File name: Pandora29s1_Fajardo_20230524_L2Fit_fout2c17d20220426p1-8.txt File generation date: 20260429T105954.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c17p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v17d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230524_L1_smca1c17d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230524 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0234 305.1644 305.3054 305.4464 305.5874 305.7283 305.8693 306.0102 306.1512 306.2921 306.4330 306.5739 306.7148 306.8557 306.9966 307.1374 307.2783 307.4191 307.5599 307.7007 307.8415 307.9823 308.1231 308.2639 308.4046 308.5454 308.6861 308.8268 308.9676 309.1083 309.2490 309.3896 309.5303 309.6710 309.8116 309.9522 310.0929 310.2335 310.3741 310.5147 310.6552 310.7958 310.9364 311.0769 311.2174 311.3579 311.4985 311.6390 311.7794 311.9199 312.0604 312.2008 312.3413 312.4817 312.6221 312.7625 312.9029 313.0433 313.1837 313.3240 313.4644 313.6047 313.7451 313.8854 314.0257 314.1660 314.3062 314.4465 314.5868 314.7270 314.8673 315.0075 315.1477 315.2879 315.4281 315.5683 315.7084 315.8486 315.9887 316.1288 316.2690 316.4091 316.5492 316.6893 316.8293 316.9694 317.1094 317.2495 317.3895 317.5295 317.6695 317.8095 317.9495 318.0895 318.2294 318.3694 318.5093 318.6492 318.7891 318.9290 319.0689 319.2088 319.3487 319.4885 319.6284 319.7682 319.9080 320.0478 320.1876 320.3274 320.4672 320.6069 320.7467 320.8864 321.0261 321.1659 321.3056 321.4452 321.5849 321.7246 321.8642 322.0039 322.1435 322.2831 322.4228 322.5623 322.7019 322.8415 322.9811 323.1206 323.2602 323.3997 323.5392 323.6787 323.8182 323.9577 324.0971 324.2366 324.3760 324.5155 324.6549 324.7943 324.9337 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230524T102441.8Z 8544.433818 54 1 51.87 2 82.38 70.59 127.28 35.51 0.00 1 0.00 1 0 25 6.348e-01 1.703e-02 2.856e-01 4.359e-03 8.092803e-01 2.456997e-03 8.654790e-03 -6.000000e+00 3.703000e-01 229.69 -2.00 3.11 -2.00 321.74 0.00e+00 -5.221152e-03 1.485822e-03 7.246000e-03 -6.000000e+00 1.834324e-02 294.40 -2.00 20.00 -2.00 321.13 0.00e+00 6.998 0.001 302.00 328.00 3 7.0308e-01 1.0165e-02 8.8927e-02 -6.0000e+00 9.2595e-01 2.9588e-01 1.5083e-02 6.8275e-02 -6.0000e+00 1.0035e+00 -4.4595e-01 1.4898e-02 2.6107e-02 -6.0000e+00 5.9497e-01 1.8465e-01 6.7818e-03 6.8056e-03 -6.0000e+00 2.5492e-01 1.2807e-04 -1.3208e-03 1.1888e-04 1.1843e-04 -6.0000e+00 1.7608e-02 -5.2545e-04 0.0000e+00 12 8 8 10 0 0 81.18 22.25 0.53 -0.00053 -0.01045 67 11 1 5 0 774.020 25.47 20.00 22.25 30.61 20.7 1021.23 -236570 33936 -127702 -202110 -146672 -224343 -219749 900000 900000 -223496 -168268 900000 900000 900000 -166398 900000 -108535 141824 12016 211 3262 -95608 38209 58093 43739 266163 -22131 21881 35596 -32739 900000 -30295 26293 121217 18532 153838 -57189 -2036 -4602 45008 28996 -11637 -4500 17404 33619 -17897 37243 27533 51008 -1944 -1908 42581 14355 -620 14796 3493 22587 2258 7154 20718 10785 12721 12083 6927 6767 3953 -1796 1778 954 -483 -4797 -3295 -2432 -1227 4247 4751 6256 -4797 -6465 -2859 3132 -5199 -4447 -1703 -1720 -728 1056 1264 -2957 11 3331 -468 779 1849 4462 4216 5227 3533 1596 750 490 144 841 -1031 -3346 -5257 -5563 -2654 -68 -1354 -73 -2007 -643 -310 1279 1252 1318 267 -1489 -1141 -808 837 1339 938 1195 433 1212 4048 1376 -166 -362 455 480 512 -751 -540 181 -183 -61 -968 -460 -294 978 -2283 144 -542 -1794 -679 -2165 -2205 900000 900000 -3623 -1857 900000 900000 900000 -3956 900000 -2028 602 82 2 26 -2070 227 321 316 1130 -348 214 287 -542 900000 -707 413 823 346 718 -2379 -58 -168 1242 1096 -721 -273 865 1413 -1269 1550 1309 2036 -143 -158 2585 1292 -72 1602 451 2532 314 914 2217 1273 1588 1734 1206 1290 779 -374 375 224 -134 -1568 -1126 -825 -390 1165 1156 1386 -1202 -1842 -944 1165 -2454 -2132 -853 -923 -414 622 768 -1881 7 1806 -248 396 965 2566 2867 3798 3041 1563 758 472 126 657 -803 -2855 -4854 -5419 -2704 -74 -1719 -104 -3188 -1037 -491 1916 1804 1900 406 -2441 -1792 -1357 1322 2021 1378 1689 598 1610 5434 2166 -284 -693 937 1053 1116 -1786 -1357 463 -478 -160 -2441 -1076 -640 2164 SS 20230524T104121.2Z 8544.445384 59 1 51.79 2 78.64 71.68 125.01 38.96 0.00 1 0.00 1 0 25 1.663e-01 1.504e-02 6.036e-02 1.469e-03 5.860422e-01 7.654263e-04 6.543404e-03 -6.000000e+00 9.564260e-02 229.69 -2.00 3.11 -2.00 320.45 0.00e+00 -2.279193e-03 3.069093e-04 3.575579e-03 -6.000000e+00 4.395852e-03 294.40 -2.00 20.00 -2.00 319.65 0.00e+00 4.904 0.000 302.00 328.00 3 1.0179e+00 2.4475e-03 5.8257e-02 -6.0000e+00 2.3778e-01 5.3395e-03 3.1331e-03 3.6560e-02 -6.0000e+00 2.5709e-01 -6.8341e-02 2.8135e-03 1.4789e-02 -6.0000e+00 1.5406e-01 2.8489e-02 1.4213e-03 4.3522e-03 -6.0000e+00 6.6039e-02 8.5043e-04 -6.0822e-04 4.0742e-05 5.6918e-05 -6.0000e+00 4.4649e-03 8.1896e-04 0.0000e+00 12 8 8 10 0 0 99.99 22.25 0.49 0.00082 -0.00375 250 39 1 5 0 207.110 25.47 20.00 22.25 32.01 20.8 1031.07 -30064 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689 835 410 -575 -427 -549 -160 464 -410 -1076 -1013 -1027 -552 -405 -81 272 -418 -425 -1043 -1316 -1817 -3332 -2379 -1720 -1418 -961 -1601 -1149 -700 352 1138 2550 3810 4155 4688 4745 5231 3259 1456 1438 1169 1863 705 -2936 -4562 -3868 -2273 -194 -126 -864 -1950 -1274 -1419 165 987 1382 441 -798 -1990 -1973 -60 696 706 1098 326 2384 4517 1955 -27 -999 -419 331 429 -1531 -1919 -136 -6 -823 -1657 -696 658 3229 SS 20230524T110358.9Z 8544.461098 71 1 52.19 2 73.53 73.06 121.65 43.22 0.00 1 0.00 1 0 25 3.815e-02 1.620e-02 1.174e-02 1.224e-03 4.148746e-01 6.213434e-04 4.663801e-03 -6.000000e+00 2.195136e-02 229.69 -2.00 3.11 -2.00 318.82 0.00e+00 -4.215920e-04 1.437450e-04 1.519856e-03 -6.000000e+00 1.008817e-03 294.40 -2.00 20.00 -2.00 317.87 0.00e+00 3.469 0.000 302.00 328.00 3 2.4172e+00 1.7330e-03 3.9880e-02 -6.0000e+00 5.4574e-02 -3.3450e-02 2.0094e-03 2.1862e-02 -6.0000e+00 5.9002e-02 1.3722e-03 1.4023e-03 9.6803e-03 -6.0000e+00 3.5357e-02 -3.5443e-03 7.3993e-04 2.8986e-03 -6.0000e+00 1.5160e-02 9.7568e-04 -1.3991e-04 3.4696e-05 2.9727e-05 -6.0000e+00 1.0245e-03 -6.7815e-04 0.0000e+00 12 8 8 10 0 0 96.39 22.25 0.44 -0.00068 -0.00173 73 11 1 5 0 714.740 25.47 19.99 22.25 31.31 20.8 1025.38 -18790 -6773 -11463 -8882 -12950 -12628 -339 -5292 -5149 -15822 -9888 7575 2412 7076 -6764 5080 -2632 2015 882 1692 -27 -2651 5236 3116 3197 2788 -569 1749 2769 1667 6455 1043 1007 -1765 -2568 -681 -2963 1189 789 460 170 -514 -580 591 1287 -126 812 226 456 -257 637 1316 591 -69 137 670 313 -145 109 1529 2529 1913 1904 901 -1249 -1303 -897 291 1250 -1005 -1729 -1719 -1941 -1121 -731 -165 984 -83 161 -1406 -1319 -2391 -3717 -2294 -1736 -1612 -1265 -1425 -967 -796 466 1429 3244 5207 5277 5200 5260 4835 2698 1501 1457 1102 1583 776 -2446 -3397 -2756 -1925 -221 42 -659 -1339 -1075 -1198 -440 392 670 9 -388 -1121 -1163 -370 410 227 808 287 1427 2964 1347 -104 -690 -415 13 181 -534 -887 -164 -86 -344 -603 -279 451 1641 -563 -209 -397 -295 -405 -374 -9 -176 -197 -739 -447 300 116 391 -513 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