File name: Pandora29s1_Fajardo_20230102_L2Fit_fout2c17d20220426p1-8.txt File generation date: 20260429T102437.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v17d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230102_L1_smca1c17d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0234 305.1644 305.3054 305.4464 305.5874 305.7283 305.8693 306.0102 306.1512 306.2921 306.4330 306.5739 306.7148 306.8557 306.9966 307.1374 307.2783 307.4191 307.5599 307.7007 307.8415 307.9823 308.1231 308.2639 308.4046 308.5454 308.6861 308.8268 308.9676 309.1083 309.2490 309.3896 309.5303 309.6710 309.8116 309.9522 310.0929 310.2335 310.3741 310.5147 310.6552 310.7958 310.9364 311.0769 311.2174 311.3579 311.4985 311.6390 311.7794 311.9199 312.0604 312.2008 312.3413 312.4817 312.6221 312.7625 312.9029 313.0433 313.1837 313.3240 313.4644 313.6047 313.7451 313.8854 314.0257 314.1660 314.3062 314.4465 314.5868 314.7270 314.8673 315.0075 315.1477 315.2879 315.4281 315.5683 315.7084 315.8486 315.9887 316.1288 316.2690 316.4091 316.5492 316.6893 316.8293 316.9694 317.1094 317.2495 317.3895 317.5295 317.6695 317.8095 317.9495 318.0895 318.2294 318.3694 318.5093 318.6492 318.7891 318.9290 319.0689 319.2088 319.3487 319.4885 319.6284 319.7682 319.9080 320.0478 320.1876 320.3274 320.4672 320.6069 320.7467 320.8864 321.0261 321.1659 321.3056 321.4452 321.5849 321.7246 321.8642 322.0039 322.1435 322.2831 322.4228 322.5623 322.7019 322.8415 322.9811 323.1206 323.2602 323.3997 323.5392 323.6787 323.8182 323.9577 324.0971 324.2366 324.3760 324.5155 324.6549 324.7943 324.9337 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230102T113612.1Z 8402.483474 145 1 51.68 2 81.99 117.45 138.48 332.27 0.00 1 0.00 1 0 25 4.179e-01 1.540e-02 1.700e-01 2.742e-03 6.404409e-01 1.444441e-03 6.986015e-03 -6.000000e+00 2.360331e-01 224.83 -2.00 3.11 -2.00 321.09 0.00e+00 -3.261700e-03 7.145969e-04 4.423089e-03 -6.000000e+00 1.143999e-02 291.95 -2.00 20.00 -2.00 320.40 0.00e+00 6.705 0.001 302.00 328.00 3 4.9913e-01 5.1037e-03 7.5579e-02 -6.0000e+00 5.8055e-01 9.3316e-02 6.9599e-03 4.2686e-02 -6.0000e+00 6.3046e-01 -1.8753e-01 6.6712e-03 1.7700e-02 -6.0000e+00 3.7881e-01 8.0221e-02 3.2110e-03 4.6309e-03 -6.0000e+00 1.6404e-01 2.5898e-04 -6.4397e-04 7.7576e-05 8.1092e-05 -6.0000e+00 1.1259e-02 4.4770e-03 0.0000e+00 12 8 8 10 0 0 98.50 21.15 0.45 0.00448 -0.00036 94 15 1 5 0 549.640 25.58 20.00 21.15 29.90 18.0 1027.76 -180466 -81362 -144399 -128286 -13465 -81440 231798 -85839 -62573 -134563 -128534 900000 292 900000 -110876 94621 -85829 -13916 62132 29616 -14577 -11175 1197 9581 -20696 62778 -27534 20246 9925 21186 91654 -8110 1866 -840 3563 12790 -21187 -8854 -3450 12397 16302 1638 -269 7695 6885 2369 19812 -233 13187 -2422 -361 6701 692 4567 3935 5077 9443 1388 3369 10008 1247 2883 8133 4629 -129 1346 -2463 486 -223 -1177 -2247 -1402 -3343 -2304 856 972 2075 -3136 -3928 -2573 -689 -3161 -4911 -2298 -1959 -1838 -861 -803 -1022 -1150 628 1023 2731 4564 4106 4148 5091 3963 2019 1140 934 664 1778 -604 -3301 -4106 -2953 -2389 150 -528 -528 -1499 -552 -266 294 854 1065 581 -935 -1009 -1154 113 893 455 778 643 1801 3176 1280 -143 -317 101 29 518 -942 -623 504 -184 -128 -1179 -435 46 1248 -2412 -479 -1737 -1303 -40 -457 620 -643 -435 -2158 -2062 900000 2 900000 -3083 405 -2524 -219 498 348 -277 -206 20 169 -553 789 -883 390 202 396 980 -280 68 -35 137 438 -1110 -488 -224 845 1233 156 -27 743 672 245 1748 -26 1333 -305 -50 967 117 818 765 1030 1919 309 715 1935 267 659 2000 1337 -42 423 -789 156 -79 -443 -959 -628 -1531 -997 330 370 722 -1147 -1450 -1109 -343 -1861 -3271 -1591 -1451 -1339 -656 -634 -812 -888 486 738 1856 3108 2865 3359 4377 3965 2267 1307 1015 658 1592 -554 -3355 -4467 -3340 -2877 192 -767 -794 -2436 -897 -420 437 1298 1616 861 -1496 -1696 -1943 182 1379 684 1208 967 2586 4651 1994 -256 -584 198 60 1062 -2102 -1466 1204 -452 -316 -2827 -977 97 2682 SS 20230102T120112.6Z 8402.500840 156 1 51.75 2 76.79 119.96 140.70 340.29 0.00 1 0.00 1 0 25 4.029e-02 1.532e-02 1.725e-02 1.105e-03 4.192400e-01 5.537210e-04 4.827495e-03 -6.000000e+00 2.274594e-02 224.83 -2.00 3.11 -2.00 319.52 0.00e+00 -1.031569e-03 1.624705e-04 2.199313e-03 -6.000000e+00 1.053475e-03 291.95 -2.00 20.00 -2.00 318.66 0.00e+00 4.264 0.000 302.00 328.00 3 1.3121e+00 1.6042e-03 4.7212e-02 -6.0000e+00 5.5956e-02 -4.7249e-02 1.9197e-03 2.4273e-02 -6.0000e+00 6.0754e-02 2.4581e-03 1.4896e-03 1.0351e-02 -6.0000e+00 3.6493e-02 -2.0067e-03 7.8104e-04 2.9078e-03 -6.0000e+00 1.5753e-02 1.4308e-03 -8.2475e-05 3.1902e-05 3.4385e-05 -6.0000e+00 1.0807e-03 4.3797e-03 0.0000e+00 12 8 8 10 0 0 99.99 21.17 0.50 0.00438 0.00376 435 68 1 5 0 118.930 25.58 19.96 21.17 30.17 18.1 1029.39 -8718 -11935 -12449 -14431 -4473 -20527 8261 4536 -8150 -8618 -15027 4962 3026 8220 -6206 792 -5047 3249 5176 3679 2610 2062 5286 4357 3132 4839 1791 4737 2266 1523 7436 1690 2123 -1128 -2879 1386 -2675 2280 43 1514 1204 76 213 -366 1308 145 1189 -172 322 -442 151 237 -184 283 530 769 793 -198 619 1822 1772 1586 1836 907 -1902 -1198 -485 -107 1111 -1165 -1779 -1303 -1757 -901 -703 -409 217 -282 361 -1488 -1941 -2517 -3618 -2324 -1629 -1488 -1203 -1449 -797 -566 326 1402 3517 5559 5556 4978 5194 4789 2619 1521 1308 1162 1795 760 -2365 -3260 -2654 -1668 -220 -57 -549 -1287 -986 -1011 -279 510 538 361 -465 -1250 -1310 -314 368 118 727 288 1686 3073 1112 -7 -591 -264 63 311 -565 -825 -288 -92 -402 -628 -281 555 1625 -146 -238 -267 -309 -79 -405 131 86 -201 -235 -450 128 92 286 -298 41 -304 193 322 245 182 145 373 338 268 434 170 420 194 131 665 181 255 -151 -377 169 -368 351 8 347 314 19 57 -101 355 40 327 -48 90 -129 47 81 -69 113 224 336 358 -91 276 792 789 764 980 493 -1103 -659 -274 -60 658 -741 -1269 -977 -1332 -652 -473 -247 129 -164 221 -979 -1477 -2173 -3181 -2132 -1590 -1561 -1238 -1549 -853 -631 335 1318 3021 4609 4961 4690 5546 5411 3274 1922 1564 1275 1950 848 -2756 -4065 -3444 -2265 -315 -89 -875 -2150 -1620 -1578 -428 735 772 542 -705 -2027 -2160 -503 571 188 1105 422 2330 4247 1712 -12 -1024 -478 111 570 -1116 -1632 -583 -190 -839 -1278 -577 1080 3049 SS 20230102T121718.3Z 8402.512018 162 1 5.85 2 73.51 121.75 141.72 345.85 0.00 1 0.00 1 0 17 9.402e-02 2.001e-02 7.661e-02 1.031e-02 3.324878e-01 5.109308e-03 3.837078e-03 -6.000000e+00 5.310049e-02 224.83 -2.00 3.11 -2.00 318.49 0.00e+00 -3.056521e-04 1.078122e-03 1.265352e-03 -6.000000e+00 2.459173e-03 291.94 -2.00 20.00 -2.00 317.59 0.00e+00 3.466 0.000 302.00 328.00 3 3.7909e+00 1.3985e-02 3.7715e-02 -6.0000e+00 1.3063e-01 -4.0174e-02 1.6083e-02 1.7469e-02 -6.0000e+00 1.4181e-01 2.6174e-02 1.0690e-02 7.7203e-03 -6.0000e+00 8.5185e-02 -1.6156e-02 5.6208e-03 2.4237e-03 -6.0000e+00 3.6785e-02 2.8056e-04 4.0789e-04 2.9747e-04 2.5186e-05 -6.0000e+00 2.5219e-03 2.3096e-03 0.0000e+00 12 9 9 12 33 1 999.00 21.17 0.58 0.00231 0.00537 1 3 1 5 0 2838.670 25.58 20.02 21.17 30.08 18.0 1027.96 -50268 -19156 -23987 -26991 -9594 63426 20981 -12679 -3131 5161 3108 2578 20435 -8940 2611 6374 -10466 -2818 7617 22554 -10341 2435 10094 -6305 8380 -3854 6510 8147 -2812 18645 6133 14540 -5924 1094 1523 -2478 -7020 7686 8324 4354 -1249 -3104 -2133 -4102 2507 1463 1044 -4294 1230 124 2438 245 3969 -1289 437 -178 438 -3430 881 7489 3641 570 2916 1791 -274 1019 -830 -1571 1235 -4388 -2601 -2637 -3588 1957 -1154 -182 1398 -2251 533 -2439 865 -2863 -4542 -1129 -598 446 -1899 -30 -840 475 1327 560 2785 4020 6659 5002 4560 5961 2265 1052 460 165 1057 771 -2006 -3598 -3273 -3546 -762 -274 -399 -1285 -1031 -1344 -292 699 262 -316 -163 -544 -1658 -209 1525 1147 -2 1259 2388 4674 891 -792 -93 -95 407 -519 715 -195 -201 -362 -553 -854 -584 -244 1207 -3337 -1060 -1472 -1656 -444 1340 718 -689 -176 291 181 156 1172 -809 247 660 -1379 -363 935 2495 -1643 340 1340 -1059 1306 -717 1113 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