File name: Pandora29s1_Fajardo_20230426_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240213T063908.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230426_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230426 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230426T102626.6Z 8516.435030 43 1 50.81 2 84.37 77.62 133.62 15.52 0.00 1 0.00 1 0 25 5.918e-01 5.409e-02 2.373e-01 1.531e-02 8.595848e-01 9.536863e-03 8.973038e-03 -6.000000e+00 3.697781e-01 229.86 -2.00 3.11 -2.00 322.19 0.00e+00 3.138991e-02 5.224621e-03 1.765829e-02 -6.000000e+00 2.289201e-02 293.60 -2.00 20.00 -2.00 321.66 0.00e+00 8.959 0.003 302.00 328.00 3 7.0288e-01 3.9111e-02 1.7324e-01 -6.0000e+00 9.3012e-01 1.7707e+00 4.7343e-02 2.1036e-01 -6.0000e+00 1.0265e+00 -1.9601e+00 2.8273e-02 2.6773e-02 -6.0000e+00 5.9861e-01 7.1887e-01 1.4836e-02 4.9441e-02 -6.0000e+00 2.5279e-01 1.2065e-05 -2.0933e-03 4.4964e-04 3.1788e-04 -6.0000e+00 1.6942e-02 1.1357e-02 -9.2195e-05 12 8 8 10 0 0 10.80 22.10 1.19 0.01136 -0.00437 24 4 1 5 0 2116.750 26.11 20.00 22.10 29.58 20.2 1018.68 108878 900000 43136 900000 -25283 -18946 900000 900000 900000 -85765 -78108 900000 900000 900000 -3054 900000 -12920 900000 900000 900000 900000 75314 900000 900000 900000 900000 900000 900000 900000 273478 900000 900000 900000 900000 120098 900000 -51352 77665 256860 900000 900000 11881 -11217 37741 900000 66302 900000 91395 900000 -34854 44820 900000 900000 45731 900000 49957 203861 14903 26986 -11714 198615 87137 900000 71108 116635 90749 26362 22731 23269 14896 17673 9506 -3410 -7674 46341 65132 55214 -9065 -11944 -10231 44832 -20055 -16963 -2155 -4952 29437 13955 37590 -10735 8553 40277 -6682 4534 -8966 8436 1478 6348 9220 -3109 -721 12827 110 3014 -7277 -1394 -7951 -7447 -7007 -1761 -5051 5188 -5788 -1975 -2891 1470 -5260 735 -358 -7608 -1091 -3209 1823 3010 8386 9479 3762 691 2174 1541 1172 1352 2947 1056 456 -3678 595 11417 -2592 189 -2647 -1579 -302 -3167 3225 900000 2846 900000 -2349 -1301 900000 900000 900000 -6120 -4522 900000 900000 900000 -201 900000 -1270 900000 900000 900000 900000 2535 900000 900000 900000 900000 900000 900000 900000 4050 900000 900000 900000 900000 2846 900000 -5780 2531 3804 900000 900000 950 -1163 2459 900000 3339 900000 3790 900000 -5523 3452 900000 900000 4199 900000 4291 3623 1655 2478 -1527 3236 4775 900000 6108 6910 6855 3709 3367 3653 2890 3638 2168 -854 -1830 5697 5788 4988 -1598 -2494 -2591 7835 -7752 -7034 -808 -2002 8894 5126 11190 -5183 3293 10499 -2593 1518 -3572 3249 669 3282 5499 -2374 -550 8065 70 1631 -4223 -818 -5299 -5758 -5884 -1575 -5416 5786 -7904 -2674 -3901 1827 -6762 905 -472 -10469 -1469 -4777 2446 3825 9811 10599 4334 795 2589 2164 1763 2296 5388 2101 978 -8879 1456 25594 -6789 482 -6657 -3648 -637 -6529 SS 20230426T103847.6Z 8516.443607 46 1 51.86 2 81.50 78.51 132.80 18.95 0.00 1 0.00 1 0 25 4.492e-01 1.600e-02 1.298e-01 2.418e-03 6.860041e-01 1.282681e-03 7.268264e-03 -6.000000e+00 2.544175e-01 229.86 -2.00 3.11 -2.00 321.18 0.00e+00 -5.223445e-03 6.431772e-04 3.309773e-03 -6.000000e+00 1.165695e-02 293.60 -2.00 20.00 -2.00 320.49 0.00e+00 6.366 0.001 302.00 328.00 3 9.8313e-01 4.6021e-03 7.1927e-02 -6.0000e+00 6.3324e-01 1.0109e-01 6.3412e-03 3.8083e-02 -6.0000e+00 6.8557e-01 -2.8076e-01 6.0331e-03 1.8805e-02 -6.0000e+00 4.1043e-01 1.2742e-01 2.8807e-03 5.0829e-03 -6.0000e+00 1.7617e-01 2.1171e-04 -6.0728e-04 6.4966e-05 8.6008e-05 -6.0000e+00 1.1514e-02 1.1511e-02 -9.5678e-05 12 8 8 10 0 0 -6.04 22.10 0.41 0.01151 0.00695 132 21 1 5 0 392.860 26.11 20.00 22.10 30.56 20.0 1024.78 -138785 -107227 -137610 -152169 -199494 -177463 -73751 -123980 -92353 -152288 -142863 -14230 -28532 -29360 -132338 136645 -65230 26136 44591 -6211 -17035 -48980 -2167 -28646 -9446 24081 -20763 7461 11128 -23518 59751 -10274 -4341 15389 -3255 10657 -22376 2170 -919 10538 16500 928 3122 7052 15680 7174 18603 854 16872 -5119 4704 11240 3960 3903 5326 8692 10776 4499 6167 10072 5709 3455 7174 2746 1682 818 -1271 -385 246 -595 -3 -275 -1351 -729 470 1557 -262 -3144 -3836 -4683 -2906 -5014 -4712 -3080 -2478 -1052 -313 -861 -1762 -854 1135 435 2409 3407 4633 4672 4744 4221 2654 1466 1455 -418 -475 -2418 -4271 -4492 -3543 -1969 104 -476 146 -755 -110 -278 408 -8 232 251 -795 -1066 -625 353 1370 1087 1334 787 1841 2126 1067 247 -276 65 -157 -57 -871 -476 571 -1 -69 -714 -690 149 697 -1145 -759 -1428 -1794 -3387 -2343 -383 -1257 -806 -2729 -2459 -74 -209 -270 -4213 354 -1431 253 389 -95 -301 -1190 -35 -682 -209 415 -578 150 202 -621 803 -332 -155 497 -122 337 -1082 98 -54 683 1163 83 286 630 1279 645 1509 85 1500 -606 566 1439 603 656 955 1595 2035 914 1191 1807 1081 728 1656 756 502 241 -377 -117 82 -213 -1 -116 -579 -295 172 555 -88 -1089 -1352 -1991 -1433 -2923 -3051 -2089 -1795 -809 -232 -663 -1375 -640 849 307 1604 2306 3190 3749 4417 4218 2981 1683 1575 -417 -429 -2230 -4373 -4898 -4035 -2371 135 -699 222 -1243 -182 -448 620 -11 339 385 -1313 -1853 -1075 578 2146 1657 1953 1208 2689 3209 1721 457 -530 132 -318 -122 -2041 -1108 1346 -3 -166 -1673 -1612 325 1452 SS 20230426T105116.7Z 8516.452276 51 1 51.57 2 78.59 79.39 131.82 22.28 0.00 1 0.00 1 0 25 1.547e-01 1.593e-02 2.244e-02 9.087e-04 5.368558e-01 4.643498e-04 5.830929e-03 -6.000000e+00 8.762304e-02 229.86 -2.00 3.11 -2.00 320.08 0.00e+00 -2.983652e-03 1.621618e-04 2.243790e-03 -6.000000e+00 4.014690e-03 293.60 -2.00 20.00 -2.00 319.24 0.00e+00 4.884 0.000 302.00 328.00 3 8.3666e-01 1.4209e-03 5.5088e-02 -6.0000e+00 2.1809e-01 -6.1398e-02 1.7621e-03 2.8491e-02 -6.0000e+00 2.3612e-01 -4.5742e-02 1.5067e-03 1.3496e-02 -6.0000e+00 1.4135e-01 2.7022e-02 7.7470e-04 3.4847e-03 -6.0000e+00 6.0676e-02 1.1441e-03 -2.3444e-04 2.5012e-05 5.0020e-05 -6.0000e+00 3.9655e-03 1.1110e-02 -1.1142e-04 12 8 8 10 0 0 -2.69 22.10 0.40 0.01111 0.00935 339 53 1 5 0 152.110 26.11 20.00 22.10 31.76 20.2 1033.03 -64292 -47751 -61345 -43566 -74989 -62005 -40918 -30270 -30941 -46662 -44994 -27389 -15908 -8813 -33623 2965 -16755 -900 -30 -2767 -2184 -6847 3215 -3340 4267 7535 -674 4407 -2896 -3593 4220 -253 2420 -2234 -5564 -2544 -2700 -1489 2938 4919 4464 4317 3498 3447 4212 2181 2251 -183 2074 -592 1564 1774 694 1006 1500 2316 1772 1465 1055 2510 2184 1568 2286 918 -720 -1883 -1534 -815 -113 -655 -1134 -895 -1362 -1032 -816 -855 -531 -1951 -1686 -2732 -3003 -3362 -4193 -2997 -2253 -1488 -1147 -1322 -673 -562 606 1523 3226 4833 5376 5236 5174 5069 3626 2388 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