File name: Pandora178s1_FountainHillsAZ_20250920_L2Fit_fout2c10d20250717p1-8.txt File generation date: 20260219T103441.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 178 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora178_OF_v2d20231129.txt Instrument calibration file used: Pandora178s1_CF_v10d20250717.txt Level 1 file used: Pandora178s1_FountainHillsAZ_20250920_L1_smca1c10d20250717p1-8.txt Full location name: Phoenix, Arizona - Fountain Hills Short location name: FountainHillsAZ Country of location: United States Location latitude [deg]: 33.6109 Location longitude [deg]: -111.7253 Location altitude [m]: 505 Local noon date: 20250920 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0351 305.1761 305.3171 305.4581 305.5991 305.7401 305.8811 306.0220 306.1630 306.3039 306.4449 306.5858 306.7267 306.8676 307.0085 307.1494 307.2902 307.4311 307.5719 307.7127 307.8536 307.9944 308.1352 308.2759 308.4167 308.5575 308.6982 308.8390 308.9797 309.1204 309.2611 309.4018 309.5425 309.6832 309.8238 309.9645 310.1051 310.2457 310.3863 310.5270 310.6675 310.8081 310.9487 311.0892 311.2298 311.3703 311.5109 311.6514 311.7919 311.9324 312.0728 312.2133 312.3538 312.4942 312.6346 312.7751 312.9155 313.0559 313.1963 313.3366 313.4770 313.6174 313.7577 313.8980 314.0383 314.1787 314.3189 314.4592 314.5995 314.7398 314.8800 315.0203 315.1605 315.3007 315.4409 315.5811 315.7213 315.8615 316.0016 316.1418 316.2819 316.4220 316.5621 316.7022 316.8423 316.9824 317.1225 317.2625 317.4026 317.5426 317.6826 317.8226 317.9626 318.1026 318.2426 318.3826 318.5225 318.6625 318.8024 318.9423 319.0822 319.2221 319.3620 319.5019 319.6417 319.7816 319.9214 320.0613 320.2011 320.3409 320.4807 320.6204 320.7602 320.9000 321.0397 321.1794 321.3192 321.4589 321.5986 321.7383 321.8779 322.0176 322.1573 322.2969 322.4365 322.5761 322.7158 322.8553 322.9949 323.1345 323.2741 323.4136 323.5531 323.6927 323.8322 323.9717 324.1112 324.2507 324.3901 324.5296 324.6690 324.8085 324.9479 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250920T135229.4Z 9394.578118 77 1 47.45 2 82.82 93.77 69.49 96.03 0.00 1 0.00 1 0 25 7.244e-01 1.485e-02 2.830e-01 4.463e-03 7.841852e-01 2.571610e-03 8.312942e-03 -6.000000e+00 4.264016e-01 228.48 -2.00 3.34 -2.00 321.90 0.00e+00 4.958235e-03 1.621219e-03 2.039797e-03 -6.000000e+00 2.240084e-02 288.85 -2.00 20.00 -2.00 321.35 0.00e+00 7.366 0.006 302.00 328.00 3 6.5433e-01 1.0732e-02 8.0200e-02 -6.0000e+00 1.0578e+00 2.1531e-01 1.6263e-02 4.2113e-02 -6.0000e+00 1.1483e+00 -3.3493e-01 1.6372e-02 2.3654e-02 -6.0000e+00 6.8515e-01 1.3039e-01 7.2648e-03 9.1794e-03 -6.0000e+00 2.9338e-01 1.3662e-04 -9.3217e-04 1.2910e-04 1.3019e-04 -6.0000e+00 2.1068e-02 7.9569e-03 0.0000e+00 12 9 8 11 8 0 -7.29 22.82 0.33 0.00796 0.00095 162 43 1 5 0 292.880 26.21 20.00 22.82 30.34 22.4 958.93 -286951 900000 -237122 900000 900000 900000 -176321 -69550 -57982 -250979 900000 -273838 900000 -6230 900000 -161647 12140 -49293 -130220 900000 44034 -60858 -53703 900000 8682 -124544 63400 -15324 900000 -53469 -29428 -52968 23608 -15072 -53238 33670 -44599 112767 -28804 21395 21989 -12855 25295 483494 9593 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-822 -1795 -1765 -1801 -2696 474 -1817 116 -985 -748 -131 -500 398 -139 2117 -738 -1324 -1208 -5 635 1110 799 -1307 2226 2417 233 1819 -1110 128 1392 2041 -670 -373 -1046 -652 -371 2007 -1157 215 1546 574 1329 -1513 -3055 SS 20250920T140308.3Z 9394.585513 80 1 47.59 2 80.61 95.28 67.37 97.61 0.00 1 0.00 1 0 25 3.342e-01 7.085e-03 1.825e-01 1.680e-03 6.539713e-01 9.108512e-04 7.011702e-03 -6.000000e+00 1.949520e-01 228.48 -2.00 3.34 -2.00 321.12 0.00e+00 3.729996e-04 4.543293e-04 1.117340e-03 -6.000000e+00 8.824151e-03 288.85 -2.00 20.00 -2.00 320.48 0.00e+00 5.831 0.003 302.00 328.00 3 5.5467e-01 3.1724e-03 6.3960e-02 -6.0000e+00 4.8413e-01 -2.1325e-02 4.3857e-03 3.3817e-02 -6.0000e+00 5.2474e-01 2.6048e-03 4.3360e-03 1.7130e-02 -6.0000e+00 3.1373e-01 -1.0543e-02 2.0571e-03 4.9258e-03 -6.0000e+00 1.3264e-01 6.8628e-04 -5.9276e-04 4.7476e-05 6.2281e-05 -6.0000e+00 9.1684e-03 7.3975e-03 0.0000e+00 11 8 0 10 0 0 7.84 22.81 0.28 0.00740 0.00294 394 103 1 5 0 120.470 26.21 20.00 22.81 30.97 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-77 118 141 152 370 376 381 351 848 74 282 -85 46 352 451 784 963 0 -165 292 -311 1235 964 307 -77 -273 199 -627 -383 -1029 -478 -56 -788 -574 -141 -1336 -445 -47 -11 1075 413 1027 392 128 -175 -815 475 393 342 235 1274 115 -1083 -1311 -2225 -1633 388 -823 -603 -520 -848 567 965 1292 427 278 -233 -918 -151 -172 34 832 156 -534 143 1470 -127 1734 -1293 -951 1097 1086 323 -548 -955 -1273 72 919 -926 139 1060 379 546 297 -1754 SS 20250920T141211.4Z 9394.591798 85 1 47.50 2 78.74 96.57 65.56 98.98 0.00 1 0.00 1 0 17 1.914e-01 6.903e-03 3.647e-02 9.542e-04 5.681037e-01 5.046936e-04 6.153637e-03 -6.000000e+00 1.116155e-01 228.48 -2.00 3.34 -2.00 320.50 0.00e+00 3.612936e-04 2.060811e-04 6.627565e-04 -6.000000e+00 5.051948e-03 288.85 -2.00 20.00 -2.00 319.79 0.00e+00 4.944 0.002 302.00 328.00 3 4.7322e-01 1.5989e-03 5.4393e-02 -6.0000e+00 2.7718e-01 -1.6689e-02 2.0438e-03 2.8642e-02 -6.0000e+00 3.0043e-01 1.0458e-02 1.8462e-03 1.4212e-02 -6.0000e+00 1.7962e-01 -1.4820e-02 9.1852e-04 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