File name: Pandora29s1_Fajardo_20230911_L2Fit_fwvt1c0d20220426p1-8.txt File generation date: 20230913T080317.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20230911_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20230911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1664 1813 Nominal wavelengths inside fitting window [nm]: 492.0727 492.1935 492.3144 492.4352 492.5560 492.6768 492.7976 492.9184 493.0391 493.1599 493.2806 493.4013 493.5220 493.6426 493.7633 493.8839 494.0045 494.1251 494.2457 494.3663 494.4868 494.6074 494.7279 494.8484 494.9688 495.0893 495.2097 495.3302 495.4506 495.5710 495.6914 495.8117 495.9321 496.0524 496.1727 496.2930 496.4132 496.5335 496.6537 496.7740 496.8942 497.0144 497.1345 497.2547 497.3748 497.4949 497.6150 497.7351 497.8552 497.9752 498.0953 498.2153 498.3353 498.4553 498.5752 498.6952 498.8151 498.9350 499.0549 499.1748 499.2947 499.4145 499.5343 499.6541 499.7739 499.8937 500.0135 500.1332 500.2529 500.3726 500.4923 500.6120 500.7316 500.8513 500.9709 501.0905 501.2101 501.3297 501.4492 501.5687 501.6883 501.8078 501.9272 502.0467 502.1662 502.2856 502.4050 502.5244 502.6438 502.7631 502.8825 503.0018 503.1211 503.2404 503.3597 503.4789 503.5982 503.7174 503.8366 503.9558 504.0750 504.1941 504.3133 504.4324 504.5515 504.6706 504.7896 504.9087 505.0277 505.1467 505.2657 505.3847 505.5037 505.6226 505.7415 505.8604 505.9793 506.0982 506.2171 506.3359 506.4547 506.5735 506.6923 506.8111 506.9299 507.0486 507.1673 507.2860 507.4047 507.5234 507.6420 507.7606 507.8793 507.9979 508.1164 508.2350 508.3535 508.4721 508.5906 508.7091 508.8275 508.9460 509.0644 509.1829 509.3013 509.4197 509.5380 509.6564 509.7747 509.8930 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230911T131127.2Z 8654.549620 2 1 5.53 2 47.87 100.86 11.76 67.21 0.00 1 0.00 1 0 15 2.121e-03 2.115e-03 7.618e-05 7.606e-05 3.764438e+03 4.974649e+00 2.430541e+02 -6.000000e+00 1.252491e+02 294.90 -2.00 20.00 -2.00 505.24 0.00e+00 1.258260e-04 2.176262e-06 1.783255e-05 -6.000000e+00 6.185171e-05 294.90 -2.00 20.00 -2.00 500.39 0.00e+00 -1.820634e-02 1.513054e-03 2.510891e-02 -6.000000e+00 4.235070e-02 227.28 -2.00 3.11 -2.00 501.99 0.00e+00 1.488 0.000 489.00 513.00 1 4.1650e-01 1.1646e-04 3.0063e-03 -6.0000e+00 3.2601e-03 -6.9085e-03 3.0052e-05 5.7815e-04 -6.0000e+00 8.4790e-04 1.0418e+00 5.5888e-04 7.8547e-06 2.1754e-05 -6.0000e+00 2.2729e-04 1.8108e-02 -4.1001e-04 10 0 0 10 0 0 7.33 20.39 1.79 0.01811 0.02198 1509 238 1 4 0 2.970 24.46 20.00 20.39 39.61 23.8 1067.67 144 -64 -299 -263 -162 41 165 71 101 174 110 7 -307 -300 -101 114 168 63 -47 -100 96 288 314 263 199 141 -23 -231 -237 -72 279 419 172 -105 -300 -369 -216 7 44 1 94 117 75 7 30 24 61 -35 -165 -281 -188 170 352 351 121 -148 -326 -327 -198 69 266 338 168 -45 -65 -11 22 -64 -128 -19 277 420 230 -6 -170 -250 -157 -205 -257 -191 -62 -188 -238 -180 -148 -182 -252 -137 66 190 252 136 3 -217 -183 41 37 -114 -64 121 179 214 -55 -400 -646 -586 -278 93 295 336 192 -36 -21 140 242 366 359 138 -4 51 264 382 368 279 36 -86 14 70 -61 -134 -245 -286 24 173 184 216 117 -111 -168 9 29 59 24 -51 -215 -352 -375 -109 165 232 140 -63 -299 -268 -165 43 172 74 106 182 113 7 -313 -302 -102 116 170 64 -49 -105 101 304 327 275 208 148 -24 -239 -244 -73 279 417 175 -107 -311 -384 -227 7 45 1 96 120 77 7 31 25 64 -36 -168 -283 -187 166 343 342 119 -149 -331 -333 -202 70 271 344 171 -46 -66 -11 22 -64 -127 -19 269 406 224 -6 -168 -247 -153 -199 -247 -185 -60 -181 -232 -177 -145 -180 -248 -135 65 187 249 136 3 -219 -183 41 36 -110 -61 114 168 202 -53 -390 -643 -583 -275 91 287 327 189 -36 -21 140 242 368 363 141 -4 51 263 375 362 275 35 -84 13 69 -59 -131 -238 -279 23 165 175 207 112 -108 -163 9 29 59 23 -51 -216 -352 -370 -106 159 221 SQ 20230911T131135.1Z 8654.549712 2 2 8.86 2 47.84 100.88 11.73 67.16 0.00 1 0.00 1 0 15 2.099e-03 2.092e-03 7.625e-05 7.613e-05 3.769832e+03 4.979741e+00 2.434670e+02 -6.000000e+00 1.239207e+02 294.90 -2.00 20.00 -2.00 505.24 0.00e+00 1.268174e-04 2.178231e-06 1.788590e-05 -6.000000e+00 6.119544e-05 294.90 -2.00 20.00 -2.00 500.39 0.00e+00 -2.042851e-02 1.514454e-03 2.513058e-02 -6.000000e+00 4.190104e-02 227.28 -2.00 3.11 -2.00 501.99 0.00e+00 1.487 0.000 489.00 513.00 1 4.1865e-01 1.1657e-04 3.0070e-03 -6.0000e+00 3.2255e-03 -6.8617e-03 3.0080e-05 5.7877e-04 -6.0000e+00 8.3888e-04 1.0399e+00 5.3506e-04 7.8619e-06 2.1794e-05 -6.0000e+00 2.2488e-04 1.7942e-02 -4.0772e-04 10 0 0 10 0 0 29.25 20.39 1.79 0.01794 0.02165 1509 238 1 4 0 2.970 24.46 20.00 20.39 39.61 23.8 1067.67 151 -68 -302 -263 -148 33 169 63 112 189 108 -12 -306 -289 -92 123 157 56 -62 -96 94 296 305 262 201 141 -18 -236 -232 -70 265 428 156 -85 -313 -368 -221 14 46 5 82 128 85 -8 16 28 69 -34 -173 -277 -190 179 362 342 121 -143 -339 -317 -195 58 251 336 157 -63 -88 -17 26 -55 -118 -10 293 422 230 -5 -150 -245 -160 -199 -255 -197 -61 -182 -243 -178 -128 -177 -258 -132 64 179 241 142 12 -207 -181 24 39 -111 -63 104 173 218 -44 -376 -627 -584 -282 101 268 339 191 -45 -28 127 236 345 351 148 6 51 268 361 369 268 33 -88 -3 76 -55 -136 -253 -276 29 210 196 232 112 -107 -172 -4 12 56 9 -52 -199 -329 -365 -114 144 241 147 -67 -302 -268 -151 35 177 66 117 198 112 -12 -313 -291 -93 124 159 57 -64 -101 100 312 318 274 211 148 -19 -244 -238 -71 266 427 159 -87 -325 -383 -232 14 47 6 84 132 87 -8 17 29 72 -35 -176 -279 -189 175 352 334 119 -143 -345 -322 -199 59 255 342 161 -64 -90 -17 26 -54 -117 -9 284 408 224 -4 -149 -242 -156 -193 -245 -191 -59 -175 -236 -174 -125 -175 -253 -130 62 176 238 142 12 -208 -181 24 38 -107 -60 99 163 206 -42 -367 -624 -581 -279 100 261 330 188 -44 -28 127 237 347 354 150 6 51 267 354 363 264 33 -86 -3 75 -54 -132 -246 -269 28 201 186 221 108 -104 -168 -4 12 55 9 -52 -200 -329 -360 -111 139 230 SQ 20230911T131142.9Z 8654.549802 2 3 6.26 2 47.81 100.90 11.70 67.12 0.00 1 0.00 1 0 15 2.109e-03 2.104e-03 7.646e-05 7.634e-05 3.767535e+03 4.990913e+00 2.438485e+02 -6.000000e+00 1.245602e+02 294.90 -2.00 20.00 -2.00 505.24 0.00e+00 1.289318e-04 2.183523e-06 1.783153e-05 -6.000000e+00 6.151164e-05 294.90 -2.00 20.00 -2.00 500.38 0.00e+00 -1.905508e-02 1.516608e-03 2.494232e-02 -6.000000e+00 4.211796e-02 227.28 -2.00 3.11 -2.00 501.98 0.00e+00 1.486 0.000 489.00 513.00 1 4.2509e-01 1.1672e-04 2.9964e-03 -6.0000e+00 3.2421e-03 -6.8815e-03 3.0148e-05 5.7582e-04 -6.0000e+00 8.4324e-04 1.0332e+00 5.7827e-04 7.8883e-06 2.1933e-05 -6.0000e+00 2.2604e-04 1.8002e-02 -4.0984e-04 10 0 0 10 0 0 15.10 20.40 1.79 0.01800 0.02201 1509 238 1 4 0 2.970 24.46 20.00 20.40 39.61 23.8 1067.67 146 -68 -286 -274 -147 40 180 75 111 171 125 -10 -299 -310 -109 108 150 58 -52 -100 90 302 324 277 203 148 -33 -236 -228 -65 260 429 159 -83 -303 -362 -215 8 27 -13 85 124 76 -7 20 43 62 -30 -172 -300 -191 178 361 337 138 -142 -337 -323 -205 97 264 318 142 -69 -58 -14 33 -60 -132 -19 277 422 225 -7 -161 -245 -153 -195 -240 -182 -64 -168 -252 -185 -149 -194 -254 -120 74 199 252 138 6 -201 -168 26 46 -101 -66 101 183 210 -59 -388 -632 -594 -283 99 284 331 174 -47 -22 138 242 358 348 151 -6 63 259 369 351 246 31 -84 5 86 -64 -151 -258 -275 16 211 208 218 112 -114 -177 3 34 68 18 -47 -213 -345 -368 -103 168 230 142 -67 -285 -278 -152 41 188 79 117 179 129 -11 -304 -316 -111 109 152 60 -55 -105 95 317 341 289 212 155 -35 -248 -234 -66 260 427 161 -85 -314 -381 -225 9 28 -14 87 127 78 -7 21 45 65 -31 -177 -302 -189 174 351 328 135 -142 -342 -328 -208 98 267 323 145 -71 -60 -14 33 -59 -130 -19 272 412 219 -7 -158 -242 -151 -189 -233 -176 -62 -162 -244 -181 -145 -191 -252 -119 73 198 249 138 6 -202 -168 25 46 -97 -63 95 171 199 -56 -377 -628 -589 -282 97 279 325 170 -46 -22 139 241 360 351 153 -6 63 258 361 345 241 30 -82 5 84 -62 -147 -253 -267 15 200 197 208 107 -111 -174 3 34 67 18 -47 -213 -344 -362 -100 162 222 SQ 20230911T131149.5Z 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