File name: Pandora29s1_Fajardo_20221219_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240213T005722.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20221219_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20221219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221219T111811.1Z 8388.470961 168 1 51.71 2 84.55 116.90 37.29 145.25 0.00 1 0.00 1 0 45 6.188e-01 4.864e-02 2.965e-01 1.506e-02 7.762236e-01 8.462182e-03 8.505561e-03 -6.000000e+00 3.574759e-01 225.06 -2.00 3.11 -2.00 322.00 0.00e+00 -4.262463e-03 4.467740e-03 1.184793e-02 -6.000000e+00 1.867317e-02 292.26 -2.00 20.00 -2.00 321.39 0.00e+00 9.183 0.003 302.00 328.00 3 8.0021e-01 3.3836e-02 1.2078e-01 -6.0000e+00 8.8063e-01 1.2723e+00 4.3243e-02 1.0480e-01 -6.0000e+00 9.6302e-01 -1.5654e+00 2.8830e-02 3.5411e-02 -6.0000e+00 5.7674e-01 5.9869e-01 1.3821e-02 7.0053e-03 -6.0000e+00 2.4869e-01 1.3266e-05 -1.0433e-03 4.3965e-04 1.5643e-04 -6.0000e+00 1.6366e-02 1.8138e-02 -1.1014e-04 12 8 8 10 0 0 67.97 21.07 1.01 0.01814 0.01030 25 4 1 5 0 2067.940 25.58 20.01 21.07 29.41 17.6 1025.55 40836 171141 20263 154531 900000 -64484 900000 32671 33463 -43300 -81865 900000 900000 900000 -55861 900000 -22767 900000 900000 900000 193682 5712 900000 152963 16377 900000 -6933 102031 24164 88703 900000 90929 156337 24180 68641 900000 -57290 121212 66506 118829 170996 29124 -16248 47072 137717 24920 900000 65592 900000 -35280 25230 88172 124045 24481 73335 24250 69285 3365 53613 325731 37862 37461 128148 21037 33112 53263 2581 25093 11672 84 6864 8215 -10542 -2023 13330 17427 51029 -32130 -25712 10088 23575 19342 -17488 75 -1787 9966 17233 13535 3436 -3365 14545 -10866 -6849 -9005 -2843 2096 3393 6311 -703 -5241 15618 -8817 8103 -9479 -4455 -6643 -1459 -10444 2679 -7271 3913 -6683 279 1446 2546 -3272 -498 -175 -6778 -1015 -1936 3116 3325 3125 5232 3931 2857 6120 3540 859 -798 1765 1135 890 -3314 1988 6558 -3061 724 -2419 -2079 -612 -1103 1522 2506 944 2262 900000 -4291 900000 870 935 -2651 -7082 900000 900000 900000 -5799 900000 -1970 900000 900000 900000 2836 319 900000 2239 894 900000 -461 2241 1026 1948 900000 2529 2518 1522 2512 900000 -7046 2839 3213 4001 3755 2729 -2403 3584 4032 2189 900000 3745 900000 -5888 2512 5164 5448 3118 6013 3337 6188 567 5102 4769 3880 4113 6379 3449 5090 6472 510 4078 2375 22 1859 2273 -3442 -563 2849 3138 6051 -8844 -7453 2452 5902 5833 -8449 32 -832 4392 7392 6183 1731 -1744 5856 -5297 -3119 -4377 -1482 1113 2082 4376 -580 -4569 10393 -6724 4691 -6535 -3178 -5146 -1250 -10596 2651 -9123 4996 -9349 409 2059 3434 -4508 -676 -250 -10014 -1477 -3090 4521 4654 4274 6787 5030 3580 7823 5390 1409 -1489 3472 2388 2013 -8451 5088 16375 -8563 1951 -6420 -5128 -1386 -2413 SS 20221219T113151.2Z 8388.480453 171 1 51.73 2 81.67 118.15 35.63 150.01 0.00 1 0.00 1 0 25 3.702e-01 1.561e-02 1.458e-01 2.444e-03 6.113443e-01 1.259497e-03 7.070589e-03 -6.000000e+00 2.057281e-01 225.06 -2.00 3.11 -2.00 320.99 0.00e+00 -7.253150e-03 5.997097e-04 4.624616e-03 -6.000000e+00 9.549339e-03 292.26 -2.00 20.00 -2.00 320.28 0.00e+00 6.480 0.001 302.00 328.00 3 1.0635e+00 4.3548e-03 7.2391e-02 -6.0000e+00 5.0652e-01 -1.1366e-02 5.9107e-03 3.8963e-02 -6.0000e+00 5.5073e-01 -1.2470e-01 5.6835e-03 2.0253e-02 -6.0000e+00 3.3067e-01 6.0460e-02 2.7583e-03 5.8308e-03 -6.0000e+00 1.4299e-01 1.9885e-04 -7.1586e-04 6.7561e-05 1.0982e-04 -6.0000e+00 9.4835e-03 1.8245e-02 -2.0124e-04 12 8 8 10 0 0 98.05 21.07 0.41 0.01825 0.01287 121 19 1 5 0 427.460 25.58 19.99 21.07 30.12 17.6 1030.47 -133428 -107285 -127950 -96187 -85684 -122014 -81564 -38643 -98576 -123508 -113597 176986 4808 83906 -97303 2299 -58498 61374 -5891 25905 -29767 -17271 -24278 4047 19311 20343 -3852 11101 7505 -17395 50078 12904 -3218 8151 -2381 6280 -16383 -3958 -3050 2447 15910 -576 6091 9175 9805 3448 3819 1534 10454 -5665 4659 7686 2060 647 2716 4728 5921 3703 3501 8372 3141 396 5635 1445 -301 -1460 -2932 -1212 -648 -1443 -1103 -1359 -1083 -115 174 -122 1817 -4118 -3188 -4302 -2233 -4117 -5053 -2866 -2204 -1410 -585 -668 -814 -826 1785 373 3079 3863 5445 5031 4833 4725 2975 2208 1633 -141 -53 -2449 -3948 -4774 -2968 -1723 406 -276 253 -845 -361 -88 309 -111 400 -308 -1052 -1062 -797 82 933 833 1050 1043 1570 2723 1029 -55 -510 128 110 -76 -742 -410 134 -82 -195 -750 -357 204 977 -1208 -869 -1372 -734 -531 -1076 -544 -203 -1128 -2061 -1814 422 31 300 -2597 27 -1394 483 -98 333 -695 -358 -579 84 391 446 -111 262 172 -522 883 388 -132 326 -102 241 -879 -226 -219 206 1346 -62 643 951 1005 380 423 178 1154 -782 648 1174 367 129 572 1036 1349 871 800 1768 710 100 1534 464 -104 -494 -988 -414 -221 -582 -496 -646 -513 -52 72 -45 669 -1462 -1240 -2010 -1198 -2591 -3551 -2095 -1581 -1081 -470 -556 -681 -669 1313 284 2189 2789 3965 4255 4358 4900 3441 2578 1803 -143 -49 -2368 -4238 -5483 -3531 -2170 546 -390 396 -1416 -602 -141 466 -160 580 -472 -1736 -1843 -1376 135 1485 1287 1556 1495 2319 4128 1669 -95 -968 257 232 -160 -1691 -927 309 -193 -461 -1717 -816 438 2018 SS 20221219T114333.0Z 8388.488577 176 1 51.89 2 79.24 119.30 34.40 154.40 0.00 1 0.00 1 0 25 1.192e-01 1.616e-02 2.108e-02 1.006e-03 4.945941e-01 5.041076e-04 5.491671e-03 -6.000000e+00 6.623116e-02 225.05 -2.00 3.11 -2.00 319.91 0.00e+00 -3.206548e-03 1.696180e-04 2.150007e-03 -6.000000e+00 3.073537e-03 292.26 -2.00 20.00 -2.00 319.08 0.00e+00 5.152 0.001 302.00 328.00 3 9.3018e-01 1.5157e-03 5.6156e-02 -6.0000e+00 1.6307e-01 -7.9003e-02 1.8554e-03 2.5888e-02 -6.0000e+00 1.7728e-01 -2.4752e-02 1.5524e-03 1.2645e-02 -6.0000e+00 1.0645e-01 1.8346e-02 8.0679e-04 3.4456e-03 -6.0000e+00 4.6042e-02 8.7310e-04 -2.5850e-04 2.7980e-05 5.2173e-05 -6.0000e+00 3.0523e-03 1.7383e-02 -1.6901e-04 12 8 8 10 0 0 97.39 21.08 0.42 0.01738 0.01544 237 37 1 5 0 218.870 25.58 19.98 21.08 30.33 17.6 1030.66 -53099 -48728 -39150 -40396 -44158 -36810 -37896 -23753 -34855 -38403 -34574 -16115 -9238 -8935 -22566 -2259 -11550 2832 -3847 5189 -1389 -2223 3565 -478 5622 5745 4048 2368 -336 -3656 5708 353 -518 -1552 -4470 -1598 -3721 -177 3499 2438 5401 2502 3446 3857 3827 2032 1660 692 851 -615 1015 620 600 249 585 1601 1667 1080 1295 2421 1654 1739 2701 1177 -990 -1742 -1469 -1152 420 -923 -1338 -977 -1367 -842 -1033 -626 -270 -1756 -1301 -2651 -2608 -2959 -4161 -2873 -2316 -1320 -1099 -1280 -597 -658 476 1512 3335 4789 5332 5564 5171 5059 3614 2560 1817 713 -45 -1482 -3740 -3939 -2967 -1210 222 252 -66 -560 -552 -483 -316 32 50 -256 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