File name: Pandora29s1_Fajardo_20230209_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240213T043752.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230209_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230209T112113.7Z 8440.473075 240 1 51.73 2 84.41 107.50 63.22 262.63 0.00 1 0.00 1 0 25 7.561e-01 4.703e-02 3.366e-01 1.411e-02 7.963610e-01 8.233385e-03 8.139933e-03 -6.000000e+00 4.421389e-01 225.11 -2.00 3.11 -2.00 322.11 0.00e+00 9.775784e-03 5.073837e-03 1.314944e-02 -6.000000e+00 2.386653e-02 291.77 -2.00 20.00 -2.00 321.57 0.00e+00 9.006 0.003 302.00 328.00 3 8.7244e-01 3.5475e-02 1.3237e-01 -6.0000e+00 1.0923e+00 1.2643e+00 4.5172e-02 1.3239e-01 -6.0000e+00 1.1958e+00 -1.6009e+00 3.1157e-02 2.9850e-02 -6.0000e+00 7.1494e-01 6.4569e-01 1.4845e-02 2.0338e-02 -6.0000e+00 3.0982e-01 1.3414e-05 -2.5227e-03 4.1457e-04 7.5499e-05 -6.0000e+00 2.0569e-02 1.5380e-02 -1.6688e-04 12 8 8 10 0 0 71.98 21.85 0.78 0.01538 -0.00358 23 4 1 5 0 2248.590 26.00 20.00 21.85 28.56 18.7 1016.50 -23546 900000 9731 900000 57834 40175 900000 900000 28860 -95916 -8222 900000 900000 900000 -42813 900000 -45554 900000 900000 900000 269362 42999 900000 900000 900000 900000 38582 124063 900000 119992 900000 64830 97462 282314 143201 900000 -71299 94939 109455 302642 311104 23552 -34 36909 262941 30185 900000 46499 900000 -5837 51667 202221 900000 61362 66877 35304 49577 128667 9131 900000 53339 3439 170419 15595 65351 44736 30008 41762 9081 1625 -2738 -5648 -8773 -4906 16318 15776 65112 -22679 -28037 -8650 39165 -1119 -13313 -3609 -5286 25189 8948 16395 -2549 -5861 25330 888 -1970 569 541 3605 -2751 6024 144 -8316 13330 -1494 2637 -8999 -1680 -9269 -4697 -8713 -1211 -2172 2815 -3236 1101 2315 1211 -5208 1459 -352 -5310 1670 -3138 2122 4466 6823 -8534 3844 4446 4799 4845 -1388 213 2851 -74 1346 -3865 1122 6847 -3219 415 -1837 -1209 -196 -845 -1348 900000 436 900000 1152 800 900000 900000 575 -6447 -215 900000 900000 900000 -2984 900000 -4083 900000 900000 900000 3688 1392 900000 900000 900000 900000 1105 1699 900000 1643 900000 1953 2402 3865 2157 900000 -8395 2340 2698 4144 4260 1774 -3 2476 3600 2108 900000 2801 900000 -639 3466 3322 900000 4705 5036 3674 4480 5109 1125 900000 4017 461 4900 2413 6621 5451 4150 5260 1716 380 -739 -1624 -2546 -1269 3061 2614 6062 -5155 -7601 -2345 7829 -388 -5797 -1507 -2381 8898 3896 6824 -1284 -2953 8705 365 -806 236 256 1790 -1722 4056 115 -7401 9026 -1052 1585 -5970 -1121 -7107 -3642 -8398 -1207 -2516 3550 -4302 1439 3239 1643 -7259 1924 -499 -7660 2351 -4581 2803 6103 8866 -11365 4843 5382 6052 7085 -2280 386 5473 -156 2980 -9718 2841 16696 -8811 1096 -4746 -2887 -430 -1776 SS 20230209T114418.2Z 8440.489100 248 1 12.85 2 79.21 109.57 68.58 264.58 0.00 1 0.00 1 0 25 2.232e-01 1.608e-02 1.690e-01 4.139e-03 5.239792e-01 2.085637e-03 5.679705e-03 -6.000000e+00 1.241682e-01 225.11 -2.00 3.11 -2.00 320.26 0.00e+00 -3.533137e-03 7.820476e-04 2.126373e-03 -6.000000e+00 5.745963e-03 291.77 -2.00 20.00 -2.00 319.48 0.00e+00 5.141 0.001 302.00 328.00 3 2.0657e+00 6.4976e-03 5.6627e-02 -6.0000e+00 3.0581e-01 -2.4399e-02 8.1306e-03 2.6974e-02 -6.0000e+00 3.3241e-01 -6.1567e-02 7.1105e-03 1.3423e-02 -6.0000e+00 1.9953e-01 3.1290e-02 3.6366e-03 3.7851e-03 -6.0000e+00 8.6312e-02 2.6605e-04 -8.7492e-06 1.1510e-04 5.7669e-05 -6.0000e+00 5.7165e-03 1.3465e-02 -1.4542e-04 12 9 9 12 1 1 99.99 21.86 0.55 0.01346 0.01340 25 17 1 5 0 487.390 26.00 20.00 21.86 29.08 18.7 1019.56 34105 -33215 6759 -77964 -75721 -14511 -19228 167474 -7466 -58181 -74392 -30131 90688 -26313 -24134 10857 -26697 -13065 -3366 34893 -15936 2533 -4062 2620 591 4025 16134 -1851 21406 -22199 14357 11286 -9681 9105 -13813 8470 -16249 -1531 359 7416 13043 -471 7985 3892 3579 2242 7916 4315 -344 -300 -2438 572 -1285 -381 4309 1345 4201 693 -1098 6649 1596 4363 3004 1240 -1237 -1930 -473 -1304 1917 -89 -1775 -1148 -2768 -273 -1932 -1010 622 -3046 -3357 -4008 -1555 -3882 -4118 -3061 -2044 -1663 116 -128 -806 -940 787 1090 2514 3716 5940 4793 5091 4671 3559 2617 1111 857 -37 -1411 -3225 -4237 -2355 -1698 267 -107 463 -483 -495 322 -503 -446 -194 65 -1123 -868 -499 44 778 741 256 942 1701 2422 951 203 -730 -522 -201 -143 -887 -682 233 -65 152 -734 -232 460 1093 151 -335 49 -1290 -1100 -111 -171 676 -81 -1174 -1831 -511 549 -627 -682 254 -1002 -464 -117 873 -688 91 -164 111 28 201 736 -96 829 -1353 690 647 -785 665 -1210 578 -1567 -152 44 1027 1942 -86 1405 726 669 430 1441 824 -71 -64 -590 150 -341 -109 1259 424 1343 231 -362 1983 511 1479 1161 546 -584 -878 -205 -577 896 -49 -1024 -693 -1699 -156 -1132 -525 293 -1462 -1761 -2280 -1003 -2921 -3407 -2650 -1738 -1517 109 -126 -802 -905 692 963 2070 3040 4835 4518 5081 5339 4186 3101 1254 943 -37 -1484 -3778 -5316 -3051 -2328 362 -161 763 -790 -803 529 -779 -655 -286 100 -1870 -1426 -820 71 1269 1169 388 1369 2347 3408 1517 341 -1343 -952 -379 -285 -1806 -1464 508 -144 341 -1598 -476 942 2160 SS 20230209T115838.0Z 8440.499051 257 1 51.65 2 76.02 110.95 71.91 265.73 0.00 1 0.00 1 0 25 4.060e-02 1.670e-02 5.124e-03 5.066e-04 4.127075e-01 2.505953e-04 4.567196e-03 -6.000000e+00 2.258015e-02 225.11 -2.00 3.11 -2.00 318.91 0.00e+00 -1.170074e-03 6.012720e-05 1.222481e-03 -6.000000e+00 1.044955e-03 291.77 -2.00 20.00 -2.00 318.02 0.00e+00 4.046 0.000 302.00 328.00 3 7.3847e-01 6.9761e-04 4.4313e-02 -6.0000e+00 5.5612e-02 -7.7424e-02 8.1307e-04 2.0367e-02 -6.0000e+00 6.0450e-02 1.2650e-02 5.8702e-04 9.6490e-03 -6.0000e+00 3.6286e-02 -2.4299e-03 3.1169e-04 2.6198e-03 -6.0000e+00 1.5695e-02 3.1751e-03 -1.0632e-04 1.3994e-05 2.9817e-05 -6.0000e+00 1.0396e-03 1.3840e-02 -1.5179e-04 12 8 8 10 0 0 89.80 21.86 0.33 0.01384 0.01304 571 90 1 5 0 90.370 26.00 20.00 21.86 29.56 18.7 1023.03 -7968 -12443 -12016 -17961 -18258 -19255 -12229 -8083 -7027 -7007 -9050 -1930 -3606 -774 -3335 -386 -1236 1196 1345 1826 455 1063 2247 3794 1974 3728 2873 2312 1186 710 3078 139 1044 -2072 -3618 -1850 -1516 1233 1051 1643 1352 767 1340 816 1770 696 551 -312 -546 -332 443 429 -135 370 304 536 562 -3 481 1034 1873 2097 1824 1353 -926 -1530 -1221 -803 282 -778 -1084 -1112 -1365 -738 -845 -624 -562 -1160 -1040 -2002 -2411 -2907 -3692 -2733 -1942 -1522 -1114 -1195 -492 -350 336 1810 3456 4960 5530 5383 5405 5097 3953 2703 1931 838 -42 -1213 -3487 -3772 -2866 -1216 318 167 -298 -805 -776 -909 -675 -212 -124 -190 -596 -929 -805 0 779 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