File name: Pandora29s1_Fajardo_20230111_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240213T023734.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230111_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230111T112634.8Z 8411.476791 249 1 52.54 2 84.43 115.19 52.54 270.79 0.00 1 0.00 1 0 25 5.881e-01 5.155e-02 2.688e-01 1.556e-02 7.468680e-01 9.541354e-03 7.581793e-03 -6.000000e+00 3.588004e-01 224.68 -2.00 3.11 -2.00 321.99 0.00e+00 2.170888e-02 5.590128e-03 1.030617e-02 -6.000000e+00 2.253490e-02 291.75 -2.00 20.00 -2.00 321.42 0.00e+00 9.038 0.003 302.00 328.00 3 9.7860e-01 3.9858e-02 1.2725e-01 -6.0000e+00 8.9322e-01 1.3448e+00 5.2068e-02 1.2947e-01 -6.0000e+00 9.9239e-01 -1.4278e+00 4.1037e-02 2.1343e-02 -6.0000e+00 5.8100e-01 5.1256e-01 1.9403e-02 3.0344e-02 -6.0000e+00 2.4982e-01 1.0725e-05 -1.2610e-03 4.8774e-04 1.8666e-04 -6.0000e+00 1.8302e-02 8.9739e-03 -4.5541e-05 12 9 8 11 32 0 -21.97 21.16 1.14 0.00897 -0.00050 19 3 1 5 0 2764.720 25.58 20.03 21.16 28.31 18.1 1016.85 135872 900000 -16661 900000 900000 900000 900000 900000 -29160 269021 30287 900000 900000 900000 77563 900000 -51644 900000 900000 900000 900000 900000 900000 900000 900000 900000 -69194 900000 900000 900000 900000 900000 900000 900000 900000 900000 -45154 900000 900000 900000 75146 97289 -20905 35952 213485 900000 900000 118593 900000 -17249 36711 203521 900000 102618 148206 69725 141464 1992 16780 900000 119451 79142 -23456 74885 55968 91737 2399 11429 14135 20685 -25615 15034 -24283 4177 49540 30516 89433 -28593 -15738 -10721 51416 1147 11922 518 -1812 40476 -1690 22266 3984 -1405 28891 -10197 3684 -6294 -2223 -2607 2761 8913 -1448 -863 15098 -9735 11661 -10477 -8727 -8475 -204 -7029 3792 -4317 2207 -1378 224 1001 -2525 -3425 -1292 45 -10838 2230 -1923 415 3959 4013 6424 4867 -784 3052 3668 -392 -2103 3658 -1006 469 -2819 2132 5003 1288 153 -1246 -2234 -2280 -1661 2044 900000 -866 900000 900000 900000 900000 900000 -838 4047 456 900000 900000 900000 1485 900000 -4803 900000 900000 900000 900000 900000 900000 900000 900000 900000 -5205 900000 900000 900000 900000 900000 900000 900000 900000 900000 -4416 900000 900000 900000 3278 3513 -2547 2542 3212 900000 900000 3925 900000 -2387 3203 3674 900000 5712 5351 5455 5321 291 1994 900000 5032 5477 -5187 7097 6904 7729 480 2115 2722 4263 -9210 3709 -8658 1037 7006 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9.5882e-05 -6.0000e+00 9.4187e-03 8.9091e-03 -4.3212e-05 12 8 8 10 0 0 17.58 21.15 0.44 0.00891 0.00751 114 18 1 5 0 452.640 25.58 20.03 21.15 29.03 18.0 1021.54 -158047 900000 -119727 -49583 -72807 -112036 78082 -74580 -47380 -117798 -89460 -33525 -5751 197518 -106580 132274 -81812 -2781 3801 38811 31442 -24179 57067 -14746 15099 34391 -14765 28756 3974 11465 7495 -1805 -4447 -1490 317 1734 -14354 -11129 7061 13151 12045 9591 1542 6830 11040 719 13368 1800 15787 -6174 1935 5549 575 2558 7 6484 5148 1543 4040 8786 4720 1325 7695 1287 440 273 -2779 139 -918 224 -3876 -1074 -2091 -1138 1511 -645 1788 -3718 -4415 -4246 -2071 -3261 -5563 -3186 -2682 -1212 -599 -1134 -267 -1301 1110 986 2946 4353 4769 5349 4930 4456 3345 1880 1610 -373 230 -2185 -4059 -4101 -3542 -1306 292 189 42 -499 -2 -300 97 191 528 104 -1054 -940 -1137 126 797 910 1180 579 1562 2122 1278 -50 -450 -99 -129 204 -834 -426 64 -60 28 -732 -457 309 1037 -1955 900000 -1282 -260 -433 -960 186 -586 -338 -1934 -1171 -271 -42 470 -3246 441 -2589 -44 61 462 419 -564 625 -379 327 671 -488 588 97 265 207 -64 -189 -68 14 72 -768 -691 460 1001 1072 947 173 739 1140 83 1374 212 1683 -870 280 877 105 506 1 1410 1194 376 931 1869 1057 333 2054 416 153 92 -947 47 -315 89 -1799 -513 -1013 -521 621 -242 664 -1318 -1732 -1974 -1107 -2033 -3941 -2344 -1935 -928 -482 -951 -224 -1067 829 752 2107 2864 3478 4487 4425 4623 3868 2065 1801 -386 215 -2104 -4346 -4671 -4227 -1632 392 265 65 -834 -3 -487 148 278 767 158 -1739 -1632 -1978 209 1272 1409 1751 836 2309 2987 2050 -85 -852 -200 -255 427 -1898 -961 147 -142 66 -1679 -1047 664 2133 SS 20230111T115327.7Z 8411.495459 257 1 51.72 2 78.72 117.73 58.81 272.61 0.00 1 0.00 1 0 25 9.958e-02 1.626e-02 1.778e-02 9.117e-04 4.806322e-01 4.562998e-04 5.330757e-03 -6.000000e+00 5.534128e-02 224.68 -2.00 3.11 -2.00 319.78 0.00e+00 -2.568643e-03 1.464807e-04 1.961460e-03 -6.000000e+00 2.563855e-03 291.74 -2.00 20.00 -2.00 318.96 0.00e+00 4.936 0.000 302.00 328.00 3 9.3099e-01 1.3501e-03 5.3881e-02 -6.0000e+00 1.3617e-01 -7.3924e-02 1.6373e-03 2.4924e-02 -6.0000e+00 1.4801e-01 -1.3383e-02 1.3495e-03 1.1921e-02 -6.0000e+00 8.8878e-02 1.1551e-02 7.0464e-04 3.1695e-03 -6.0000e+00 3.8519e-02 1.0698e-03 -9.7223e-05 2.5359e-05 4.5246e-05 -6.0000e+00 2.5493e-03 9.0179e-03 -7.6790e-05 12 8 8 10 0 0 18.04 21.15 0.40 0.00902 0.00829 302 48 1 5 0 171.230 25.58 20.03 21.15 30.29 18.2 1030.28 -41225 -19444 -44063 -29227 -34530 -46981 -29364 -27987 -26005 -26421 -30449 -12587 -11211 632 -16403 5369 -9505 -1755 113 -738 2669 -4171 3342 2671 3473 7033 620 4993 -157 -1356 4137 254 -140 -2185 -3261 -927 -3000 433 2117 4052 3721 3068 2437 2568 3570 1765 2089 -81 654 -407 621 1062 -275 726 778 1351 1442 306 1375 1918 2143 2113 2168 1197 -947 -1327 -1462 -1114 -84 -688 -1449 -1212 -1354 -809 -569 -757 -228 -1686 -1476 -2210 -2762 -2944 -4031 -2885 -2072 -1417 -1219 -1219 -633 -466 449 1614 3277 4961 5439 5248 5351 5049 3884 2536 1837 638 41 -1235 -3710 -4048 -2946 -1170 394 254 -126 -698 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