File name: Pandora29s1_Fajardo_20220804_L2Fit_fout2c17d20220426p1-8.txt File generation date: 20260429T100418.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v17d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20220804_L1_smca1c17d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20220804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0234 305.1644 305.3054 305.4464 305.5874 305.7283 305.8693 306.0102 306.1512 306.2921 306.4330 306.5739 306.7148 306.8557 306.9966 307.1374 307.2783 307.4191 307.5599 307.7007 307.8415 307.9823 308.1231 308.2639 308.4046 308.5454 308.6861 308.8268 308.9676 309.1083 309.2490 309.3896 309.5303 309.6710 309.8116 309.9522 310.0929 310.2335 310.3741 310.5147 310.6552 310.7958 310.9364 311.0769 311.2174 311.3579 311.4985 311.6390 311.7794 311.9199 312.0604 312.2008 312.3413 312.4817 312.6221 312.7625 312.9029 313.0433 313.1837 313.3240 313.4644 313.6047 313.7451 313.8854 314.0257 314.1660 314.3062 314.4465 314.5868 314.7270 314.8673 315.0075 315.1477 315.2879 315.4281 315.5683 315.7084 315.8486 315.9887 316.1288 316.2690 316.4091 316.5492 316.6893 316.8293 316.9694 317.1094 317.2495 317.3895 317.5295 317.6695 317.8095 317.9495 318.0895 318.2294 318.3694 318.5093 318.6492 318.7891 318.9290 319.0689 319.2088 319.3487 319.4885 319.6284 319.7682 319.9080 320.0478 320.1876 320.3274 320.4672 320.6069 320.7467 320.8864 321.0261 321.1659 321.3056 321.4452 321.5849 321.7246 321.8642 322.0039 322.1435 322.2831 322.4228 322.5623 322.7019 322.8415 322.9811 323.1206 323.2602 323.3997 323.5392 323.6787 323.8182 323.9577 324.0971 324.2366 324.3760 324.5155 324.6549 324.7943 324.9337 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220804T104019.1Z 8251.444666 51 1 51.42 2 81.99 74.49 159.53 68.09 0.00 1 0.00 1 0 25 5.790e-01 1.759e-02 2.821e-01 4.223e-03 7.589574e-01 2.331934e-03 7.955559e-03 -6.000000e+00 3.345281e-01 227.46 -2.00 3.11 -2.00 321.49 0.00e+00 -3.990742e-03 1.329536e-03 5.401129e-03 -6.000000e+00 1.741669e-02 294.91 -2.00 20.00 -2.00 320.83 0.00e+00 6.702 0.001 302.00 328.00 3 1.0037e+00 9.1841e-03 8.0700e-02 -6.0000e+00 8.2666e-01 2.7320e-01 1.3279e-02 5.5401e-02 -6.0000e+00 8.9848e-01 -4.0578e-01 1.2751e-02 2.1230e-02 -6.0000e+00 5.3821e-01 1.6739e-01 5.8941e-03 6.5993e-03 -6.0000e+00 2.3254e-01 1.3256e-04 -3.9293e-04 1.1752e-04 8.2659e-05 -6.0000e+00 1.5795e-02 1.1323e-02 0.0000e+00 12 9 8 11 8 0 72.01 22.84 0.51 0.01132 0.00837 56 9 1 5 0 918.050 25.79 20.00 22.84 31.31 14.3 1059.49 -227097 900000 -90747 -233750 35397 -106391 900000 -73488 -48869 -210239 -175364 900000 900000 900000 -139289 900000 -91037 69271 54956 900000 900000 -25616 54593 211235 24266 900000 1941 118061 251924 -26477 900000 26473 -29234 49255 -4463 158213 -70115 20882 -36851 25753 51864 3093 8944 10417 26113 8085 56173 16329 56138 1781 15914 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-3284 -718 -1340 -320 -3287 -543 20 -14 1530 1914 939 -1035 -1527 -2787 -164 550 1820 2138 113 2264 4872 1834 -332 -256 590 82 1633 -3109 -1430 4143 -542 -919 -2606 -1940 -193 2040 SS 20220804T105627.2Z 8251.455870 56 1 50.57 2 78.29 75.59 156.12 72.49 0.00 1 0.00 1 0 25 1.560e-01 1.356e-02 2.972e-02 1.121e-03 5.652908e-01 5.729126e-04 6.425223e-03 -6.000000e+00 8.891320e-02 227.46 -2.00 3.11 -2.00 320.05 0.00e+00 -2.618070e-03 2.027466e-04 3.686949e-03 -6.000000e+00 4.131449e-03 294.91 -2.00 20.00 -2.00 319.19 0.00e+00 4.768 0.000 302.00 328.00 3 7.5619e-01 1.7564e-03 5.6516e-02 -6.0000e+00 2.1982e-01 1.0704e-02 2.1868e-03 3.6101e-02 -6.0000e+00 2.3817e-01 -5.6818e-02 1.8598e-03 1.4163e-02 -6.0000e+00 1.4303e-01 1.9873e-02 9.5839e-04 4.2404e-03 -6.0000e+00 6.1530e-02 1.2903e-03 -7.4417e-05 3.0959e-05 5.3410e-05 -6.0000e+00 4.1896e-03 1.0430e-02 0.0000e+00 12 8 8 10 0 0 45.58 22.82 0.42 0.01043 0.00987 206 32 1 5 0 245.430 25.68 20.01 22.82 31.80 14.3 1062.16 -68345 -36200 -48151 -61160 -71038 -48874 -48904 -45303 -31403 -57830 -52105 -13488 -15085 7566 -27096 8335 -13438 242 -10047 1428 -4045 -5460 -4094 3407 3685 5607 3927 1289 422 -4888 7181 1889 -4301 615 -2576 591 -6100 291 -1641 1775 5927 1924 2453 3035 3242 1467 2783 272 861 1096 2131 464 965 646 1721 2387 1901 404 1112 2890 2343 1625 1934 743 -1538 -1268 -478 -64 1265 -691 -1513 -1105 -1564 -528 -1027 -4 278 -219 -24 -2024 -2053 -2498 -3706 -2147 -1978 -1524 -1348 -1367 -846 -891 -540 -759 744 2286 2508 2496 3650 3886 2329 1392 2059 3008 4365 3152 -476 -1656 -1645 -1624 -558 -379 -953 -1383 -956 -657 -177 721 729 306 -603 -1504 -1499 -382 300 -21 428 106 1742 2843 915 -229 -600 -193 209 228 -640 -831 102 50 -438 -719 -342 526 1536 -754 -340 -552 -789 -924 -497 -545 -569 -401 -1074 -962 -184 -252 125 -776 199 -445 8 -381 51 -159 -220 -171 147 176 283 208 67 21 -267 396 129 -359 53 -222 48 -587 31 -223 284 1040 345 459 576 616 288 544 56 180 242 513 127 288 211 595 860 716 156 414 1035 861 653 799 348 -774 -617 -224 -30 649 -417 -947 -726 -1032 -329 -593 -2 142 -111 -13 -1237 -1461 -1892 -3122 -1891 -1863 -1430 -1332 -1396 -862 -878 -529 -692 635 1942 2187 2499 3894 4437 2938 1675 2454 3227 4522 3338 -532 -1980 -2063 -2166 -798 -567 -1496 -2298 -1578 -1037 -276 1060 1073 473 -948 -2503 -2499 -610 486 -34 641 154 2530 4208 1452 -388 -1057 -360 385 444 -1283 -1762 220 109 -926 -1536 -688 1042 2926 SS 20220804T111911.2Z 8251.471658 68 1 48.24 2 73.05 77.06 151.18 77.13 0.00 1 0.00 1 0 33 2.824e-02 1.424e-02 2.832e-03 4.077e-04 4.029310e-01 2.049946e-04 4.532637e-03 -6.000000e+00 1.609182e-02 227.46 -2.00 3.11 -2.00 318.36 0.00e+00 -8.206114e-04 4.193768e-05 1.430124e-03 -6.000000e+00 7.477055e-04 294.91 -2.00 20.00 -2.00 317.39 0.00e+00 3.378 0.000 302.00 328.00 3 3.3312e-01 5.6136e-04 3.8478e-02 -6.0000e+00 3.9784e-02 -2.4479e-02 6.4400e-04 2.0504e-02 -6.0000e+00 4.3104e-02 7.3540e-04 4.2604e-04 9.2510e-03 -6.0000e+00 2.5886e-02 -6.0625e-03 2.2418e-04 2.6777e-03 -6.0000e+00 1.1136e-02 8.7282e-03 5.9870e-05 1.1437e-05 2.8285e-05 -6.0000e+00 7.5821e-04 1.0064e-02 0.0000e+00 12 8 8 10 0 0 60.07 22.84 0.37 0.01006 0.01051 608 96 1 5 0 79.330 25.79 20.03 22.84 31.95 14.4 1063.81 -10363 -7564 -8509 -11476 -11928 -9285 -8013 -5754 -4199 -7729 -5184 -2672 -610 134 -2546 434 -931 478 167 1276 -92 894 2896 2019 2190 2260 1473 1427 760 2341 2412 1159 491 -2688 -2495 -649 -290 515 22 -187 -72 26 48 204 987 219 21 -136 -267 403 1330 432 378 359 504 1031 309 394 666 1523 2131 1762 1502 559 -1574 -1020 -106 460 1397 -935 -1415 -1176 -1411 -667 -836 -171 591 488 875 -1213 -1767 -2253 -3361 -2036 -1625 -1464 -1425 -1570 -850 -885 -576 -544 935 2545 2661 2764 3755 4074 2490 1762 2244 3189 4408 3377 -291 -1432 -1678 -1512 -615 -374 -1038 -1482 -1197 -1069 -310 515 491 180 -499 -1455 -1517 -553 18 81 473 95 1814 2747 865 -187 -718 -306 121 196 -570 -845 -255 -85 -439 -494 -120 594 1679 -411 -334 -404 -545 -513 -373 -340 -273 -225 -468 -313 -165 -43 11 -258 49 -105 57 21 168 -13 123 402 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