File name: Pandora29s1_Fajardo_20221021_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240212T223713.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20221021_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20221021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20221021T104732.2Z 8329.449678 93 1 51.31 2 84.00 103.47 36.43 94.20 0.00 1 0.00 1 0 25 7.978e-01 6.583e-02 3.237e-01 1.833e-02 7.659047e-01 1.055782e-02 8.149773e-03 -6.000000e+00 4.635220e-01 226.98 -2.00 3.11 -2.00 321.82 0.00e+00 2.796335e-02 5.325351e-03 1.119511e-02 -6.000000e+00 2.606732e-02 294.10 -2.00 20.00 -2.00 321.19 0.00e+00 8.521 0.003 302.00 328.00 3 1.4687e+00 4.0937e-02 1.3423e-01 -6.0000e+00 1.1512e+00 1.5704e+00 4.9068e-02 1.5083e-01 -6.0000e+00 1.2573e+00 -1.6662e+00 2.7460e-02 1.7888e-02 -6.0000e+00 7.4949e-01 6.0819e-01 1.4657e-02 4.1767e-02 -6.0000e+00 3.2790e-01 9.7159e-06 -2.7737e-03 5.3050e-04 2.5505e-04 -6.0000e+00 2.2301e-02 2.4790e-02 -3.0184e-04 12 8 8 10 0 0 98.73 22.70 0.56 0.02479 0.00395 13 2 1 5 0 3945.960 25.47 19.99 22.70 31.87 16.3 1048.25 -14956 900000 -16474 900000 900000 4196 23164 900000 900000 -83649 -13980 900000 900000 900000 -34997 900000 31477 227251 900000 900000 412757 52963 900000 900000 83407 900000 8881 167495 900000 92175 900000 57316 84374 104889 49876 900000 -63108 189937 213364 900000 243310 77900 -27725 7976 269682 9323 900000 5481 900000 -14846 30635 900000 224770 59376 169719 24563 60850 644 22852 900000 105883 45234 236635 31259 71214 99760 23842 58102 23581 -1517 24773 5997 -13796 -12695 36969 39127 84529 -33209 -30846 7172 39145 12421 -23521 -4738 -2891 28089 13277 15379 7142 -412 27886 2496 -5505 -4542 -7461 -2037 2682 6221 -3977 -6975 27355 -10269 13000 -9181 -5839 -7326 -2705 -10258 839 -2221 5113 -3936 -4331 841 2810 -2939 -1581 402 -9724 520 -3839 3645 5196 5513 6709 4388 297 4901 6542 -3386 -383 3191 -1537 4394 -2388 899 14228 -4422 -1179 -2048 -2450 -1437 -1815 -1669 900000 -2105 900000 900000 251 974 900000 900000 -7305 -543 900000 900000 900000 -3962 900000 2393 4043 900000 900000 7343 2741 900000 900000 2293 900000 445 2980 900000 2296 900000 3059 3903 4105 3017 900000 -10553 3379 3796 900000 4329 4435 -4686 965 4798 1144 900000 731 900000 -2588 3652 900000 4399 6338 6039 3627 6062 111 2968 900000 6028 5231 4631 5450 8868 9051 4496 7856 4824 -453 6170 1835 -4958 -4133 6511 5917 7519 -9807 -10207 1978 9262 4397 -13055 -2276 -1435 10793 6165 7168 3608 -216 10219 1097 -2517 -2133 -4128 -1156 1722 4528 -3570 -6509 16944 -8237 7338 -6385 -4240 -5722 -2353 -10456 854 -2675 6495 -5902 -6618 1190 3719 -3974 -2147 567 -14720 815 -6187 5194 7016 7199 8342 5418 369 6130 9357 -5619 -688 5981 -3200 9195 -5755 2209 31178 -11871 -3066 -5135 -5748 -3107 -3772 SU 20221021T105830.9Z 8329.457302 114 1 12.55 2 81.47 104.42 33.89 95.42 0.00 1 0.00 1 0 25 5.001e-01 2.175e-02 3.192e-01 9.161e-03 6.376500e-01 4.841561e-03 7.049674e-03 -6.000000e+00 2.825808e-01 226.98 -2.00 3.11 -2.00 321.17 0.00e+00 -4.611072e-03 2.447234e-03 4.791797e-03 -6.000000e+00 1.389212e-02 294.10 -2.00 20.00 -2.00 320.45 0.00e+00 6.346 0.001 302.00 328.00 3 2.0982e+00 1.7626e-02 7.2944e-02 -6.0000e+00 6.9954e-01 8.8474e-02 2.3842e-02 4.3616e-02 -6.0000e+00 7.6058e-01 -2.6296e-01 2.1841e-02 1.8141e-02 -6.0000e+00 4.5449e-01 1.2402e-01 1.0498e-02 4.3303e-03 -6.0000e+00 1.9673e-01 7.5509e-05 -1.6985e-04 2.5466e-04 8.6141e-05 -6.0000e+00 1.3187e-02 2.2156e-02 -9.6625e-05 12 9 9 12 1 1 97.06 22.71 0.54 0.02216 0.02088 8 6 1 5 0 1374.450 25.47 20.00 22.71 32.06 16.3 1049.71 -192100 900000 -166409 -159835 900000 -58253 -194370 900000 -113781 -20387 -143532 900000 12254 -49248 -130105 900000 -95821 105145 2636 56957 -40503 -34125 96845 -438 -21338 79286 107773 -25674 118652 25599 235506 661 -24061 55354 -9256 78014 -28006 27617 26104 5942 30410 -6074 8351 14442 31444 18206 18115 14534 22608 -6856 7147 5132 15893 2679 17076 2230 11244 -1065 -1977 21314 10348 6678 15265 3275 3773 -978 4136 -343 1469 -2741 1124 1438 -5403 1158 430 3826 -1128 -11529 -5761 -5562 1739 -2861 -6293 -5168 -4400 -248 -334 -168 -1993 -464 1891 612 5140 4283 4845 4758 5069 3645 1954 2080 2119 -545 273 -3198 -3221 -4565 -3513 -4030 506 320 126 -424 -1568 981 520 -198 -698 232 -1482 -1080 -2215 63 1801 2185 2628 1774 1840 3428 1545 -664 -399 753 264 -285 -1079 -55 2127 -498 -860 -1148 -211 140 -155 -3429 900000 -2836 -2711 900000 -520 -4511 900000 -1625 -182 -3203 900000 109 -703 -5110 900000 -3507 939 42 559 -1085 -853 864 -9 -629 920 962 -825 1059 480 2102 22 -1181 1334 -405 1393 -1600 1085 1305 446 2036 -629 783 1289 2358 1576 1585 1349 2018 -875 887 733 2241 474 2805 448 2158 -232 -420 3481 1921 1407 3352 918 1111 -293 1156 -103 483 -1098 483 588 -2354 493 169 1298 -373 -4260 -2242 -2343 798 -1583 -3978 -3430 -3120 -181 -258 -134 -1622 -359 1330 409 3153 2728 3452 3610 4434 3722 2051 2181 2257 -538 245 -3013 -3316 -5046 -4058 -5024 660 435 191 -685 -2570 1513 761 -279 -1000 347 -2403 -1826 -3763 101 2745 3214 3703 2437 2635 5045 2432 -1206 -737 1463 540 -624 -2395 -127 4928 -1209 -2096 -2686 -460 308 -331 SU 20221021T110016.9Z 8329.458529 117 1 52.03 2 81.07 104.58 33.48 95.62 0.00 1 0.00 1 0 25 4.860e-01 1.781e-02 2.380e-01 3.313e-03 6.276833e-01 1.714040e-03 7.039581e-03 -6.000000e+00 2.724584e-01 226.98 -2.00 3.11 -2.00 321.01 0.00e+00 -4.282076e-03 8.274476e-04 4.873508e-03 -6.000000e+00 1.264225e-02 294.10 -2.00 20.00 -2.00 320.28 0.00e+00 6.091 0.001 302.00 328.00 3 1.9090e+00 6.0345e-03 7.0659e-02 -6.0000e+00 6.7365e-01 3.9235e-02 8.1550e-03 4.3408e-02 -6.0000e+00 7.3203e-01 -1.5453e-01 7.6766e-03 1.8066e-02 -6.0000e+00 4.3938e-01 7.2667e-02 3.7239e-03 4.1722e-03 -6.0000e+00 1.8887e-01 1.1569e-04 -1.0500e-03 9.0645e-05 8.8996e-05 -6.0000e+00 1.2463e-02 2.4879e-02 -2.7851e-04 12 8 8 10 0 0 99.03 22.71 0.45 0.02488 0.01699 58 9 1 5 0 895.940 25.58 20.00 22.71 32.16 16.4 1050.34 -139460 -94559 -186351 62571 103237 -159367 -116652 171199 118213 -134479 -73785 213201 193220 30472 -136160 900000 -60328 46750 10713 25715 24363 -45989 35626 2545 28670 102315 -11619 17756 15417 7879 80001 6476 1995 -437 -776 23558 -22215 -774 12748 14585 19831 4516 -3688 3039 7861 -1870 21776 1076 19318 -8834 2289 13959 5961 1428 3584 6326 7280 224 1854 13679 5551 1702 10182 1374 1626 1492 -2215 596 651 -2569 -2376 -1573 -603 -1262 1914 1906 5007 -5292 -5854 -5172 -1072 -3784 -6241 -4112 -2799 -1378 -946 -651 -558 -545 1432 883 2226 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