File name: Pandora29s1_Fajardo_20221127_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240212T232157.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20221127_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20221127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221127T110535.0Z 8366.462211 44 1 51.07 2 84.36 114.53 133.13 109.14 0.00 1 0.00 1 0 25 6.738e-01 4.935e-02 2.308e-01 1.593e-02 8.168092e-01 8.600759e-03 8.769187e-03 -6.000000e+00 3.780024e-01 225.74 -2.00 3.11 -2.00 321.66 0.00e+00 -8.410600e-03 3.387873e-03 6.102386e-03 -6.000000e+00 1.845882e-02 292.96 -2.00 20.00 -2.00 320.94 0.00e+00 8.944 0.003 302.00 328.00 3 9.1168e-01 2.9898e-02 1.0004e-01 -6.0000e+00 9.3033e-01 1.5133e+00 3.6060e-02 5.2940e-02 -6.0000e+00 1.0120e+00 -1.7444e+00 2.0919e-02 2.2064e-02 -6.0000e+00 6.0833e-01 6.6342e-01 1.1077e-02 5.2026e-03 -6.0000e+00 2.6329e-01 1.3055e-05 -1.0626e-03 4.3437e-04 1.5036e-04 -6.0000e+00 1.7484e-02 1.6467e-02 -1.0165e-04 12 9 8 11 40 0 -11.26 21.21 0.21 0.01647 0.00848 20 3 1 5 0 2553.200 25.58 19.97 21.21 29.96 17.3 1031.90 15956 370051 -1568 31894 65763 -38166 7006 387339 6355 -52374 -37863 30060 900000 900000 -37719 900000 -13798 62733 242947 115419 149471 -22357 12235 63264 -1935 900000 22091 96047 62008 409 900000 21689 2797 45438 35053 21198 -45907 30809 70418 900000 15264 25815 -10471 38 84144 -21029 242043 5980 95288 -44324 17855 15475 103675 5303 65104 26938 68364 -13692 22007 113582 42385 29484 172594 27704 30630 39781 -7251 18405 520 5544 72978 3572 -19547 -11598 9651 17995 33619 -34885 7804 -6194 15666 -5934 -9346 -4751 14512 21473 11316 15692 -2254 -805 10529 -11948 -7054 -8321 -9508 -1153 3210 3627 -2094 -1949 15234 -4709 -1668 -9606 -1912 -4391 -2465 -8684 1802 -2025 3844 -4240 585 2067 1864 -2275 1728 -2925 -8765 1221 -4606 -623 4335 5091 6057 3044 1634 5002 5486 -374 -825 1048 -1676 2823 -3635 2947 2804 -1134 1147 -994 -612 -2644 -1655 1508 5742 -173 2160 2505 -3553 415 6010 430 -6501 -3899 1569 900000 900000 -5534 900000 -1791 3805 3770 3907 3374 -2555 966 3213 -199 900000 1714 3428 2694 32 900000 1716 295 3243 2502 1579 -6910 2438 4480 900000 2179 3405 -1966 6 5484 -3752 3756 779 5175 -10110 2383 2329 6917 1012 7172 4473 7638 -3378 3517 6697 4933 4117 6427 4944 5608 6420 -1834 3713 137 1600 11777 1192 -8007 -4049 2426 3630 5321 -11042 1804 -1970 4716 -2560 -4626 -2374 6350 9296 5654 7670 -1308 -441 4770 -6359 -3481 -4351 -5739 -685 2133 2788 -1891 -1773 10959 -3700 -1136 -7033 -1405 -3506 -2242 -9082 1888 -2532 5171 -6113 906 3104 2686 -3290 2424 -4516 -13860 1817 -7140 -971 6196 7031 8016 4038 2128 6629 8411 -639 -1587 2143 -3747 6467 -9593 7694 7468 -3188 3141 -2645 -1505 -6150 -3643 SS 20221127T111950.8Z 8366.472116 47 1 51.50 2 81.30 115.83 130.11 109.27 0.00 1 0.00 1 0 25 3.255e-01 1.569e-02 1.075e-01 2.366e-03 6.146709e-01 1.212871e-03 6.697363e-03 -6.000000e+00 1.814290e-01 225.74 -2.00 3.11 -2.00 320.92 0.00e+00 -5.770787e-03 5.705148e-04 3.469236e-03 -6.000000e+00 8.421508e-03 292.96 -2.00 20.00 -2.00 320.19 0.00e+00 6.233 0.001 302.00 328.00 3 1.2311e+00 4.2199e-03 6.9116e-02 -6.0000e+00 4.4728e-01 2.6402e-02 5.6324e-03 3.5078e-02 -6.0000e+00 4.8594e-01 -1.7107e-01 5.2354e-03 1.7867e-02 -6.0000e+00 2.9176e-01 8.4178e-02 2.5578e-03 5.0805e-03 -6.0000e+00 1.2613e-01 2.0629e-04 -3.0647e-04 6.4686e-05 9.1071e-05 -6.0000e+00 8.3383e-03 1.6795e-02 -1.3186e-04 12 9 8 11 8 0 30.03 21.20 0.40 0.01680 0.01449 109 17 1 5 0 472.340 25.58 19.97 21.20 30.64 17.3 1036.32 -135193 -50893 -114985 -125073 -126290 -83658 -55397 -57988 -49725 -121361 -118874 4229 -2721 55720 -93954 110988 -43383 -16689 -11243 6202 2430 -16703 -12565 -8346 -2304 58707 4877 30989 5959 -13856 19395 4632 -1532 5329 -6351 3154 -12371 -2971 10114 9119 11823 2194 6011 4962 8133 2109 12136 1862 2385 -2543 1919 7687 1225 996 2131 4829 7193 582 5573 5545 3384 2319 6553 1051 -40 -1198 -2771 -345 -855 -236 -2821 -713 -2213 -100 310 55 920 -4638 -3379 -3489 -2408 -3590 -4966 -3408 -2781 -1473 -364 -1034 -408 -603 590 828 2862 3584 5016 5288 4754 4297 3359 2044 1795 240 -89 -2270 -3880 -4259 -2858 -1630 456 -223 191 -634 -45 -143 -18 336 78 -239 -1109 -1041 -835 -26 992 738 1270 915 1841 2395 1189 -198 -429 -87 -195 -46 -1009 -543 655 40 -94 -918 -489 206 1067 -1560 -294 -1353 -1587 -1457 -618 -345 -441 -413 -2324 -2331 26 -22 309 -2840 512 -1041 -335 -231 113 48 -397 -304 -221 -65 975 143 665 154 -448 519 169 -69 245 -314 138 -702 -184 693 778 1127 248 685 579 916 255 1338 232 308 -367 295 1261 236 212 481 1122 1713 149 1317 1272 806 608 1867 325 -13 -389 -894 -112 -308 -99 -1353 -353 -1111 -47 133 21 324 -1725 -1373 -1687 -1350 -2342 -3329 -2389 -2085 -1173 -303 -896 -353 -505 456 596 1934 2460 3793 4614 4441 4633 3723 2300 1902 251 -86 -2261 -4290 -5013 -3498 -2112 587 -324 307 -1018 -72 -237 -28 498 117 -376 -1757 -1730 -1380 -40 1615 1167 1921 1343 2571 3453 1963 -349 -830 -166 -393 -98 -2207 -1249 1523 95 -225 -2131 -1066 446 2222 SS 20221127T113211.1Z 8366.480684 52 1 51.28 2 78.68 117.04 127.49 109.45 0.00 1 0.00 1 0 25 1.153e-01 1.612e-02 2.068e-02 1.028e-03 4.914194e-01 5.160768e-04 5.432662e-03 -6.000000e+00 6.427436e-02 225.73 -2.00 3.11 -2.00 319.84 0.00e+00 -2.520836e-03 1.696137e-04 2.099042e-03 -6.000000e+00 2.983564e-03 292.96 -2.00 20.00 -2.00 319.00 0.00e+00 4.917 0.000 302.00 328.00 3 1.1539e+00 1.5355e-03 5.4035e-02 -6.0000e+00 1.5846e-01 -6.6942e-02 1.8737e-03 2.5864e-02 -6.0000e+00 1.7215e-01 -2.1235e-02 1.5543e-03 1.2138e-02 -6.0000e+00 1.0336e-01 1.5533e-02 8.1074e-04 3.1611e-03 -6.0000e+00 4.4683e-02 8.5925e-04 -1.9546e-04 2.8472e-05 4.4382e-05 -6.0000e+00 2.9541e-03 1.6473e-02 -1.4943e-04 12 8 8 10 0 0 29.33 21.21 0.37 0.01647 0.01500 236 37 1 5 0 217.230 25.68 19.98 21.21 31.40 17.4 1041.51 -48790 -33417 -43235 -45063 -44954 -47000 -25965 -20953 -26717 -33878 -40762 -14358 -3507 8573 -25728 4536 -8803 -3415 3024 1399 891 -2020 1061 1165 3991 11896 3401 8768 -1666 -1004 6470 -288 1212 -455 -4471 -120 -2960 260 1613 4242 4328 2893 2578 2190 3547 1437 2419 -430 535 -1244 633 1653 67 371 942 1462 1742 487 1313 2097 2336 1719 2046 1406 -852 -1451 -1439 -1011 23 -996 -1821 -1088 -1503 -952 -777 -867 -280 -1602 -1541 -2429 -2466 -3065 -4052 -3006 -2014 -1535 -841 -1115 -522 -483 384 1577 3379 4859 5236 5331 5355 4922 3670 2436 1763 565 -134 -1261 -3658 -4076 -2868 -1235 240 189 -104 -742 -428 -630 -317 -100 -121 -227 -624 -1078 -890 -9 807 580 869 476 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