-03 6.6219e-03 -6.0000e+00 2.9828e-01 3.2864e-05 -5.0992e-04 2.0635e-04 8.6771e-05 -6.0000e+00 2.0072e-02 1.4530e-02 -5.8935e-05 12 8 8 10 0 0 97.28 22.85 0.45 0.01453 0.01070 22 3 1 5 0 2407.010 25.79 20.01 22.85 31.19 13.5 1067.43 -179471 900000 -94893 -96144 900000 -190985 900000 900000 -121994 -159159 -98475 900000 102958 900000 -111485 900000 12503 -38487 273936 41463 900000 -42032 51181 356012 56019 900000 -17983 295147 92900 -21623 213635 -1667 92336 -3439 137346 900000 -61323 149327 5697 111537 88442 30535 9669 -8361 88517 14559 267816 16865 157073 -9499 31851 51534 15117 28028 58831 10031 49081 -15185 16849 45712 14195 21056 33708 17029 14694 14944 -5636 17985 3650 -3298 4178 -5997 -1476 2258 4806 6772 9052 -5054 -12809 -7239 -1806 -11166 -8169 -729 -2317 4248 400 3451 1630 395 1460 2894 -6883 -4920 -1695 1136 3797 3710 964 -2396 6586 -1353 2052 -2070 -2788 -3521 -3406 -3757 -291 -247 2539 -3235 -1317 590 189 -1299 298 -472 -3266 52 -1262 -208 2617 1898 3782 639 1513 2165 1982 827 -481 858 -697 1739 -1194 -594 3976 -852 -229 -1381 -820 -482 -1120 -5564 900000 -1502 -1459 900000 -6047 900000 900000 -2656 -5459 -1884 900000 747 900000 -5177 900000 218 -1201 1988 632 900000 -1433 706 2583 894 900000 -639 2142 944 -706 1550 -62 1541 -162 1495 900000 -4983 1734 343 2833 3209 2105 849 -880 3468 1194 1943 1383 3305 -1123 2773 4150 1920 3417 5635 1638 5627 -3294 2531 4909 2091 3132 5014 3410 3220 3188 -1456 3797 980 -1106 1446 -2406 -560 775 1457 1784 2154 -1397 -4284 -2747 -766 -6020 -4748 -417 -1441 2644 272 2130 1025 266 907 1661 -4210 -2778 -1049 801 3035 3440 933 -2416 6221 -1242 1638 -1718 -2531 -3412 -3476 -4141 -342 -329 3718 -4950 -2006 861 287 -1917 436 -731 -5064 81 -1974 -308 3957 2804 5279 892 2014 2990 3149 1393 -911 1725 -1501 3899 -2743 -1432 9331 -2131 -570 -3312 -1825 -1079 -2424 SS 20220628T104404.5Z 8214.447274 63 1 51.79 2 78.81 68.99 71.86 67.41 0.00 1 0.00 1 0 25 2.246e-01 1.392e-02 9.230e-02 2.477e-03 5.746629e-01 1.276490e-03 6.671874e-03 -6.000000e+00 1.272957e-01 228.26 -2.00 3.11 -2.00 320.44 0.00e+00 -5.497530e-03 5.098221e-04 4.289696e-03 -6.000000e+00 5.888250e-03 294.96 -2.00 20.00 -2.00 319.62 0.00e+00 4.971 0.000 302.00 328.00 3 2.4980e+00 4.0921e-03 5.8997e-02 -6.0000e+00 3.1540e-01 -5.4367e-03 5.2384e-03 3.7477e-02 -6.0000e+00 3.4189e-01 -7.9053e-02 4.6418e-03 1.6203e-02 -6.0000e+00 2.0451e-01 3.8569e-02 2.3454e-03 3.6867e-03 -6.0000e+00 8.7885e-02 1.8907e-04 -1.5187e-04 6.8267e-05 7.6809e-05 -6.0000e+00 5.7967e-03 1.3573e-02 -6.8607e-05 12 8 8 10 0 0 99.96 22.86 0.55 0.01357 0.01243 64 10 1 5 0 809.090 25.79 20.03 22.86 32.19 13.5 1073.44 -105180 14396 -73935 -89611 -53756 -84114 900000 -46415 -38511 -81361 -55153 -16232 26340 82966 -67563 58358 -39744 7915 -2122 -16056 3280 -10103 11951 -5120 11423 19071 -7321 22518 1699 -1703 5135 4953 -682 3025 330 1422 -10779 1423 -988 5514 11107 5514 1570 137 4003 2032 10364 -1493 5585 -7434 1364 3637 -486 1070 4287 4401 6954 391 1939 4934 1498 1821 6130 1000 -715 -2453 -2619 -242 621 -589 -1568 -1260 -1573 -345 -490 744 1009 -3962 -1951 -3205 -2266 -3586 -4738 -2314 -2208 -851 -1573 -284 -217 -667 49 -837 10 1177 2707 3586 3788 4714 2782 2071 2596 1793 3070 891 -1309 -2153 -2188 -1771 135 -319 16 -838 -355 -373 -382 -257 146 -263 -1302 -1141 -1155 -482 783 799 1036 352 972 1811 1441 41 -359 -367 -175 145 -847 -427 865 0 -178 -777 -503 325 1080 -1295 63 -839 -1169 -441 -914 900000 -460 -419 -1533 -839 -180 229 501 -2235 648 -1305 176 -56 -520 91 -322 323 -187 397 668 -345 750 65 -69 221 249 -42 196 21 87 -825 116 -103 664 1451 820 254 23 640 335 1579 -260 936 -1496 278 816 -125 296 1120 1210 1953 118 561 1345 429 564 2047 395 -303 -1019 -1057 -97 271 -303 -911 -770 -965 -200 -261 351 436 -1776 -937 -1837 -1375 -2524 -3718 -1877 -1922 -786 -1427 -263 -202 -603 44 -710 8 939 2169 3271 3956 5178 3409 2558 2998 1890 2918 875 -1435 -2521 -2694 -2316 188 -462 25 -1423 -599 -604 -581 -370 210 -398 -2121 -1954 -1980 -794 1234 1217 1507 532 1399 2656 2222 72 -644 -698 -346 285 -1806 -958 1851 1 -395 -1664 -1075 652 2206 SS 20220628T104946.1Z 8214.451228 66 1 51.78 2 77.55 69.34 70.65 67.66 0.00 1 0.00 1 0 25 1.294e-01 1.355e-02 3.672e-02 1.519e-03 5.209158e-01 7.705223e-04 5.870263e-03 -6.000000e+00 7.287880e-02 228.26 -2.00 3.11 -2.00 319.94 0.00e+00 -3.862206e-03 2.593605e-04 2.912290e-03 -6.000000e+00 3.378723e-03 294.96 -2.00 20.00 -2.00 319.07 0.00e+00 4.505 0.000 302.00 328.00 3 2.1701e+00 2.3322e-03 5.2048e-02 -6.0000e+00 1.8061e-01 -5.1042e-02 2.8728e-03 2.9945e-02 -6.0000e+00 1.9572e-01 -2.8000e-02 2.3889e-03 1.3543e-02 -6.0000e+00 1.1743e-01 1.6300e-02 1.2395e-03 3.2962e-03 -6.0000e+00 5.0646e-02 4.3337e-04 1.5967e-04 4.1609e-05 5.2492e-05 -6.0000e+00 3.3166e-03 1.3622e-02 -3.6462e-05 12 8 8 10 0 0 99.26 22.85 0.32 0.01362 0.01482 106 17 1 5 0 488.380 25.79 20.01 22.85 32.39 13.5 1074.78 -66352 -24822 -56491 -40131 -24055 -52237 4131 -39310 -31350 -52107 -32605 -18806 -17157 14517 -32405 17363 -14168 -1015 -3195 1511 -3868 -8267 2797 -6686 11735 9193 1296 9782 1537 -5113 3311 401 -3984 -2075 -3384 10 -5579 49 997 1711 5886 3978 2329 1941 3769 1097 1783 -1229 1870 -2339 1147 1133 -155 -39 1826 2052 2733 812 1919 3661 1794 2124 2981 2049 -479 -1252 -1469 -385 -45 -778 -1492 -1142 -1498 -578 -519 -75 27 -1861 -1324 -2874 -2340 -3472 -4208 -2431 -1880 -1413 -1144 -841 -622 -404 103 -535 445 1633 2704 3176 4106 4764 3426 2213 2396 2004 2574 1281 -1448 -2252 -2193 -1088 95 123 -66 -862 -519 -589 -493 -131 -61 -309 -864 -1439 -1088 -340 474 347 871 293 1363 2012 1088 -115 -421 -297 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