File name: Pandora29s1_Fajardo_20221202_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240212T234600.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20221202_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20221202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221202T110846.5Z 8371.464427 96 1 48.73 2 84.37 115.41 159.97 324.01 0.00 1 0.00 1 0 25 8.506e-01 5.927e-02 3.611e-01 1.731e-02 7.955520e-01 9.948765e-03 8.322029e-03 -6.000000e+00 4.946735e-01 225.57 -2.00 3.11 -2.00 322.03 0.00e+00 2.580518e-02 5.487882e-03 1.499976e-02 -6.000000e+00 2.587722e-02 292.79 -2.00 20.00 -2.00 321.44 0.00e+00 8.957 0.003 302.00 328.00 3 9.0791e-01 4.0809e-02 1.5530e-01 -6.0000e+00 1.2243e+00 1.5970e+00 4.9991e-02 1.8052e-01 -6.0000e+00 1.3414e+00 -1.7564e+00 3.1387e-02 2.5513e-02 -6.0000e+00 7.9938e-01 6.4347e-01 1.5991e-02 4.0680e-02 -6.0000e+00 3.4416e-01 1.1406e-05 -2.8548e-03 4.9485e-04 1.8602e-04 -6.0000e+00 2.3720e-02 1.7276e-02 -4.0833e-04 12 9 9 12 1 1 99.95 21.19 0.82 0.01728 -0.00418 18 3 1 5 0 2553.880 25.68 20.00 21.19 30.17 17.3 1032.67 111044 196537 79950 71979 900000 -53678 234939 900000 33815 -51242 -38744 900000 900000 900000 -46720 900000 14322 208498 900000 900000 900000 67422 133310 234129 67896 900000 22139 133754 900000 23448 900000 390577 132639 900000 139902 900000 -77024 127312 900000 900000 278270 40495 2809 36466 900000 -7696 900000 80072 213233 -33367 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2002 7620 8185 7883 212 100 11083 -5803 -3773 -3810 -1156 -4523 5501 4973 -2272 -2486 10625 722 -748 -7459 -3262 -5614 4119 -10323 2025 17 7547 -9382 -1560 -1119 1185 -3367 -4203 -3758 -14291 3474 -4999 904 6284 5574 8925 2042 2786 9749 4487 -2621 -2824 6298 -5834 4374 -5919 728 28275 -7837 3487 -1778 -4775 -5781 -6657 SS 20221202T112223.7Z 8371.473886 99 1 6.29 2 81.46 116.67 161.55 332.66 0.00 1 0.00 1 0 25 5.077e-01 2.006e-02 3.257e-01 1.032e-02 6.378290e-01 5.466755e-03 7.172607e-03 -6.000000e+00 2.889356e-01 225.57 -2.00 3.11 -2.00 321.09 0.00e+00 -8.031299e-03 2.698041e-03 4.879216e-03 -6.000000e+00 1.344872e-02 292.79 -2.00 20.00 -2.00 320.38 0.00e+00 6.342 0.001 302.00 328.00 3 1.7356e+00 1.9562e-02 7.2230e-02 -6.0000e+00 7.1478e-01 4.0942e-02 2.6611e-02 4.1281e-02 -6.0000e+00 7.8019e-01 -2.2881e-01 2.4952e-02 2.1017e-02 -6.0000e+00 4.6701e-01 1.1517e-01 1.1978e-02 5.8400e-03 -6.0000e+00 2.0006e-01 1.1117e-04 -2.9346e-04 2.9217e-04 1.1973e-04 -6.0000e+00 1.3213e-02 1.6185e-02 -1.4013e-04 12 9 9 12 9 1 99.18 21.19 0.34 0.01618 0.01398 6 9 1 5 0 871.570 25.68 20.00 21.19 30.57 17.4 1034.94 -179331 900000 -145105 -173326 35285 -223058 900000 133167 -138200 -113970 -168233 15817 194980 900000 900000 900000 -38887 900000 900000 17920 65413 -23943 71962 6432 14432 166617 59543 130069 -38199 1353 900000 -14508 59613 14575 25098 77050 -29599 -3836 -15894 46680 16873 -6923 190 5879 22304 -2198 22308 7103 19466 -15866 -5375 -1132 13997 6147 6626 10941 17099 -38 1103 17043 8445 -4374 3655 4866 2850 -1191 -1657 624 623 -1060 -1977 -488 20 653 4472 1962 1471 -5596 -4761 -4277 1297 -3921 -2590 -4971 -3485 -438 964 389 -2610 681 515 -1187 1871 2333 3900 3411 4412 4904 3482 2136 2161 -1176 -1078 -2570 -5068 -3438 -4834 -604 859 -454 -407 -1460 -283 -164 -1299 801 -980 -284 -2002 -688 -875 565 1410 1429 3337 1671 1529 2953 961 -410 -902 266 287 314 -345 -429 1893 -415 179 -1303 -1006 132 -274 -2622 900000 -1856 -3136 355 -5829 900000 1339 -2500 -1833 -4904 159 1960 900000 900000 900000 -782 900000 900000 252 657 -529 723 129 305 1675 898 1307 -1344 33 900000 -554 1258 527 782 1394 -1726 -208 -1230 2393 1340 -752 20 591 1883 -239 1906 721 1820 -2249 -767 -175 2054 1075 1245 2089 3231 -9 238 3032 1655 -1060 926 1379 874 -369 -506 192 213 -392 -825 -212 9 266 1610 712 497 -2030 -1727 -1837 619 -2272 -1640 -3430 -2551 -334 768 295 -2048 545 385 -846 1243 1584 2679 2728 4036 4740 3747 2337 2222 -1130 -945 -2315 -5114 -3620 -5446 -700 1073 -647 -600 -2312 -445 -250 -2031 1171 -1468 -444 -3153 -1121 -1421 872 2253 2213 4879 2404 2118 4189 1466 -717 -1741 504 571 665 -741 -975 4298 -982 422 -2992 -2166 283 -568 SS 20221202T113531.6Z 8371.483004 104 1 51.10 2 78.70 117.95 162.64 342.22 0.00 1 0.00 1 0 25 1.285e-01 1.627e-02 2.305e-02 1.032e-03 5.045764e-01 5.172941e-04 5.615698e-03 -6.000000e+00 7.158510e-02 225.57 -2.00 3.11 -2.00 319.94 0.00e+00 -3.170083e-03 1.740812e-04 2.316572e-03 -6.000000e+00 3.322558e-03 292.79 -2.00 20.00 -2.00 319.10 0.00e+00 4.926 0.000 302.00 328.00 3 1.1327e+00 1.5553e-03 5.4516e-02 -6.0000e+00 1.7642e-01 -7.5100e-02 1.9128e-03 2.6865e-02 -6.0000e+00 1.9170e-01 -2.2022e-02 1.6166e-03 1.2940e-02 -6.0000e+00 1.1510e-01 1.7014e-02 8.4023e-04 3.4169e-03 -6.0000e+00 4.9768e-02 8.6146e-04 -3.3169e-04 2.8508e-05 5.0001e-05 -6.0000e+00 3.2920e-03 1.6245e-02 -1.5353e-04 12 8 8 10 0 0 92.85 21.20 0.41 0.01625 0.01375 247 39 1 5 0 206.830 25.68 20.01 21.20 31.20 17.4 1039.41 -52152 -32512 -50491 -44108 -44455 -70847 -10809 -43451 -17781 -34504 -39759 -6775 -9843 7111 -31269 4150 -9817 -3007 6017 -252 1187 -7408 1657 2104 1713 9254 -762 6883 -103 736 7842 -3408 2992 -2488 -1707 -1056 -3879 1228 1152 5972 4496 3238 2702 3156 4379 1292 3628 445 1108 -451 484 768 -124 136 530 1691 1760 -31 1716 1804 2246 1626 2469 1240 -1165 -1211 -1732 -754 -284 -938 -1343 -1140 -1702 -733 -460 -480 -589 -1853 -1586 -2434 -2414 -2848 -4018 -3092 -1995 -1861 -1066 -1249 -497 -617 447 1480 3317 4976 5455 5332 5375 4988 3666 2371 1838 642 -59 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