File name: Pandora29s1_Fajardo_20230214_L2Fit_fout2c17d20220426p1-8.txt File generation date: 20260429T103901.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v17d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230214_L1_smca1c17d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0234 305.1644 305.3054 305.4464 305.5874 305.7283 305.8693 306.0102 306.1512 306.2921 306.4330 306.5739 306.7148 306.8557 306.9966 307.1374 307.2783 307.4191 307.5599 307.7007 307.8415 307.9823 308.1231 308.2639 308.4046 308.5454 308.6861 308.8268 308.9676 309.1083 309.2490 309.3896 309.5303 309.6710 309.8116 309.9522 310.0929 310.2335 310.3741 310.5147 310.6552 310.7958 310.9364 311.0769 311.2174 311.3579 311.4985 311.6390 311.7794 311.9199 312.0604 312.2008 312.3413 312.4817 312.6221 312.7625 312.9029 313.0433 313.1837 313.3240 313.4644 313.6047 313.7451 313.8854 314.0257 314.1660 314.3062 314.4465 314.5868 314.7270 314.8673 315.0075 315.1477 315.2879 315.4281 315.5683 315.7084 315.8486 315.9887 316.1288 316.2690 316.4091 316.5492 316.6893 316.8293 316.9694 317.1094 317.2495 317.3895 317.5295 317.6695 317.8095 317.9495 318.0895 318.2294 318.3694 318.5093 318.6492 318.7891 318.9290 319.0689 319.2088 319.3487 319.4885 319.6284 319.7682 319.9080 320.0478 320.1876 320.3274 320.4672 320.6069 320.7467 320.8864 321.0261 321.1659 321.3056 321.4452 321.5849 321.7246 321.8642 322.0039 322.1435 322.2831 322.4228 322.5623 322.7019 322.8415 322.9811 323.1206 323.2602 323.3997 323.5392 323.6787 323.8182 323.9577 324.0971 324.2366 324.3760 324.5155 324.6549 324.7943 324.9337 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230214T114813.7Z 8445.491825 231 1 51.74 2 77.70 108.38 44.43 196.30 0.00 1 0.00 1 0 25 7.337e-02 1.526e-02 1.158e-02 6.947e-04 4.836526e-01 3.482734e-04 5.334952e-03 -6.000000e+00 4.145909e-02 225.21 -2.00 3.11 -2.00 319.51 0.00e+00 -6.548674e-04 1.024571e-04 2.014159e-03 -6.000000e+00 1.916835e-03 291.80 -2.00 20.00 -2.00 318.66 0.00e+00 4.555 0.000 302.00 328.00 3 2.2266e-01 1.0073e-03 5.0849e-02 -6.0000e+00 1.0208e-01 -1.5507e-02 1.2044e-03 2.6182e-02 -6.0000e+00 1.1084e-01 -2.8455e-02 9.5122e-04 1.1284e-02 -6.0000e+00 6.6553e-02 9.7164e-03 5.0182e-04 3.5219e-03 -6.0000e+00 2.8673e-02 2.9527e-03 2.3282e-04 1.9518e-05 3.6737e-05 -6.0000e+00 1.9688e-03 9.8169e-03 0.0000e+00 12 8 8 10 0 0 92.32 21.85 0.41 0.00982 0.01157 436 69 1 5 0 118.640 26.00 20.00 21.85 28.71 18.8 1018.45 -29848 -22158 -28606 -27829 -31664 -27315 -22397 -17414 -18561 -22387 -16082 -11656 -6377 -1729 -10267 3128 -4719 2946 -1861 1662 659 -1611 2134 692 3849 3114 465 2373 1004 -7 1896 687 286 -1774 -2371 -278 -148 538 1425 1589 1844 1237 1035 1513 2414 1512 1076 436 468 468 1734 834 320 465 547 938 434 239 700 1924 1982 1989 1803 347 -1728 -1334 -502 101 862 -1198 -1547 -1337 -1548 -704 -846 -499 -18 -751 -336 -1688 -2097 -2621 -3735 -2452 -1741 -1439 -1330 -1341 -902 -719 330 1340 3328 4980 4992 4809 4899 4505 2650 1594 1355 1350 1939 572 -2642 -3134 -2667 -1569 -267 -105 -727 -1250 -1017 -933 -245 517 551 309 -347 -1278 -1099 -153 545 231 564 238 1922 2916 1043 -247 -572 -367 101 113 -590 -859 -210 -84 -504 -655 -205 613 1650 -475 -380 -562 -532 -571 -455 -384 -327 -406 -560 -391 -291 -179 -57 -446 139 -251 157 -112 102 42 -106 141 51 299 260 41 197 80 -1 173 73 35 -237 -306 -34 -20 85 250 336 441 319 280 417 663 424 305 126 138 144 573 283 118 186 232 412 199 110 314 838 885 965 905 196 -1037 -765 -274 55 506 -767 -1105 -1003 -1165 -503 -560 -319 -10 -433 -209 -1146 -1654 -2197 -3459 -2225 -1682 -1488 -1452 -1425 -958 -783 331 1232 3013 4432 4546 4706 5169 5410 3325 2017 1617 1552 2056 625 -3231 -3861 -3429 -2116 -382 -156 -1137 -2053 -1648 -1440 -369 771 823 460 -555 -2071 -1791 -241 870 357 830 356 2712 4176 1596 -402 -965 -650 185 208 -1172 -1730 -432 -175 -1021 -1340 -396 1172 3038 SS 20230214T115337.3Z 8445.495571 234 1 51.63 2 76.48 108.90 44.81 197.93 0.00 1 0.00 1 0 25 4.179e-02 1.553e-02 6.959e-03 5.660e-04 4.434454e-01 2.823225e-04 4.943088e-03 -6.000000e+00 2.361307e-02 225.21 -2.00 3.11 -2.00 319.16 0.00e+00 -4.986295e-04 7.383850e-05 1.749240e-03 -6.000000e+00 1.091795e-03 291.80 -2.00 20.00 -2.00 318.28 0.00e+00 4.174 0.000 302.00 328.00 3 2.3887e-01 7.9678e-04 4.6467e-02 -6.0000e+00 5.8141e-02 -2.4679e-02 9.3696e-04 2.3531e-02 -6.0000e+00 6.3132e-02 -1.2218e-02 6.9579e-04 1.0319e-02 -6.0000e+00 3.7907e-02 2.4875e-03 3.6856e-04 3.1272e-03 -6.0000e+00 1.6329e-02 4.3456e-03 1.7134e-04 1.5961e-05 3.3076e-05 -6.0000e+00 1.1215e-03 1.0613e-02 0.0000e+00 12 8 8 10 0 0 99.69 21.86 0.40 0.01061 0.01190 563 89 1 5 0 91.680 26.00 20.00 21.86 29.31 18.8 1023.30 -16631 -13105 -9134 -15050 -13436 -18241 -17431 -7498 -11024 -8987 -10873 -3630 -3120 839 -6017 444 -2069 2555 1477 1857 1446 901 2557 1789 2367 3084 1139 1443 406 1243 3224 685 933 -1523 -2691 -207 -764 961 990 970 1171 453 709 748 1717 560 436 25 -147 319 1162 556 321 208 510 799 217 -49 455 1473 2166 1815 1639 543 -1675 -1394 -652 52 945 -945 -1447 -1438 -1466 -936 -824 -474 -28 -299 227 -1497 -1860 -2457 -3523 -2352 -1783 -1373 -1330 -1455 -750 -586 250 1355 3589 5218 5307 4894 5105 4581 2731 1588 1412 1374 1871 771 -2551 -3176 -2594 -1536 -285 -193 -769 -1272 -1072 -1017 -373 440 595 254 -387 -1251 -1136 -156 481 242 617 183 1906 2919 1056 -126 -636 -340 48 71 -596 -889 -241 -73 -420 -581 -209 583 1661 -360 -316 -226 -386 -307 -421 -429 -192 -335 -293 -372 -123 -123 39 -357 29 -150 190 119 157 127 80 231 178 254 349 135 163 44 135 382 95 146 -238 -408 -33 -121 176 222 262 356 136 222 239 546 182 143 8 -49 110 431 229 143 92 239 387 109 -25 224 709 1063 969 976 334 -1092 -865 -383 30 589 -689 -1099 -1149 -1174 -715 -625 -322 -17 -181 146 -1137 -1524 -2142 -3381 -2220 -1794 -1477 -1428 -1617 -832 -627 262 1294 3335 4737 4916 4874 5470 5296 3472 2034 1705 1597 2013 855 -3171 -3994 -3397 -2106 -413 -291 -1212 -2094 -1735 -1563 -556 646 873 373 -610 -2008 -1842 -246 765 372 901 272 2658 4113 1584 -201 -1048 -585 85 128 -1145 -1736 -479 -148 -827 -1155 -394 1088 2987 SS 20230214T115927.8Z 8445.499628 237 1 51.68 2 75.17 109.47 45.25 199.65 0.00 1 0.00 1 0 25 2.859e-02 1.593e-02 3.962e-03 4.837e-04 4.060023e-01 2.408513e-04 4.549437e-03 -6.000000e+00 1.615307e-02 225.21 -2.00 3.11 -2.00 318.62 0.00e+00 -2.937065e-04 5.325596e-05 1.349494e-03 -6.000000e+00 7.468772e-04 291.80 -2.00 20.00 -2.00 317.72 0.00e+00 3.829 0.000 302.00 328.00 3 3.5503e-01 6.6209e-04 4.2400e-02 -6.0000e+00 3.9773e-02 -3.1701e-02 7.6383e-04 2.0676e-02 -6.0000e+00 4.3188e-02 -1.0767e-03 5.2460e-04 9.2901e-03 -6.0000e+00 2.5931e-02 -2.6247e-03 2.7801e-04 2.8443e-03 -6.0000e+00 1.1170e-02 5.6024e-03 2.3418e-04 1.3603e-05 2.9981e-05 -6.0000e+00 7.6718e-04 1.0791e-02 0.0000e+00 12 8 8 10 0 0 99.67 21.86 0.37 0.01079 0.01255 493 78 1 5 0 104.810 26.00 20.00 21.86 30.07 18.7 1027.17 -9087 -8370 -5680 -11743 -8653 -12593 -6006 -5228 -7506 -5788 -6429 -633 113 657 -2048 493 -180 1437 1143 2056 851 1304 2720 2725 2555 2403 843 1157 712 1353 3529 841 343 -2070 -2887 -532 -253 715 180 300 103 -99 173 167 1302 205 401 167 -235 479 1115 508 514 288 297 808 261 -175 490 1366 2115 1946 1505 626 -1726 -1250 -576 41 1080 -1256 -1401 -1498 -1502 -770 -956 -398 86 -70 394 -1440 -1937 -2618 -3574 -2285 -1737 -1434 -1393 -1457 -859 -720 222 1426 3486 5325 5298 4888 5057 4562 2731 1669 1380 1392 1824 741 -2521 -3155 -2558 -1630 -268 -139 -753 -1346 -1121 -1127 -415 436 423 190 -401 -1174 -1157 -220 405 244 648 279 1925 2852 1053 -160 -676 -388 29 66 -592 -881 -288 -151 -404 -584 -134 638 1680 -300 -314 -221 -471 -304 -441 -211 -208 -349 -289 -330 -32 7 46 -176 48 -19 160 136 255 100 168 358 353 359 359 130 171 100 189 532 147 68 -446 -599 -105 -54 179 51 101 39 -37 67 66 512 82 161 67 -95 198 495 249 253 152 165 463 155 -104 285 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