File name: Pandora60s1_Fajardo_20251231_L2Fit_fout2c14d20240201p1-8.txt File generation date: 20260205T143659.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 60 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora60_OF_v1d20230913.txt Instrument calibration file used: Pandora60s1_CF_v14d20240201.txt Level 1 file used: Pandora60s1_Fajardo_20251231_L1_smca1c14d20240201p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20251231 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 13 First and last pixel inside fitting window: 185 327 Nominal wavelengths inside fitting window [nm]: 305.0457 305.1868 305.3279 305.4690 305.6101 305.7511 305.8922 306.0332 306.1742 306.3153 306.4563 306.5973 306.7382 306.8792 307.0202 307.1611 307.3021 307.4430 307.5839 307.7248 307.8657 308.0066 308.1475 308.2883 308.4292 308.5700 308.7109 308.8517 308.9925 309.1333 309.2741 309.4148 309.5556 309.6964 309.8371 309.9778 310.1186 310.2593 310.4000 310.5407 310.6813 310.8220 310.9626 311.1033 311.2439 311.3845 311.5251 311.6657 311.8063 311.9469 312.0875 312.2280 312.3686 312.5091 312.6496 312.7901 312.9306 313.0711 313.2116 313.3521 313.4925 313.6329 313.7734 313.9138 314.0542 314.1946 314.3350 314.4754 314.6157 314.7561 314.8964 315.0368 315.1771 315.3174 315.4577 315.5980 315.7382 315.8785 316.0188 316.1590 316.2992 316.4394 316.5796 316.7198 316.8600 317.0002 317.1404 317.2805 317.4206 317.5608 317.7009 317.8410 317.9811 318.1212 318.2612 318.4013 318.5413 318.6814 318.8214 318.9614 319.1014 319.2414 319.3814 319.5214 319.6613 319.8013 319.9412 320.0811 320.2210 320.3609 320.5008 320.6407 320.7806 320.9204 321.0603 321.2001 321.3399 321.4797 321.6195 321.7593 321.8991 322.0389 322.1786 322.3183 322.4581 322.5978 322.7375 322.8772 323.0169 323.1565 323.2962 323.4359 323.5755 323.7151 323.8547 323.9943 324.1339 324.2735 324.4131 324.5526 324.6922 324.8317 324.9712 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251231T115005.7Z 9496.493121 182 1 29.96 2 78.98 119.02 131.78 331.07 0.00 1 0.00 1 0 25 1.474e-01 7.327e-03 2.274e-02 1.209e-03 4.675541e-01 6.334852e-04 4.948820e-03 -6.000000e+00 8.549543e-02 224.86 -2.00 3.11 -2.00 320.39 0.00e+00 1.871988e-03 2.408255e-04 1.074699e-03 -6.000000e+00 3.952488e-03 291.99 -2.00 20.00 -2.00 319.63 0.00e+00 5.040 0.001 302.00 328.00 3 1.8030e-01 1.9627e-03 5.4048e-02 -6.0000e+00 2.1030e-01 1.9148e-02 2.4631e-03 2.2452e-02 -6.0000e+00 2.2735e-01 -6.8298e-02 2.0695e-03 1.1328e-02 -6.0000e+00 1.3652e-01 2.5749e-02 1.0551e-03 3.3666e-03 -6.0000e+00 5.9813e-02 1.9795e-03 -1.6345e-03 3.6269e-05 4.3938e-05 -6.0000e+00 4.1626e-03 -1.1605e-01 1.4491e-04 11 8 0 10 0 0 7.66 24.57 0.27 -0.11605 -0.12833 448 448 1 5 0 66.860 27.56 20.00 24.57 30.22 5.8 1009.39 900000 -49294 -44122 -41130 -49867 -50067 -55411 -58175 -45699 -37938 -42378 -42625 -38627 -36269 -21510 -18295 -11192 -11161 -3541 -4252 -753 -5761 -5759 -5369 -1983 -4522 -6424 -8079 -9979 -7441 -9066 -5123 -4094 707 -2574 -3181 -6435 -5380 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-666 386 1483 1472 1376 1253 1046 122 -462 249 -534 -24 -496 -436 170 1353 767 203 -192 -1945 301 442 -637 -109 -604 -79 -130 457 -468 -676 1556 735 -187 -80 -585 -402 SS 20251231T115523.0Z 9496.496794 185 1 29.94 2 77.88 119.56 132.33 332.41 0.00 1 0.00 1 0 25 9.499e-02 6.946e-03 1.504e-02 9.215e-04 4.323175e-01 4.835553e-04 4.661879e-03 -6.000000e+00 5.508117e-02 224.86 -2.00 3.11 -2.00 320.07 0.00e+00 2.393357e-03 1.640908e-04 9.888142e-04 -6.000000e+00 2.546465e-03 291.99 -2.00 20.00 -2.00 319.28 0.00e+00 4.620 0.000 302.00 328.00 3 1.6518e-01 1.4317e-03 4.9612e-02 -6.0000e+00 1.3549e-01 3.0840e-03 1.7554e-03 2.0622e-02 -6.0000e+00 1.4648e-01 -3.7430e-02 1.4287e-03 1.0575e-02 -6.0000e+00 8.7955e-02 1.1395e-02 7.4244e-04 3.3295e-03 -6.0000e+00 3.8533e-02 3.0901e-03 -1.6489e-03 2.7813e-05 4.2434e-05 -6.0000e+00 2.6821e-03 -1.1573e-01 1.4058e-04 11 8 0 10 0 0 8.19 24.57 0.28 -0.11573 -0.12812 563 563 1 5 0 53.160 27.56 20.00 24.57 30.71 5.8 1012.31 900000 -19905 -32212 -19868 -36983 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537 -226 225 581 541 169 -140 -556 -1092 -1395 -1198 -1272 -1253 -1567 -1818 -692 -549 97 450 894 829 777 604 -377 -465 -494 -542 -301 893 693 -207 -351 -744 -1320 -28 -419 -2221 -814 -597 202 1538 1600 1554 1190 914 235 -361 237 -431 -33 -499 -286 -192 1125 534 317 -25 -1911 282 646 -489 -64 -836 -319 30 317 -491 -699 1585 526 19 -40 -442 -443 SS 20251231T120032.0Z 9496.500370 188 1 29.95 2 76.82 120.11 132.85 333.74 0.00 1 0.00 1 0 25 6.683e-02 6.590e-03 9.518e-03 7.219e-04 4.050742e-01 3.773175e-04 4.379793e-03 -6.000000e+00 3.875791e-02 224.86 -2.00 3.11 -2.00 319.78 0.00e+00 2.031608e-03 1.160501e-04 8.516446e-04 -6.000000e+00 1.791751e-03 291.99 -2.00 20.00 -2.00 318.96 0.00e+00 4.275 0.000 302.00 328.00 3 1.2001e-01 1.0955e-03 4.6000e-02 -6.0000e+00 9.5336e-02 -1.1350e-03 1.3141e-03 1.9254e-02 -6.0000e+00 1.0306e-01 -2.9482e-02 1.0164e-03 9.6983e-03 -6.0000e+00 6.1886e-02 8.7197e-03 5.3304e-04 2.9550e-03 -6.0000e+00 2.7117e-02 4.6135e-03 -1.4785e-03 2.1777e-05 3.8154e-05 -6.0000e+00 1.8867e-03 -1.1628e-01 1.6658e-04 11 8 0 10 0 0 5.20 24.57 0.27 -0.11628 -0.12739 700 700 1 5 0 42.780 27.56 20.00 24.57 31.39 5.7 1015.05 900000 -21998 -17293 -20600 -19327 -26329 -24996 -25834 -18234 -20835 -21643 -20852 -17182 -11589 -10169 -784 -4375 -869 -559 1154 -139 409 -1472 20 -1951 -1527 -2321 -3666 -4230 -4902 -3014 -3102 -280 41 -2093 -4411 -4200 -3888 -821 -465 411 437 1474 980 1224 2211 1131 562 342 -498 552 1136 677 1763 1407 1194 1477 284 137 -66 250 1051 1931 2609 2066 447 1162 -278 -46 785 -262 417 850 802 471 -104 -982 -2290 -2657 -1828 -2118 -1635 -2036 -2192 -678 -708 -169 437 722 876 569 769 -431 -470 -366 -693 -284 777 624 -243 -172 -764 -1047 -59 -347 -1694 -649 -301 220 1093 1027 866 619 606 -2 -92 145 -267 -44 -205 -263 -160 590 297 74 115 -1113 108 416 -343 -100 -466 -97 -96 327 -223 -292 722 206 -58 6 -195 -247 900000 -465 -396 -513 -458 -612 -556 -616 -452 -592 -664 -652 -556 -418 -436 -36 -242 -51 -35 75 -10 29 -106 1 -156 -129 -207 -336 -375 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