File name: Pandora29s1_Fajardo_20231209_L2Fit_fout2c0d20220426p1-8.txt File generation date: 20240113T145358.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 29 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora29_OF_v2d20211130.txt Instrument calibration file used: Pandora29s1_CF_v2d20220426.txt Level 1 file used: Pandora29s1_Fajardo_20231209_L1_smca1c0d20220426p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20231209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.0193 305.1603 305.3013 305.4423 305.5833 305.7243 305.8652 306.0062 306.1471 306.2880 306.4289 306.5699 306.7107 306.8516 306.9925 307.1334 307.2742 307.4150 307.5559 307.6967 307.8375 307.9783 308.1190 308.2598 308.4006 308.5413 308.6820 308.8228 308.9635 309.1042 309.2449 309.3855 309.5262 309.6668 309.8075 309.9481 310.0887 310.2293 310.3699 310.5105 310.6511 310.7917 310.9322 311.0727 311.2133 311.3538 311.4943 311.6348 311.7753 311.9157 312.0562 312.1966 312.3371 312.4775 312.6179 312.7583 312.8987 313.0391 313.1794 313.3198 313.4601 313.6005 313.7408 313.8811 314.0214 314.1617 314.3019 314.4422 314.5825 314.7227 314.8629 315.0031 315.1433 315.2835 315.4237 315.5639 315.7040 315.8442 315.9843 316.1244 316.2646 316.4047 316.5447 316.6848 316.8249 316.9649 317.1050 317.2450 317.3850 317.5250 317.6650 317.8050 317.9450 318.0849 318.2249 318.3648 318.5048 318.6447 318.7846 318.9245 319.0643 319.2042 319.3441 319.4839 319.6237 319.7636 319.9034 320.0432 320.1829 320.3227 320.4625 320.6022 320.7420 320.8817 321.0214 321.1611 321.3008 321.4405 321.5802 321.7198 321.8595 321.9991 322.1387 322.2783 322.4179 322.5575 322.6971 322.8367 322.9762 323.1157 323.2553 323.3948 323.5343 323.6738 323.8133 323.9527 324.0922 324.2316 324.3711 324.5105 324.6499 324.7893 324.9287 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231209T111323.0Z 8743.467627 143 1 52.50 2 84.30 116.34 44.83 134.46 0.00 1 0.00 1 0 25 7.088e-01 3.089e-02 3.073e-01 9.604e-03 7.696700e-01 5.682171e-03 7.965518e-03 -6.000000e+00 4.190411e-01 225.33 -2.00 3.11 -2.00 322.04 0.00e+00 2.048993e-02 3.651229e-03 7.483770e-03 -6.000000e+00 2.383357e-02 292.56 -2.00 20.00 -2.00 321.49 0.00e+00 8.878 0.003 302.00 328.00 3 5.1377e-01 2.4596e-02 1.1624e-01 -6.0000e+00 1.0407e+00 9.2430e-01 3.3547e-02 1.0797e-01 -6.0000e+00 1.1418e+00 -1.0748e+00 2.9367e-02 2.0054e-02 -6.0000e+00 6.7355e-01 4.0904e-01 1.3564e-02 2.8476e-02 -6.0000e+00 2.8860e-01 2.3085e-05 -1.4752e-03 2.8376e-04 2.1528e-04 -6.0000e+00 1.9618e-02 -3.6870e-04 6.1085e-06 12 8 8 10 0 0 73.74 20.26 0.83 -0.00037 -0.01145 38 6 1 5 0 1380.990 24.25 20.00 20.26 31.13 25.8 1004.47 5699 -104576 -136598 6110 900000 -99446 900000 900000 900000 -144221 -93121 900000 900000 900000 -129821 900000 -55591 900000 900000 900000 900000 5630 243304 900000 900000 900000 -2435 900000 57835 900000 900000 24737 900000 146617 76900 900000 -63833 60194 180001 333048 412241 16824 23686 9298 73061 31012 900000 28082 900000 -24741 44580 120262 77315 18720 67420 23567 41055 17577 13829 140029 30370 28798 74995 26832 40709 21889 4524 3511 16404 -4410 3082 2311 -7036 4743 19863 -2036 26159 -22462 -14737 -9233 14385 -1900 -12317 -7997 -9300 6216 1580 6607 -1141 2682 9425 -8431 12984 -1485 -2851 4331 5335 6730 -421 508 4883 -1391 4189 -6351 -4594 -6955 -1338 -5577 109 -1430 1260 -2963 -182 -1273 -653 -2056 488 -773 -2684 -373 -214 1287 2348 2198 1378 1670 1660 4630 2973 -1212 -331 1088 662 1119 -2289 -99 4633 -946 -64 -1078 -807 -693 -1120 53 -2570 -4978 57 900000 -1770 900000 900000 900000 -3422 -1263 900000 900000 900000 -6271 900000 -1837 900000 900000 900000 900000 121 2268 900000 900000 900000 -48 900000 593 900000 900000 600 900000 1367 1362 900000 -4284 1291 1678 3105 3843 863 1192 563 2384 1590 900000 1597 900000 -2652 2618 3699 3964 1850 4274 2329 3406 1802 1405 3916 2605 2765 5243 3527 5123 3306 797 638 2814 -1073 776 612 -2020 1132 3685 -416 3706 -5235 -3586 -2599 3835 -693 -5569 -3668 -4577 2793 782 3221 -606 1338 4112 -4102 4902 -664 -1464 2242 3250 4768 -362 447 3906 -1066 2687 -4386 -3356 -5558 -1069 -5043 103 -1579 1549 -4156 -256 -1776 -867 -2659 619 -1047 -3960 -566 -323 1826 3169 2891 1765 2073 1991 5567 4190 -2074 -632 2226 1444 2377 -5428 -244 11158 -2453 -166 -2718 -1898 -1519 -2558 SS 20231209T112558.9Z 8743.476376 146 1 51.82 2 81.64 117.50 42.83 137.70 0.00 1 0.00 1 0 25 2.933e-01 1.495e-02 1.604e-01 2.128e-03 6.247071e-01 1.109375e-03 6.889879e-03 -6.000000e+00 1.637031e-01 225.33 -2.00 3.11 -2.00 320.99 0.00e+00 -6.270184e-03 5.343013e-04 3.643158e-03 -6.000000e+00 7.922677e-03 292.56 -2.00 20.00 -2.00 320.29 0.00e+00 6.457 0.001 302.00 328.00 3 8.1034e-01 3.8681e-03 7.1412e-02 -6.0000e+00 4.0330e-01 -2.2348e-02 5.3035e-03 3.6097e-02 -6.0000e+00 4.3789e-01 -9.3298e-02 5.2180e-03 1.8853e-02 -6.0000e+00 2.6290e-01 4.8084e-02 2.5290e-03 5.5515e-03 -6.0000e+00 1.1444e-01 2.5429e-04 -3.3315e-04 5.8396e-05 9.4304e-05 -6.0000e+00 7.5284e-03 -1.6860e-03 -1.9272e-05 12 8 8 10 0 0 99.95 20.28 0.53 -0.00169 -0.00419 162 26 1 5 0 319.810 24.25 20.00 20.28 31.34 25.7 1005.83 -70317 -127376 -109877 -43035 -81290 -103602 -27099 151981 -8724 -61129 -120761 900000 -15961 -24734 -101961 10147 -16694 34181 30023 44882 -86 -25172 -11291 17020 25395 28912 -4139 12992 10485 3387 37077 1219 2153 -2301 172 6553 -17126 -5869 -2077 13975 9615 4267 7041 4134 7167 -1226 9779 -4416 6010 -6446 1889 4226 946 1912 3328 3913 6885 2217 4000 6941 3485 2346 4806 1097 -184 -1631 -2579 -1456 -486 -468 -928 -2055 -1477 -531 -297 -788 813 -3128 -3014 -3931 -2469 -3634 -5085 -3618 -2998 -1288 -692 -770 -697 -192 379 776 3473 4021 5300 4929 4945 5030 3553 2231 1372 116 298 -1886 -3869 -4637 -3171 -1329 554 72 208 -441 -83 -379 177 140 473 -342 -682 -1343 -826 14 812 652 694 546 1369 2368 1232 -186 -438 -336 62 0 -793 -549 176 89 -26 -612 -508 310 1165 -263 -1004 -798 -161 -405 -623 -84 315 -33 -444 -1704 900000 -103 -216 -2370 93 -225 305 305 419 -1 -501 -206 268 422 510 -106 272 211 74 662 37 76 -95 7 233 -842 -308 -132 948 796 406 688 426 714 -134 972 -517 661 -852 256 635 163 360 670 831 1500 515 890 1452 759 558 1265 341 -57 -550 -856 -490 -161 -181 -408 -973 -702 -239 -123 -295 275 -1088 -1141 -1780 -1299 -2236 -3545 -2649 -2147 -979 -554 -641 -585 -157 287 546 2478 2643 3807 4113 4401 5151 4101 2463 1559 122 282 -1810 -4123 -5314 -3766 -1660 739 101 324 -740 -141 -624 275 207 691 -527 -1124 -2197 -1350 24 1310 1023 1046 797 1903 3327 1972 -320 -831 -681 123 -1 -1813 -1252 410 211 -63 -1426 -1116 676 2424 SS 20231209T113937.4Z 8743.485850 151 1 51.90 2 78.79 118.84 40.81 141.52 0.00 1 0.00 1 0 25 8.110e-02 1.634e-02 2.221e-02 8.962e-04 4.908006e-01 4.527503e-04 5.471590e-03 -6.000000e+00 4.525807e-02 225.33 -2.00 3.11 -2.00 319.92 0.00e+00 -2.815751e-03 1.507188e-04 2.237676e-03 -6.000000e+00 2.097796e-03 292.55 -2.00 20.00 -2.00 319.08 0.00e+00 4.961 0.000 302.00 328.00 3 8.2216e-01 1.3597e-03 5.4564e-02 -6.0000e+00 1.1150e-01 -7.5590e-02 1.6708e-03 2.6400e-02 -6.0000e+00 1.2103e-01 -3.2237e-03 1.4100e-03 1.2516e-02 -6.0000e+00 7.2677e-02 6.5482e-03 7.3147e-04 3.2526e-03 -6.0000e+00 3.1553e-02 1.1463e-03 -8.5322e-05 2.4869e-05 4.8920e-05 -6.0000e+00 2.0757e-03 -2.2596e-03 5.0704e-07 12 8 8 10 0 0 99.99 20.28 0.45 -0.00226 -0.00290 396 62 1 5 0 131.030 24.25 20.00 20.28 31.56 25.9 1007.76 -37428 -30643 -27126 -31369 -20458 -35941 -31377 1679 -6296 -20659 -25385 5107 659 -8761 -16381 557 -4486 5101 2532 2957 -102 2172 3120 5541 4804 6554 2351 4982 1800 1570 6966 255 976 -1605 -3976 -755 -3585 347 1933 2551 3515 1756 2683 2371 3225 1942 1780 -41 291 -779 415 927 418 590 621 1128 1466 687 1395 2254 1675 1675 2182 1407 -750 -1999 -1233 -1045 -111 -864 -1479 -1153 -1465 -937 -999 -843 -368 -1661 -1210 -2547 -2782 -3166 -4078 -3175 -2259 -1639 -1245 -1254 -474 -365 413 1544 3518 5030 5749 5471 5385 5405 4029 2699 1793 642 -4 -1328 -3603 -4262 -2949 -1239 422 279 -225 -578 -602 -651 -419 35 165 -199 -600 -1149 -1071 -191 728 505 641 467 1239 2532 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