File name: Pandora29s1_Fajardo_20230222_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240213T052900.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230222_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230222T111408.6Z 8453.468155 45 1 51.95 2 84.32 102.74 109.65 84.75 0.00 1 0.00 1 0 33 7.682e-01 4.538e-02 3.290e-01 1.539e-02 8.201686e-01 8.619736e-03 8.800133e-03 -6.000000e+00 4.408291e-01 225.82 -2.00 3.11 -2.00 321.93 0.00e+00 -2.386914e-04 4.362075e-03 1.171781e-02 -6.000000e+00 2.162645e-02 291.98 -2.00 20.00 -2.00 321.32 0.00e+00 8.905 0.003 302.00 328.00 3 9.1686e-01 3.3168e-02 1.1979e-01 -6.0000e+00 1.0840e+00 1.4700e+00 4.0878e-02 1.0473e-01 -6.0000e+00 1.1784e+00 -1.6998e+00 2.5697e-02 2.9158e-02 -6.0000e+00 7.0999e-01 6.4171e-01 1.2920e-02 1.1553e-02 -6.0000e+00 3.0882e-01 1.3007e-05 -2.4524e-03 4.3059e-04 1.1047e-04 -6.0000e+00 2.0397e-02 1.6817e-02 -1.7410e-04 12 8 8 10 0 0 73.97 21.88 0.77 0.01682 -0.00161 23 4 1 5 0 2258.210 26.00 20.00 21.88 28.26 19.0 1014.16 22905 118377 23868 97105 120175 -229 -15057 900000 -58596 -46811 -14970 85546 900000 900000 -48049 900000 -27568 416469 255558 900000 135937 -22299 900000 138943 149270 900000 -4780 92288 900000 25865 900000 75807 -5441 252681 23274 137142 -46083 97726 228451 189916 900000 20082 15138 54993 223709 15750 900000 80394 900000 -47563 49321 126683 221797 8547 117349 28642 65052 -8009 30783 900000 12606 25518 74946 9315 37454 41660 15734 12903 373 -2872 13783 10555 5011 -24127 26172 44012 44063 -22576 -13350 20627 47270 -10402 -16228 -5461 -6742 22534 7729 25602 4038 1022 32064 -5361 -7071 -16278 -2592 -4238 3742 9095 -4394 -150 7260 -2876 6002 -11445 -2669 -7278 -2720 -9855 1747 -1545 3343 -3799 1729 951 640 -1355 -2813 -2537 -4655 -1169 -3457 941 3492 6536 6102 2003 359 2946 1431 85 944 1685 -283 1743 -1843 1504 2500 -280 1084 -2236 -1319 -1779 -1146 1371 2900 1462 2511 1963 -11 -779 900000 -4944 -3504 -774 1630 900000 900000 -5623 900000 -3114 6234 3826 900000 2775 -2003 900000 2458 2438 900000 -345 2487 900000 1200 900000 2837 -513 3783 1568 2669 -5726 3218 3420 3412 900000 2225 1768 4198 3349 1650 900000 4332 900000 -9826 4208 5499 3984 1382 6675 4030 6427 -1595 3871 900000 1736 3285 6619 1799 5831 6049 2897 2511 89 -817 3652 2986 1463 -8704 5093 6259 5738 -5779 -3497 4632 9623 -4360 -8016 -2559 -3391 8973 3726 10578 2061 517 11040 -2512 -3271 -8602 -1362 -2434 2332 6275 -3875 -129 5454 -2141 3635 -8115 -1874 -5685 -2358 -9928 1744 -1834 4324 -5761 2549 1393 903 -1876 -3988 -3771 -6835 -1729 -5155 1406 4893 8649 7847 2612 460 3854 2209 140 1737 3345 -610 3944 -4671 3904 6554 -766 2926 -5955 -3233 -4062 -2478 SS 20230222T112646.1Z 8453.476922 48 1 51.78 2 81.41 103.82 106.76 85.73 0.00 1 0.00 1 0 25 3.377e-01 1.518e-02 1.251e-01 2.230e-03 6.410275e-01 1.159870e-03 6.891553e-03 -6.000000e+00 1.887890e-01 225.82 -2.00 3.11 -2.00 321.02 0.00e+00 -5.390489e-03 5.616533e-04 3.374583e-03 -6.000000e+00 8.727184e-03 291.98 -2.00 20.00 -2.00 320.33 0.00e+00 6.305 0.001 302.00 328.00 3 1.0151e+00 4.0670e-03 7.0263e-02 -6.0000e+00 4.6581e-01 3.8485e-02 5.5170e-03 3.5922e-02 -6.0000e+00 5.0648e-01 -1.8383e-01 5.3320e-03 1.8165e-02 -6.0000e+00 3.0407e-01 8.5103e-02 2.5820e-03 5.1136e-03 -6.0000e+00 1.3103e-01 2.3102e-04 -4.9047e-04 6.1075e-05 8.8993e-05 -6.0000e+00 8.6739e-03 1.6226e-02 -1.4824e-04 12 9 8 11 8 0 47.95 21.88 0.45 0.01623 0.01254 137 22 1 5 0 377.910 26.00 20.00 21.88 28.89 18.9 1018.13 -190119 -17681 -143528 -5296 -61056 -97330 -72287 -101406 -105335 -129306 -95303 -11578 -23251 900000 -108062 900000 -56402 49411 55 8565 7901 -41422 35672 -17606 27736 34871 -21090 44807 -9286 33905 27622 -6374 4173 2909 7523 -2657 -12164 -7275 3921 14165 14481 7845 6410 10314 11081 5831 16161 -1670 15099 -6767 8916 5464 1470 1652 2616 5721 4486 3245 4190 7756 5031 450 5126 154 -3 -1310 -2527 -512 -479 -132 -2104 -1336 -515 -917 1166 -990 704 -3683 -3000 -3206 -2892 -3695 -5468 -3663 -2659 -1807 -591 -841 -437 -850 1246 942 2259 4302 4626 4914 4371 4573 3231 1706 1832 -226 495 -1996 -3734 -4478 -3095 -1110 482 200 12 -623 -147 -282 288 20 258 -353 -798 -867 -840 571 889 728 951 486 1525 1941 1029 -235 -347 -134 -143 2 -876 -557 534 84 -81 -665 -476 90 1030 -2976 -58 -1779 -16 -292 -656 -424 -948 -1214 -2137 -1181 -68 -187 900000 -3101 900000 -1288 430 1 129 124 -1063 450 -433 488 622 -679 711 -238 582 589 -226 155 120 285 -109 -606 -414 251 1013 1187 742 645 1014 1077 605 1529 -194 1546 -920 1159 833 257 318 538 1205 1005 741 918 1590 1076 110 1359 49 -1 -434 -833 -171 -161 -52 -939 -624 -238 -405 463 -359 256 -1273 -1145 -1461 -1544 -2293 -3825 -2452 -1896 -1374 -469 -692 -359 -679 909 646 1600 2808 3375 4148 3961 4763 3481 1873 2034 -231 458 -1914 -3976 -5097 -3665 -1382 646 281 18 -1048 -247 -460 440 29 380 -550 -1331 -1416 -1366 944 1420 1129 1416 703 2102 2766 1681 -411 -668 -257 -288 4 -1916 -1284 1246 201 -196 -1541 -1037 194 2137 SS 20230222T113857.2Z 8453.485384 53 1 51.75 2 78.61 104.90 103.96 86.65 0.00 1 0.00 1 0 25 1.223e-01 1.598e-02 1.790e-02 8.712e-04 5.034133e-01 4.373970e-04 5.514667e-03 -6.000000e+00 6.819872e-02 225.82 -2.00 3.11 -2.00 319.87 0.00e+00 -2.964427e-03 1.455838e-04 2.002407e-03 -6.000000e+00 3.151158e-03 291.98 -2.00 20.00 -2.00 319.05 0.00e+00 4.889 0.000 302.00 328.00 3 8.4751e-01 1.3087e-03 5.3982e-02 -6.0000e+00 1.6822e-01 -6.6955e-02 1.5977e-03 2.5861e-02 -6.0000e+00 1.8278e-01 -3.1087e-02 1.3332e-03 1.2556e-02 -6.0000e+00 1.0967e-01 1.9595e-02 6.9341e-04 3.3961e-03 -6.0000e+00 4.7357e-02 1.1797e-03 -1.9583e-04 2.3948e-05 4.9655e-05 -6.0000e+00 3.1332e-03 1.5703e-02 -1.4910e-04 12 8 8 10 0 0 74.03 21.88 0.38 0.01570 0.01423 339 53 1 5 0 152.620 26.00 20.00 21.88 29.51 19.0 1022.54 -55032 -41470 -39497 -46790 -40604 -59038 -33468 -29920 -34253 -24480 -34971 -13825 -19113 3309 -21455 -779 -7176 11 -1279 -180 -2419 -5713 -1582 705 2951 7860 -253 4826 -890 -1346 3822 -1926 2193 -2310 -2505 -1827 -2241 1147 1553 4153 5039 3578 3399 3017 4207 1538 2887 394 1208 -455 858 1162 -51 512 668 1385 1591 881 1626 1674 2565 1660 2068 1150 -1255 -1325 -1432 -1058 -20 -966 -1043 -1202 -1269 -1043 -747 -685 -407 -1762 -1715 -2527 -2586 -3102 -3933 -2946 -2199 -1695 -992 -1167 -569 -281 427 1521 3232 4928 5386 4995 5277 4901 3708 2515 1903 617 -13 -1280 -3706 -4002 -2883 -1194 343 213 -130 -637 -560 -677 -393 36 11 -136 -608 -862 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