File name: Pandora29s1_Fajardo_20230507_L2Fit_fout2c17d20220426p1-8.txt File generation date: 20260429T105445.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v17d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230507_L1_smca1c17d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230507 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0234 305.1644 305.3054 305.4464 305.5874 305.7283 305.8693 306.0102 306.1512 306.2921 306.4330 306.5739 306.7148 306.8557 306.9966 307.1374 307.2783 307.4191 307.5599 307.7007 307.8415 307.9823 308.1231 308.2639 308.4046 308.5454 308.6861 308.8268 308.9676 309.1083 309.2490 309.3896 309.5303 309.6710 309.8116 309.9522 310.0929 310.2335 310.3741 310.5147 310.6552 310.7958 310.9364 311.0769 311.2174 311.3579 311.4985 311.6390 311.7794 311.9199 312.0604 312.2008 312.3413 312.4817 312.6221 312.7625 312.9029 313.0433 313.1837 313.3240 313.4644 313.6047 313.7451 313.8854 314.0257 314.1660 314.3062 314.4465 314.5868 314.7270 314.8673 315.0075 315.1477 315.2879 315.4281 315.5683 315.7084 315.8486 315.9887 316.1288 316.2690 316.4091 316.5492 316.6893 316.8293 316.9694 317.1094 317.2495 317.3895 317.5295 317.6695 317.8095 317.9495 318.0895 318.2294 318.3694 318.5093 318.6492 318.7891 318.9290 319.0689 319.2088 319.3487 319.4885 319.6284 319.7682 319.9080 320.0478 320.1876 320.3274 320.4672 320.6069 320.7467 320.8864 321.0261 321.1659 321.3056 321.4452 321.5849 321.7246 321.8642 322.0039 322.1435 322.2831 322.4228 322.5623 322.7019 322.8415 322.9811 323.1206 323.2602 323.3997 323.5392 323.6787 323.8182 323.9577 324.0971 324.2366 324.3760 324.5155 324.6549 324.7943 324.9337 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230507T103032.4Z 8527.437875 223 1 51.66 2 82.15 74.83 82.35 240.32 0.00 1 0.00 1 0 25 5.859e-01 2.164e-02 2.658e-01 4.899e-03 7.209042e-01 2.715015e-03 7.352341e-03 -6.000000e+00 3.427366e-01 229.97 -2.00 3.11 -2.00 321.54 0.00e+00 4.749542e-03 1.517604e-03 4.246970e-03 -6.000000e+00 1.598799e-02 293.92 -2.00 20.00 -2.00 320.89 0.00e+00 6.821 0.001 302.00 328.00 3 1.1074e+00 1.0592e-02 8.1072e-02 -6.0000e+00 8.5415e-01 3.6238e-01 1.4575e-02 5.4846e-02 -6.0000e+00 9.2512e-01 -5.1109e-01 1.3401e-02 1.7319e-02 -6.0000e+00 5.5010e-01 2.1105e-01 6.2921e-03 1.2700e-02 -6.0000e+00 2.3533e-01 1.0563e-04 -6.9081e-04 1.3854e-04 7.6713e-05 -6.0000e+00 1.6267e-02 6.9805e-03 0.0000e+00 12 8 8 10 0 0 4.64 22.36 0.54 0.00698 0.00179 48 8 1 5 0 1076.110 25.90 20.00 22.36 30.03 20.5 1019.79 -123333 900000 -69511 4526 -223229 -162197 900000 900000 -109727 -144889 -126486 -95036 900000 900000 -140171 900000 -144737 81336 2248 32273 282374 -58125 111377 48917 124581 258855 -12591 41235 144371 61257 900000 29230 10685 68656 -6850 55970 -35456 11451 47716 23584 53436 54 -11917 3504 47464 3448 47160 21248 77742 -13888 13672 33335 21657 1479 28000 7671 21177 2869 4592 34508 16460 13746 25922 4076 11401 3007 -1328 3685 5381 122 -2557 19 -3896 -490 2301 7299 11097 -4904 -3503 -4986 4593 -6227 -6791 -2418 -1998 -369 -1281 1417 -3924 -1753 2866 -1120 1755 308 3011 4430 3796 3096 968 410 2126 1344 1776 -3242 -3692 -4576 -2907 -3405 -347 -1386 -338 -2163 -1318 -331 492 488 766 -190 -546 -647 -840 947 1408 1197 2502 181 2439 3872 1626 38 16 776 813 644 -1665 -742 2004 -507 -474 -781 -943 -298 105 -1070 900000 -452 22 -5906 -2181 900000 900000 -1204 -2419 -1810 -1088 900000 900000 -5216 900000 -7803 504 33 370 1347 -1636 584 513 654 1235 -276 511 689 643 900000 614 316 1245 -255 1068 -1810 426 1502 1136 2167 4 -1052 272 2400 276 2497 1510 3301 -1577 1311 2958 2376 217 3353 1171 2910 472 719 3902 2277 2138 4081 912 2551 725 -330 900 1417 39 -941 7 -1519 -175 727 1961 2663 -1397 -1103 -1910 1896 -3008 -3667 -1332 -1171 -228 -840 935 -2743 -1162 1696 -645 948 174 1866 3180 2951 2813 994 429 2067 1191 1421 -2712 -3337 -4425 -2914 -3690 -403 -1841 -500 -3509 -2155 -523 733 700 1103 -289 -888 -1101 -1422 1514 2159 1783 3540 253 3237 5281 2577 64 30 1561 1729 1358 -3858 -1801 4846 -1280 -1196 -1897 -2150 -681 229 SS 20230507T104558.5Z 8527.448594 228 1 51.86 2 78.61 75.88 85.45 241.67 0.00 1 0.00 1 0 25 1.538e-01 1.487e-02 2.978e-02 1.200e-03 5.441283e-01 6.188515e-04 5.925346e-03 -6.000000e+00 8.849375e-02 229.97 -2.00 3.11 -2.00 320.09 0.00e+00 -1.038048e-03 2.183384e-04 2.520655e-03 -6.000000e+00 4.055910e-03 293.92 -2.00 20.00 -2.00 319.25 0.00e+00 4.890 0.000 302.00 328.00 3 8.1893e-01 1.8997e-03 5.5893e-02 -6.0000e+00 2.2019e-01 6.8677e-03 2.3539e-03 3.1167e-02 -6.0000e+00 2.3813e-01 -6.9844e-02 1.9877e-03 1.2947e-02 -6.0000e+00 1.4262e-01 2.8620e-02 1.0193e-03 4.1273e-03 -6.0000e+00 6.0998e-02 1.1053e-03 5.2662e-05 3.3654e-05 4.3430e-05 -6.0000e+00 4.1316e-03 6.8977e-03 0.0000e+00 12 8 8 10 0 0 -0.31 22.36 0.41 0.00690 0.00729 196 31 1 5 0 264.560 25.90 20.00 22.36 31.15 20.6 1028.02 -40961 -50774 -37861 -58182 -83422 -75511 -31864 -29026 -42827 -52978 -37499 -14992 -14720 6013 -29142 9665 -17801 3547 -459 2192 1751 -9222 1437 1784 1209 8612 -5091 2589 135 -5599 12530 -772 3362 -92 -2262 1041 -3648 632 548 2235 3595 1068 1511 2351 3899 1204 2155 884 2342 73 1492 2334 588 754 835 1758 1740 191 1481 2764 2504 2337 2526 428 -1391 -758 -1091 -466 1166 -1317 -1416 -1552 -1751 -1016 -642 -170 145 -1135 -523 -1962 -1974 -2920 -3711 -2448 -1764 -1514 -1371 -1540 -1005 -843 310 1097 3117 4919 4985 4737 4831 4308 2503 1421 1411 1139 1817 555 -2651 -3282 -2629 -1647 -156 -23 -730 -1296 -771 -793 8 646 673 274 -433 -1158 -1022 -24 705 300 646 265 2096 2994 1085 -178 -562 -173 159 74 -556 -862 -38 -30 -479 -823 -222 453 1445 -388 -624 -443 -824 -1387 -1123 -332 -340 -667 -1011 -641 -221 -260 107 -904 241 -652 115 -17 82 69 -406 59 81 61 431 -300 137 7 -315 669 -55 264 -8 -198 86 -345 68 73 355 641 191 283 448 736 237 425 179 482 16 358 619 174 242 285 623 640 72 537 972 904 918 1113 197 -686 -360 -502 -216 579 -774 -857 -993 -1125 -619 -391 -93 72 -566 -282 -1255 -1357 -2309 -3017 -2087 -1601 -1473 -1313 -1529 -997 -866 294 957 2523 3932 4373 4458 4894 5000 3033 1744 1633 1280 1872 586 -3123 -4120 -3441 -2136 -216 -34 -1167 -2193 -1292 -1276 12 969 1010 408 -692 -1962 -1739 -39 1112 459 999 396 2956 4296 1664 -308 -1006 -309 297 145 -1124 -1844 -80 -64 -1024 -1788 -454 918 2817 SS 20230507T105152.9Z 8527.452696 231 1 51.84 2 77.25 76.28 86.65 242.16 0.00 1 0.00 1 0 25 7.787e-02 1.521e-02 1.531e-02 8.616e-04 4.916408e-01 4.403016e-04 5.367917e-03 -6.000000e+00 4.480582e-02 229.97 -2.00 3.11 -2.00 319.58 0.00e+00 -3.612416e-04 1.310979e-04 1.933551e-03 -6.000000e+00 2.053549e-03 293.92 -2.00 20.00 -2.00 318.69 0.00e+00 4.406 0.000 302.00 328.00 3 7.2728e-01 1.2897e-03 4.9998e-02 -6.0000e+00 1.1149e-01 -1.6010e-02 1.5403e-03 2.6852e-02 -6.0000e+00 1.2057e-01 -3.5630e-02 1.2065e-03 1.1410e-02 -6.0000e+00 7.2209e-02 1.2860e-02 6.3360e-04 3.8172e-03 -6.0000e+00 3.0885e-02 2.0195e-03 2.4349e-04 2.4327e-05 3.4617e-05 -6.0000e+00 2.0918e-03 6.6672e-03 0.0000e+00 12 8 8 10 0 0 -0.72 22.36 0.40 0.00667 0.00850 278 44 1 5 0 186.390 25.90 20.00 22.36 31.65 20.4 1030.39 -24615 -20993 -16599 -30819 -42152 -33461 -20784 -17478 -19196 -25130 -24596 -9710 -5151 275 -14311 793 -4603 3135 1507 2491 1258 722 1500 970 2907 2284 -37 1724 227 -1267 4707 514 2255 -1184 -2484 -556 -1523 1627 1327 1284 2805 460 969 974 2909 949 1161 85 757 178 1400 1060 339 237 743 1076 975 -201 629 2079 2335 1697 1940 799 -1437 -1428 -694 -163 834 -1205 -1701 -1335 -1532 -873 -754 -496 68 -645 -6 -1741 -1880 -2705 -3761 -2244 -1753 -1301 -1235 -1464 -930 -870 369 1305 3313 4743 5271 4873 4796 4662 2550 1450 1377 1259 1685 550 -2633 -3276 -2532 -1584 -200 -184 -736 -1231 -963 -954 -167 471 577 292 -348 -1179 -1024 -82 529 271 543 312 1944 2928 1081 -191 -590 -380 118 59 -659 -849 -141 -96 -452 -635 -282 579 1569 -345 -332 -271 -570 -793 -557 -328 -307 -395 -604 -610 -222 -134 8 -607 34 -231 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