File name: Pandora60s1_Fajardo_20260115_L2Fit_fout2c14d20240201p1-8.txt File generation date: 20260205T160206.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 60 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora60_OF_v1d20230913.txt Instrument calibration file used: Pandora60s1_CF_v14d20240201.txt Level 1 file used: Pandora60s1_Fajardo_20260115_L1_smca1c14d20240201p1-8.txt Full location name: Cape San Juan Light, Fajardo (Puerto Rico) Short location name: Fajardo Country of location: Puerto Rico Location latitude [deg]: 18.3797 Location longitude [deg]: -65.6184 Location altitude [m]: 66 Local noon date: 20260115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 13 First and last pixel inside fitting window: 185 327 Nominal wavelengths inside fitting window [nm]: 305.0457 305.1868 305.3279 305.4690 305.6101 305.7511 305.8922 306.0332 306.1742 306.3153 306.4563 306.5973 306.7382 306.8792 307.0202 307.1611 307.3021 307.4430 307.5839 307.7248 307.8657 308.0066 308.1475 308.2883 308.4292 308.5700 308.7109 308.8517 308.9925 309.1333 309.2741 309.4148 309.5556 309.6964 309.8371 309.9778 310.1186 310.2593 310.4000 310.5407 310.6813 310.8220 310.9626 311.1033 311.2439 311.3845 311.5251 311.6657 311.8063 311.9469 312.0875 312.2280 312.3686 312.5091 312.6496 312.7901 312.9306 313.0711 313.2116 313.3521 313.4925 313.6329 313.7734 313.9138 314.0542 314.1946 314.3350 314.4754 314.6157 314.7561 314.8964 315.0368 315.1771 315.3174 315.4577 315.5980 315.7382 315.8785 316.0188 316.1590 316.2992 316.4394 316.5796 316.7198 316.8600 317.0002 317.1404 317.2805 317.4206 317.5608 317.7009 317.8410 317.9811 318.1212 318.2612 318.4013 318.5413 318.6814 318.8214 318.9614 319.1014 319.2414 319.3814 319.5214 319.6613 319.8013 319.9412 320.0811 320.2210 320.3609 320.5008 320.6407 320.7806 320.9204 321.0603 321.2001 321.3399 321.4797 321.6195 321.7593 321.8991 322.0389 322.1786 322.3183 322.4581 322.5978 322.7375 322.8772 323.0169 323.1565 323.2962 323.4359 323.5755 323.7151 323.8547 323.9943 324.1339 324.2735 324.4131 324.5526 324.6922 324.8317 324.9712 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260115T123656.6Z 9511.525655 170 1 29.91 2 69.75 121.75 50.31 158.68 0.00 1 0.00 1 0 17 1.974e-02 6.866e-03 1.017e-02 2.024e-03 2.959944e-01 1.037098e-03 3.246242e-03 -6.000000e+00 1.143755e-02 224.61 -2.00 3.11 -2.00 318.26 0.00e+00 1.268637e-03 1.993293e-04 3.939274e-04 -6.000000e+00 5.285121e-04 291.65 -2.00 20.00 -2.00 317.37 0.00e+00 2.858 0.000 302.00 328.00 3 3.7718e+00 2.7829e-03 3.1207e-02 -6.0000e+00 2.8121e-02 1.3830e-02 3.1746e-03 1.3759e-02 -6.0000e+00 3.0410e-02 -7.3383e-03 2.0470e-03 6.7834e-03 -6.0000e+00 1.8260e-02 -1.9814e-04 1.0693e-03 1.9678e-03 -6.0000e+00 8.0006e-03 5.1709e-04 -1.9281e-03 6.0253e-05 2.2883e-05 -6.0000e+00 5.5744e-04 -1.1564e-01 1.3446e-04 11 8 0 10 0 0 93.23 24.75 0.32 -0.11564 -0.13013 33 33 1 5 0 906.300 27.78 20.00 24.75 27.27 6.2 996.53 900000 2915 -4088 -1755 -7602 -5063 -3057 -6739 -8802 -5737 -2194 -7148 -6146 -3187 -468 -984 2339 362 754 1687 2060 929 1314 2102 756 37 626 -1139 -1211 -8 1106 -631 541 1170 -3082 -2988 -3561 -4261 -1458 -1325 -272 -764 1013 102 373 1274 677 288 -222 -1044 -76 639 914 1471 280 1172 890 71 -254 12 326 648 1471 2048 1484 450 415 -187 -329 902 -128 29 136 844 906 -60 -739 -1648 -1219 -1598 -2343 -1901 -1795 -2237 -328 -325 -21 330 651 922 395 550 -704 -400 -555 -412 -294 874 810 -211 -284 -771 -1090 -235 -17 -1203 -690 -417 17 967 1085 835 496 756 10 141 184 -108 -126 -107 -126 -16 575 157 323 -121 -1268 194 408 -392 -90 -492 -148 -186 298 -92 -341 801 371 10 -43 -318 -400 900000 160 -267 -116 -506 -326 -185 -444 -658 -462 -181 -622 -551 -314 -52 -127 297 50 108 251 349 162 228 371 143 7 130 -241 -243 -2 205 -127 118 275 -782 -719 -850 -1118 -433 -428 -102 -315 432 45 168 569 305 129 -98 -460 -34 299 458 779 159 683 532 43 -156 7 195 400 971 1467 1141 349 301 -128 -223 645 -96 24 116 711 732 -50 -553 -1135 -808 -1127 -1883 -1573 -1642 -2199 -333 -354 -24 371 752 1064 477 612 -726 -381 -522 -414 -327 1078 1023 -283 -373 -956 -1354 -275 -21 -1480 -891 -564 24 1437 1602 1305 786 1149 16 200 248 -147 -180 -163 -203 -24 923 247 484 -173 -1753 254 545 -568 -140 -806 -249 -298 497 -165 -637 1520 722 20 -82 -582 -708 SS 20260115T124212.8Z 9511.529315 173 1 29.89 2 68.69 122.42 49.88 160.05 0.00 1 0.00 1 0 17 1.691e-02 6.703e-03 7.467e-03 1.622e-03 2.851473e-01 8.287791e-04 3.111084e-03 -6.000000e+00 9.796339e-03 224.61 -2.00 3.11 -2.00 318.08 0.00e+00 1.125376e-03 1.520203e-04 3.234097e-04 -6.000000e+00 4.526306e-04 291.65 -2.00 20.00 -2.00 317.20 0.00e+00 2.725 0.000 302.00 328.00 3 3.4604e+00 2.2128e-03 2.9793e-02 -6.0000e+00 2.4086e-02 2.3570e-02 2.5160e-03 1.3172e-02 -6.0000e+00 2.6044e-02 -4.2416e-03 1.5991e-03 6.5047e-03 -6.0000e+00 1.5638e-02 -2.9671e-03 8.3272e-04 1.9006e-03 -6.0000e+00 6.8544e-03 8.1006e-04 -1.5985e-03 4.8359e-05 2.1953e-05 -6.0000e+00 4.7721e-04 -1.1720e-01 1.6443e-04 11 8 0 10 0 0 88.26 24.74 0.27 -0.11720 -0.12922 58 58 1 5 0 515.310 27.78 20.00 24.74 27.19 6.2 997.33 900000 4218 -88 1077 -3135 -1561 -8759 -2093 -3338 -5150 -5320 -5791 -3621 -6323 34 245 629 -97 2088 -407 1807 5 1703 46 865 631 220 -1323 -1316 -1301 -1475 222 141 1390 -2689 -2488 -3748 -2332 -2065 246 -940 84 823 369 615 901 512 -12 5 -1365 425 172 609 558 1092 141 1790 -232 -54 -261 475 1011 1367 2356 1435 -177 339 219 -419 1071 -788 291 690 867 499 73 -541 -1476 -1671 -1452 -1972 -1851 -1560 -2168 -454 -546 -161 142 918 566 423 320 -526 -488 -403 -372 -332 899 692 -180 -235 -550 -977 108 -66 -1526 -550 -366 192 1037 1010 814 653 462 62 -189 133 -390 204 6 -298 -308 413 175 434 204 -1110 125 262 -365 -153 -351 -149 101 473 -263 -304 665 188 116 -101 -322 -303 900000 274 -7 82 -238 -105 -605 -142 -255 -444 -486 -535 -339 -685 4 33 94 -16 342 -71 322 1 309 9 171 131 48 -292 -276 -256 -290 46 32 335 -696 -610 -917 -613 -630 88 -396 38 393 168 283 413 257 -6 3 -669 207 89 337 301 618 84 1064 -143 -33 -158 284 623 905 1682 1102 -138 245 148 -281 757 -640 255 629 786 436 59 -399 -1002 -1194 -1004 -1547 -1634 -1517 -2094 -454 -586 -184 171 1126 697 500 350 -531 -494 -400 -394 -360 1076 919 -235 -300 -713 -1175 123 -77 -1977 -745 -482 264 1497 1560 1327 1075 734 92 -259 186 -550 279 8 -465 -487 640 265 626 301 -1588 170 363 -546 -227 -550 -240 166 809 -450 -544 1210 351 217 -184 -565 -549 SS 20260115T131255.4Z 9511.550642 187 1 29.88 2 62.68 126.71 47.97 168.45 0.00 1 0.00 1 0 17 1.094e-02 6.623e-03 7.598e-04 2.765e-04 2.298948e-01 1.414370e-04 2.515077e-03 -6.000000e+00 6.336789e-03 224.61 -2.00 3.11 -2.00 317.08 0.00e+00 9.408250e-04 2.002548e-05 1.442211e-04 -6.000000e+00 2.928103e-04 291.65 -2.00 20.00 -2.00 316.22 0.00e+00 2.167 0.000 302.00 328.00 3 6.8983e-01 3.6909e-04 2.3734e-02 -6.0000e+00 1.5580e-02 1.6010e-03 4.1403e-04 1.0543e-02 -6.0000e+00 1.6849e-02 -5.5539e-03 2.4690e-04 5.1831e-03 -6.0000e+00 1.0117e-02 -9.0512e-04 1.2329e-04 1.5223e-03 -6.0000e+00 4.4325e-03 2.4422e-02 -1.8469e-03 8.1787e-06 1.8086e-05 -6.0000e+00 3.0890e-04 -1.1650e-01 7.9198e-05 11 8 0 10 0 0 99.99 24.68 0.29 -0.11650 -0.13038 1489 1489 1 5 0 20.060 27.67 20.00 24.68 29.89 6.1 1008.96 900000 32 557 791 -2104 -2542 -2725 -2718 -1016 -1324 -2620 -3722 -2170 -2284 -827 770 88 929 1461 1504 1777 925 1153 1508 371 419 208 -730 -850 -863 -127 -149 824 873 -2650 -3022 -2307 -2979 -987 -204 -433 -244 472 281 254 1023 271 -212 -216 -1017 250 562 427 935 663 515 1062 131 -120 26 482 1088 1325 2005 1184 -326 409 -467 -141 943 -529 -28 618 682 630 -115 -505 -1324 -1530 -1170 -1959 -1727 -1932 -2206 -573 -578 -215 304 618 618 386 529 -492 -263 61 -244 -106 957 698 -175 -178 -501 -854 186 35 -1483 -480 -355 -26 920 882 773 514 448 35 -69 159 -201 104 3 -174 -145 461 205 136 208 -1091 187 343 -318 -75 -440 -178 7 397 -91 -202 701 255 -85 -55 -324 -433 900000 4 80 115 -296 -322 -329 -343 -139 -201 -423 -605 -355 -414 -168 175 20 219 354 378 460 245 333 443 105 124 64 -225 -272 -258 -37 -46 268 305 -980 -1058 -788 -1115 -382 -93 -230 -141 284 174 159 635 169 -130 -129 -599 146 344 279 641 439 352 734 93 -84 18 333 772 1007 1639 1031 -285 327 -351 -103 726 -465 -27 611 671 597 -102 -405 -1061 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