File name: Pandora178s1_FountainHillsAZ_20250820_L2Fit_fwvt1c7d20250227p1-8.txt File generation date: 20251010T181354.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 178 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora178_OF_v2d20231129.txt Instrument calibration file used: Pandora178s1_CF_v7d20250227.txt Level 1 file used: Pandora178s1_FountainHillsAZ_20250820_L1_smca1c7d20250227p1-8.txt Full location name: Phoenix, Arizona - Fountain Hills Short location name: FountainHillsAZ Country of location: United States Location latitude [deg]: 33.6109 Location longitude [deg]: -111.7253 Location altitude [m]: 505 Local noon date: 20250820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on new lab analysis First and last pixel inside fitting window: 1633 1782 Nominal wavelengths inside fitting window [nm]: 492.0960 492.2172 492.3383 492.4595 492.5806 492.7017 492.8228 492.9439 493.0649 493.1860 493.3070 493.4280 493.5490 493.6700 493.7910 493.9119 494.0329 494.1538 494.2747 494.3955 494.5164 494.6373 494.7581 494.8789 494.9997 495.1205 495.2412 495.3620 495.4827 495.6034 495.7241 495.8448 495.9655 496.0861 496.2068 496.3274 496.4480 496.5686 496.6891 496.8097 496.9302 497.0507 497.1712 497.2917 497.4122 497.5326 497.6530 497.7735 497.8939 498.0142 498.1346 498.2550 498.3753 498.4956 498.6159 498.7362 498.8565 498.9767 499.0969 499.2172 499.3374 499.4575 499.5777 499.6979 499.8180 499.9381 500.0582 500.1783 500.2983 500.4184 500.5384 500.6584 500.7784 500.8984 501.0184 501.1383 501.2583 501.3782 501.4981 501.6180 501.7378 501.8577 501.9775 502.0973 502.2171 502.3369 502.4567 502.5764 502.6961 502.8159 502.9356 503.0552 503.1749 503.2945 503.4142 503.5338 503.6534 503.7730 503.8925 504.0121 504.1316 504.2511 504.3706 504.4901 504.6095 504.7290 504.8484 504.9678 505.0872 505.2066 505.3259 505.4453 505.5646 505.6839 505.8032 505.9225 506.0417 506.1610 506.2802 506.3994 506.5186 506.6378 506.7569 506.8761 506.9952 507.1143 507.2334 507.3525 507.4715 507.5905 507.7096 507.8286 507.9476 508.0665 508.1855 508.3044 508.4233 508.5422 508.6611 508.7800 508.8988 509.0177 509.1365 509.2553 509.3741 509.4928 509.6116 509.7303 509.8490 509.9677 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250820T133418.4Z 9363.565491 3 1 5.90 2 82.43 80.30 49.76 83.95 0.00 1 0.00 1 0 22 2.674e-03 2.650e-03 1.501e-04 1.499e-04 1.329505e+04 1.117599e+01 8.629270e+02 -6.000000e+00 1.581727e+02 290.72 -2.00 20.00 -2.00 505.31 0.00e+00 1.189621e-03 4.282533e-06 8.337535e-05 -6.000000e+00 7.757700e-05 290.72 -2.00 20.00 -2.00 500.52 0.00e+00 6.884106e-01 2.999777e-03 7.871523e-02 -6.000000e+00 5.346079e-02 230.28 -2.00 3.34 -2.00 502.11 0.00e+00 7.042 0.005 489.00 513.00 1 6.6808e-01 2.3096e-04 1.1819e-02 -6.0000e+00 4.1219e-03 -1.0593e-02 5.7638e-05 1.9965e-03 -6.0000e+00 1.0505e-03 3.5590e-01 1.6446e-03 1.4551e-05 7.5331e-05 -6.0000e+00 2.8507e-04 1.2486e-02 1.6438e-05 10 0 0 10 0 0 -2.33 22.76 1.60 0.01249 0.02389 502 132 1 4 0 11.650 26.11 19.98 22.76 34.26 23.4 949.73 -245 -247 266 335 -79 213 422 400 329 -143 138 134 -156 -111 -136 -175 -265 171 433 -7 66 134 37 216 245 -10 214 483 -105 -554 -28 -435 -339 429 381 -147 -199 -7 -97 -109 17 -30 -13 110 120 55 -87 -82 51 -222 -394 -372 -656 -389 -3 113 192 100 71 2 230 302 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20250820T133424.4Z 9363.565561 3 2 5.88 2 82.41 80.32 49.74 83.96 0.00 1 0.00 1 0 22 2.646e-03 2.620e-03 1.487e-04 1.484e-04 1.326707e+04 1.107909e+01 8.629068e+02 -6.000000e+00 1.565075e+02 290.72 -2.00 20.00 -2.00 505.31 0.00e+00 1.190164e-03 4.244989e-06 8.332711e-05 -6.000000e+00 7.676107e-05 290.72 -2.00 20.00 -2.00 500.52 0.00e+00 6.913113e-01 2.971979e-03 7.822610e-02 -6.000000e+00 5.289921e-02 230.28 -2.00 3.34 -2.00 502.10 0.00e+00 7.026 0.005 489.00 513.00 1 6.5092e-01 2.2895e-04 1.1780e-02 -6.0000e+00 4.0786e-03 -1.0711e-02 5.7050e-05 1.9892e-03 -6.0000e+00 1.0395e-03 3.6278e-01 1.7594e-03 1.4429e-05 7.3185e-05 -6.0000e+00 2.8206e-04 1.3101e-02 8.4916e-06 10 0 0 10 0 0 1.75 22.76 1.60 0.01310 0.02530 502 132 1 4 0 11.650 26.11 19.98 22.76 34.26 23.4 949.73 -254 -267 262 320 -50 275 420 410 346 -136 133 144 -137 -125 -154 -173 -330 109 456 12 65 127 17 209 234 9 200 488 -121 -523 2 -384 -335 429 356 -148 -150 -26 -141 -94 15 -6 -33 132 98 64 -120 -75 72 -216 -383 -386 -660 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115 127 88 38 122 41 -192 -477 -406 -267 SQ 20250820T133430.3Z 9363.565629 3 3 5.88 2 82.39 80.33 49.72 83.97 0.00 1 0.00 1 0 22 2.676e-03 2.652e-03 1.473e-04 1.470e-04 1.323946e+04 1.095738e+01 8.616016e+02 -6.000000e+00 1.583267e+02 290.72 -2.00 20.00 -2.00 505.31 0.00e+00 1.189869e-03 4.200456e-06 8.348592e-05 -6.000000e+00 7.765321e-05 290.72 -2.00 20.00 -2.00 500.52 0.00e+00 6.843999e-01 2.942307e-03 7.806174e-02 -6.000000e+00 5.351389e-02 230.28 -2.00 3.34 -2.00 502.10 0.00e+00 7.010 0.005 489.00 513.00 1 6.3579e-01 2.2652e-04 1.1756e-02 -6.0000e+00 4.1260e-03 -1.0601e-02 5.6543e-05 1.9845e-03 -6.0000e+00 1.0516e-03 3.6931e-01 1.7454e-03 1.4283e-05 7.4594e-05 -6.0000e+00 2.8534e-04 1.2856e-02 1.0303e-05 10 0 0 10 0 0 -1.96 22.76 1.60 0.01286 0.02496 502 132 1 4 0 11.650 26.11 19.98 22.76 34.26 23.4 949.73 -247 -255 306 314 -54 233 414 414 337 -109 123 110 -153 -88 -151 -177 -326 166 442 10 100 134 21 180 248 -9 219 465 -124 -550 -31 -389 -328 424 358 -158 -185 -14 -95 -101 42 -38 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