File name: Pandora29s1_Fajardo_20230507_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240213T074836.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230507_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230507 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230507T103032.4Z 8527.437875 223 1 51.66 2 82.15 74.83 82.35 240.32 0.00 1 0.00 1 0 25 5.188e-01 2.231e-02 2.675e-01 4.944e-03 7.040614e-01 2.670786e-03 7.282512e-03 -6.000000e+00 2.946580e-01 229.97 -2.00 3.11 -2.00 321.53 0.00e+00 1.444066e-03 1.468429e-03 4.001616e-03 -6.000000e+00 1.354187e-02 293.92 -2.00 20.00 -2.00 320.88 0.00e+00 6.821 0.001 302.00 328.00 3 1.6580e+00 1.0372e-02 7.8956e-02 -6.0000e+00 7.3354e-01 3.3828e-01 1.4082e-02 4.8365e-02 -6.0000e+00 7.9464e-01 -5.5343e-01 1.2639e-02 1.7271e-02 -6.0000e+00 4.7613e-01 2.3873e-01 5.9702e-03 8.2150e-03 -6.0000e+00 2.0447e-01 6.4589e-05 -1.1720e-03 1.3649e-04 6.2912e-05 -6.0000e+00 1.3335e-02 1.3136e-02 -1.4950e-04 12 8 8 10 0 0 5.01 22.36 0.50 0.01314 0.00433 48 8 1 5 0 1076.110 25.90 20.00 22.36 30.03 20.5 1019.79 -124384 81909 -81914 -47071 -212851 -159935 29609 219638 -109220 -135333 -123256 -95342 74667 900000 -130108 900000 -133913 49137 -3149 21139 146273 -55675 76175 37023 92149 155866 -9454 33235 100510 45326 900000 24128 9136 60901 -7770 46649 -34326 10825 46476 26468 55126 4746 -7036 7005 47722 5419 46280 21164 75274 -13350 13732 33780 21990 2690 28851 9283 22769 5023 6481 34561 16826 14172 26158 5021 12325 2807 -1782 3030 4719 674 -1878 575 -3406 -115 2433 6985 10118 -6036 -4879 -5827 3641 -6847 -7109 -2981 -2314 -348 -1142 1630 -3622 -1507 2849 -917 1708 180 3204 4779 3792 3279 1752 1061 2211 398 -441 -5456 -4774 -5230 -3219 -3040 167 -1056 126 -1650 -968 -175 322 -93 190 -628 -702 -453 -554 1038 1661 1575 2819 532 2175 3292 1642 175 134 728 551 346 -1648 -559 1971 -463 -187 -639 -904 -429 -323 -1471 395 -789 -309 -6434 -2662 143 1058 -1579 -2739 -2257 -1424 360 900000 -5392 900000 -7743 497 -58 316 705 -1771 661 517 799 751 -241 528 775 633 900000 593 304 1321 -318 1056 -1886 443 1635 1377 2444 373 -651 574 2598 457 2631 1591 3446 -1576 1376 3125 2511 407 3587 1463 3248 854 1046 4080 2408 2274 4248 1152 2821 691 -452 755 1269 220 -703 221 -1354 -42 787 1922 2496 -1763 -1575 -2283 1535 -3371 -3902 -1668 -1378 -218 -761 1093 -2574 -1016 1716 -537 938 103 2010 3458 2966 2994 1803 1112 2161 358 -360 -4675 -4421 -5173 -3295 -3344 196 -1421 188 -2704 -1597 -279 486 -134 276 -969 -1157 -780 -949 1681 2582 2378 4046 757 2930 4554 2640 302 255 1481 1184 792 -3858 -1371 4813 -1181 -477 -1569 -2085 -993 -718 SS 20230507T104558.5Z 8527.448594 228 1 51.86 2 78.61 75.88 85.45 241.67 0.00 1 0.00 1 0 25 1.647e-01 1.570e-02 2.735e-02 1.199e-03 5.301609e-01 6.145369e-04 5.757077e-03 -6.000000e+00 9.328069e-02 229.97 -2.00 3.11 -2.00 320.11 0.00e+00 -2.640041e-03 2.143670e-04 2.198303e-03 -6.000000e+00 4.278369e-03 293.92 -2.00 20.00 -2.00 319.25 0.00e+00 4.890 0.000 302.00 328.00 3 1.3617e+00 1.8920e-03 5.5013e-02 -6.0000e+00 2.3221e-01 -3.9459e-02 2.3420e-03 2.8328e-02 -6.0000e+00 2.5138e-01 -5.9630e-02 1.9714e-03 1.3219e-02 -6.0000e+00 1.5051e-01 3.1144e-02 1.0108e-03 3.3733e-03 -6.0000e+00 6.4596e-02 6.7379e-04 -3.2368e-04 3.3204e-05 4.9801e-05 -6.0000e+00 4.2208e-03 1.2398e-02 -1.2016e-04 12 8 8 10 0 0 0.09 22.36 0.38 0.01240 0.00997 196 31 1 5 0 264.560 25.90 20.00 22.36 31.15 20.6 1028.02 -48036 -55715 -43606 -62659 -87965 -80772 -39188 -33844 -43390 -51555 -37458 -16960 -15755 3503 -29091 8091 -18426 2098 -1698 1049 959 -10361 402 2557 2723 10624 -2309 4301 518 -6216 11735 -1478 3039 39 -3344 -646 -4424 404 1315 3851 5362 2638 3013 3489 4533 1783 2363 733 2014 -687 991 2152 248 641 826 1824 2307 772 1828 2839 2389 2396 2686 956 -830 -1132 -1809 -1342 438 -1158 -1128 -1359 -1623 -936 -509 -430 -468 -2189 -1715 -2661 -2626 -3339 -3974 -2984 -2079 -1550 -1275 -1347 -710 -566 418 1390 3141 4754 5232 5180 5093 4772 3602 2412 1871 576 -65 -1414 -3680 -3941 -2977 -1329 326 259 -283 -811 -467 -655 -186 54 117 -187 -624 -983 -746 71 921 563 797 475 1746 2327 987 -138 -505 -254 -141 -269 -580 -706 -78 22 -175 -646 -106 465 1173 -517 -755 -566 -967 -1573 -1303 -458 -439 -725 -1043 -683 -270 -296 67 -935 212 -696 70 -64 41 39 -469 17 119 140 544 -139 232 27 -357 641 -107 242 4 -296 -54 -423 44 176 615 961 475 567 667 858 352 467 149 416 -152 238 572 74 206 283 648 851 292 665 1001 864 942 1184 440 -409 -536 -831 -621 217 -678 -682 -869 -1043 -572 -310 -234 -234 -1095 -928 -1708 -1809 -2643 -3231 -2541 -1886 -1507 -1221 -1338 -705 -544 396 1214 2543 3796 4572 4840 5452 5485 4311 2925 2146 646 -67 -1504 -4376 -4693 -3692 -1726 450 397 -452 -1368 -781 -1048 -277 80 175 -278 -996 -1666 -1269 116 1451 861 1233 710 2465 3341 1513 -239 -903 -479 -263 -529 -1168 -1505 -170 46 -373 -1401 -217 942 2285 SS 20230507T105152.9Z 8527.452696 231 1 51.84 2 77.25 76.28 86.65 242.16 0.00 1 0.00 1 0 25 8.763e-02 1.624e-02 1.431e-02 8.587e-04 4.772257e-01 4.340807e-04 5.172310e-03 -6.000000e+00 4.964935e-02 229.97 -2.00 3.11 -2.00 319.58 0.00e+00 -1.530916e-03 1.283819e-04 1.608068e-03 -6.000000e+00 2.277112e-03 293.92 -2.00 20.00 -2.00 318.69 0.00e+00 4.406 0.000 302.00 328.00 3 1.2685e+00 1.2731e-03 4.9273e-02 -6.0000e+00 1.2360e-01 -6.2889e-02 1.5208e-03 2.4520e-02 -6.0000e+00 1.3380e-01 -2.2040e-02 1.1924e-03 1.1304e-02 -6.0000e+00 8.0107e-02 1.3809e-02 6.2734e-04 2.9992e-03 -6.0000e+00 3.4384e-02 1.2311e-03 -1.0626e-04 2.3664e-05 3.5516e-05 -6.0000e+00 2.2464e-03 1.2057e-02 -1.1129e-04 12 8 8 10 0 0 -0.33 22.36 0.37 0.01206 0.01126 278 44 1 5 0 186.390 25.90 20.00 22.36 31.65 20.4 1030.39 -29692 -25028 -20616 -34304 -47192 -38894 -26019 -20361 -20116 -24592 -24662 -11161 -6030 -575 -14453 513 -5292 2111 587 1577 842 -77 818 1555 4160 4096 1972 3026 380 -1847 4174 -152 1951 -971 -3414 -2205 -2292 1263 1846 2614 4190 1583 2090 1840 3346 1423 1340 -55 447 -554 895 850 -35 55 636 979 1314 123 772 2022 2165 1754 2150 1367 -802 -1723 -1332 -1016 77 -1052 -1421 -1170 -1410 -785 -611 -712 -502 -1699 -1165 -2390 -2476 -3072 -3986 -2777 -2058 -1325 -1121 -1249 -600 -550 529 1655 3353 4557 5501 5327 5097 5178 3712 2504 1906 775 -119 -1357 -3628 -3915 -2844 -1211 331 141 -258 -722 -644 -809 -365 -120 34 -163 -531 -978 -707 69 795 563 709 539 1624 2303 990 -152 -526 -460 -195 -305 -703 -713 -198 -58 -163 -465 -157 614 1329 -458 -428 -363 -678 -952 -697 -447 -384 -440 -622 -642 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