File name: Pandora178s1_FountainHillsAZ_20250923_L2Fit_fout2c7d20250227p1-8.txt File generation date: 20251010T183556.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 178 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora178_OF_v2d20231129.txt Instrument calibration file used: Pandora178s1_CF_v7d20250227.txt Level 1 file used: Pandora178s1_FountainHillsAZ_20250923_L1_smca1c7d20250227p1-8.txt Full location name: Phoenix, Arizona - Fountain Hills Short location name: FountainHillsAZ Country of location: United States Location latitude [deg]: 33.6109 Location longitude [deg]: -111.7253 Location altitude [m]: 505 Local noon date: 20250923 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on new lab analysis First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0255 305.1665 305.3075 305.4484 305.5894 305.7303 305.8712 306.0121 306.1530 306.2939 306.4348 306.5757 306.7165 306.8574 306.9982 307.1391 307.2799 307.4207 307.5615 307.7022 307.8430 307.9838 308.1245 308.2652 308.4060 308.5467 308.6874 308.8281 308.9688 309.1094 309.2501 309.3907 309.5314 309.6720 309.8126 309.9532 310.0938 310.2344 310.3749 310.5155 310.6560 310.7965 310.9371 311.0776 311.2181 311.3586 311.4990 311.6395 311.7800 311.9204 312.0608 312.2012 312.3417 312.4821 312.6224 312.7628 312.9032 313.0435 313.1839 313.3242 313.4645 313.6048 313.7451 313.8854 314.0257 314.1659 314.3062 314.4464 314.5867 314.7269 314.8671 315.0073 315.1475 315.2876 315.4278 315.5679 315.7081 315.8482 315.9883 316.1284 316.2685 316.4086 316.5487 316.6887 316.8288 316.9688 317.1089 317.2489 317.3889 317.5289 317.6688 317.8088 317.9488 318.0887 318.2287 318.3686 318.5085 318.6484 318.7883 318.9282 319.0680 319.2079 319.3477 319.4876 319.6274 319.7672 319.9070 320.0468 320.1866 320.3264 320.4661 320.6059 320.7456 320.8853 321.0250 321.1647 321.3044 321.4441 321.5838 321.7234 321.8631 322.0027 322.1423 322.2819 322.4215 322.5611 322.7007 322.8402 322.9798 323.1193 323.2589 323.3984 323.5379 323.6774 323.8169 323.9564 324.0958 324.2353 324.3747 324.5141 324.6536 324.7930 324.9324 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250923T135351.7Z 9397.579071 53 1 47.39 2 82.97 95.09 103.66 94.32 0.00 1 0.00 1 0 17 5.632e-01 1.280e-02 3.274e-01 4.671e-03 7.828727e-01 2.743292e-03 8.391240e-03 -6.000000e+00 3.359829e-01 228.25 -2.00 3.34 -2.00 321.88 0.00e+00 2.247468e-03 1.699460e-03 4.199134e-03 -6.000000e+00 1.713623e-02 288.56 -2.00 20.00 -2.00 321.34 0.00e+00 7.495 0.006 302.00 328.00 3 3.4049e-01 1.1251e-02 8.3482e-02 -6.0000e+00 8.3468e-01 1.3889e-01 1.7394e-02 4.9335e-02 -6.0000e+00 9.0714e-01 -2.1156e-01 1.8172e-02 2.6227e-02 -6.0000e+00 5.3555e-01 8.0404e-02 8.1030e-03 7.6188e-03 -6.0000e+00 2.2742e-01 1.6950e-04 -6.9605e-04 1.3585e-04 1.2374e-04 -6.0000e+00 1.6493e-02 1.7512e-02 -4.1594e-05 12 8 8 10 0 0 5.90 22.82 0.30 0.01751 0.01228 155 41 1 5 0 305.710 26.21 20.00 22.82 28.67 22.6 955.90 -102762 900000 -227706 900000 900000 900000 -123120 900000 900000 -101976 -145389 -277084 900000 900000 900000 -136558 -21302 -135014 -110948 86979 253078 13133 1974 900000 84515 -145866 900000 150047 18391 -1428 -30031 -75354 4494 -13555 -66771 32865 -25734 94543 -36595 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725 -542 132 904 -723 -1668 -2041 -1656 -2478 265 -885 -56 -798 -520 1114 -134 704 -650 1521 -166 -1329 563 427 1214 1068 475 -1137 1009 1992 -201 1142 -1493 240 928 1913 -2196 -736 -883 -530 -322 1350 -903 174 856 757 998 273 -2758 SS 20250923T140428.8Z 9397.586444 56 1 47.54 2 80.77 96.60 101.54 95.75 0.00 1 0.00 1 0 17 2.926e-01 7.440e-03 1.536e-01 1.681e-03 6.479524e-01 9.149648e-04 6.967557e-03 -6.000000e+00 1.705944e-01 228.25 -2.00 3.34 -2.00 321.09 0.00e+00 5.124009e-04 4.481201e-04 1.189952e-03 -6.000000e+00 7.752737e-03 288.56 -2.00 20.00 -2.00 320.44 0.00e+00 5.920 0.003 302.00 328.00 3 2.0197e-01 3.1542e-03 6.4520e-02 -6.0000e+00 4.2343e-01 7.9970e-03 4.3297e-03 3.3594e-02 -6.0000e+00 4.5919e-01 -1.0603e-02 4.2630e-03 1.7041e-02 -6.0000e+00 2.7436e-01 -6.9642e-03 2.0327e-03 4.9159e-03 -6.0000e+00 1.1678e-01 8.9664e-04 -6.9798e-04 4.8046e-05 6.2557e-05 -6.0000e+00 8.1014e-03 1.7636e-02 -8.2822e-05 11 8 0 10 0 0 1.81 22.82 0.26 0.01764 0.01239 387 102 1 5 0 122.830 26.21 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129 345 618 442 725 427 915 28 480 -177 322 287 224 876 845 168 -251 236 -565 1076 1028 178 65 -293 141 -622 -325 -1080 -332 -93 -706 -630 -524 -992 -722 30 65 1230 412 870 61 20 -366 -662 831 515 472 435 1334 133 -1103 -1197 -2601 -1566 185 -621 -729 -408 -683 532 797 1033 316 519 -282 -1196 -506 -184 40 1473 370 -206 154 1356 -433 1916 -1087 -1253 954 847 301 -464 -964 -1439 -17 1099 -727 180 863 527 430 624 -2054 SS 20250923T141410.6Z 9397.593178 61 1 47.52 2 78.77 97.99 99.62 97.05 0.00 1 0.00 1 0 25 1.627e-01 6.800e-03 3.088e-02 9.277e-04 5.570101e-01 4.903032e-04 6.065714e-03 -6.000000e+00 9.484083e-02 228.25 -2.00 3.34 -2.00 320.41 0.00e+00 2.520823e-05 1.930677e-04 7.462903e-04 -6.000000e+00 4.290003e-03 288.56 -2.00 20.00 -2.00 319.69 0.00e+00 4.955 0.002 302.00 328.00 3 1.2859e-01 1.5303e-03 5.4231e-02 -6.0000e+00 2.3542e-01 5.8568e-03 1.9359e-03 2.8247e-02 -6.0000e+00 2.5518e-01 -2.1967e-03 1.7246e-03 1.3905e-02 -6.0000e+00 1.5256e-01 -9.9057e-03 8.6468e-04 3.8859e-03 -6.0000e+00 6.4571e-02 2.4774e-03 -7.9128e-04 2.6662e-05 4.2971e-05 -6.0000e+00 4.4638e-03 1.7086e-02 -7.6776e-05 11 8 0 10 0 0 -3.14 22.80 0.23 0.01709 0.01114 668 175 1 5 0 71.130 26.21 20.00 22.80 30.16 22.7 964.78 -57722 -49414 -57281 -66984 -52703 -54763 -62990 -39155 -30766 -40198 -35809 -60726 -28755 -22107 -20944 -14056 -14173 -13281 -13918 -2708 -10349 -13076 -13886 -4620 -4925 -6827 785 -4586 -5139 -11983 -5709 -7427 -3362 -1868 -8661 -6704 -4826 -101 -1359 2393 1114 -1579 529 2909 89 468 444 -1599 1085 -1364 -115 1825 1338 2041 1142 1440 1621 983 92 435 -244 1216 1567 2223 3351 -574 -663 -744 -853 1740 1499 975 88 362 -221 -1109 -1490 -1964 -1908 -205 -819 -978 -423 -2050 -591 -223 182 649 624 1055 -57 428 -526 -540 304 901 145 318 1096 104 -488 -1034 -2010 -1777 513 -643 -704 -426 -624 361 567 907 171 291 -409 -566 -202 37 -21 693 332 -318 105 658 -41 1307 -597 -660 657 541 25 -104 -684 -589 -90 516 -369 64 519 112 158 178 -882 -433 -398 -544 -703 -439 -461 -627 -354 -295 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