File name: Pandora178s1_FountainHillsAZ_20251225_L2Fit_fwvt1c7d20250227p1-8.txt File generation date: 20251226T073509.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 178 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora178_OF_v2d20231129.txt Instrument calibration file used: Pandora178s1_CF_v7d20250227.txt Level 1 file used: Pandora178s1_FountainHillsAZ_20251225_L1_smca1c7d20250227p1-8.txt Full location name: Phoenix, Arizona - Fountain Hills Short location name: FountainHillsAZ Country of location: United States Location latitude [deg]: 33.6109 Location longitude [deg]: -111.7253 Location altitude [m]: 505 Local noon date: 20251225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on new lab analysis First and last pixel inside fitting window: 1633 1782 Nominal wavelengths inside fitting window [nm]: 492.0960 492.2172 492.3383 492.4595 492.5806 492.7017 492.8228 492.9439 493.0649 493.1860 493.3070 493.4280 493.5490 493.6700 493.7910 493.9119 494.0329 494.1538 494.2747 494.3955 494.5164 494.6373 494.7581 494.8789 494.9997 495.1205 495.2412 495.3620 495.4827 495.6034 495.7241 495.8448 495.9655 496.0861 496.2068 496.3274 496.4480 496.5686 496.6891 496.8097 496.9302 497.0507 497.1712 497.2917 497.4122 497.5326 497.6530 497.7735 497.8939 498.0142 498.1346 498.2550 498.3753 498.4956 498.6159 498.7362 498.8565 498.9767 499.0969 499.2172 499.3374 499.4575 499.5777 499.6979 499.8180 499.9381 500.0582 500.1783 500.2983 500.4184 500.5384 500.6584 500.7784 500.8984 501.0184 501.1383 501.2583 501.3782 501.4981 501.6180 501.7378 501.8577 501.9775 502.0973 502.2171 502.3369 502.4567 502.5764 502.6961 502.8159 502.9356 503.0552 503.1749 503.2945 503.4142 503.5338 503.6534 503.7730 503.8925 504.0121 504.1316 504.2511 504.3706 504.4901 504.6095 504.7290 504.8484 504.9678 505.0872 505.2066 505.3259 505.4453 505.5646 505.6839 505.8032 505.9225 506.0417 506.1610 506.2802 506.3994 506.5186 506.6378 506.7569 506.8761 506.9952 507.1143 507.2334 507.3525 507.4715 507.5905 507.7096 507.8286 507.9476 508.0665 508.1855 508.3044 508.4233 508.5422 508.6611 508.7800 508.8988 509.0177 509.1365 509.2553 509.3741 509.4928 509.6116 509.7303 509.8490 509.9677 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20251225T143723.9Z 9490.609304 30 1 47.97 2 89.37 118.93 134.33 68.34 0.00 1 0.00 1 0 43 1.015e+00 4.246e-01 4.489e-01 2.021e-01 -2.092086e+04 1.295302e+04 9.042449e+03 -6.000000e+00 6.495628e+04 279.87 -2.00 20.00 -2.00 505.76 0.00e+00 1.464195e-02 7.350274e-03 1.270133e-04 -6.000000e+00 3.412265e-02 279.87 -2.00 20.00 -2.00 502.40 0.00e+00 8.895297e+00 5.925294e+00 3.734091e-01 -6.000000e+00 2.351149e+01 223.86 -2.00 3.34 -2.00 503.34 0.00e+00 19.597 0.109 489.00 513.00 1 1.0288e+01 4.2113e-01 4.5444e-02 -6.0000e+00 1.7915e+00 -6.2972e-04 1.4243e-01 1.8016e-02 -6.0000e+00 4.7398e-01 9.5758e-07 -1.9885e-01 2.0063e-02 2.1942e-04 -6.0000e+00 1.3576e-01 -4.8058e-01 1.7633e-02 12 13 12 11 32 0 96.91 22.91 44.42 -0.48058 -1.85990 12 3 1 4 0 3997.190 26.32 20.01 22.91 20.70 22.8 962.33 247167 900000 900000 900000 151066 -9874 900000 235376 -12753 176901 46681 -28487 900000 47961 900000 73397 900000 900000 900000 -40211 900000 222704 12294 -10523 166002 900000 900000 900000 45708 193277 900000 30859 41539 900000 87551 6353 14420 222067 13245 900000 69577 48140 -3780 14168 13498 40832 264681 242030 20926 -32060 -10969 -56881 70728 -14787 900000 142997 164267 900000 106252 60347 900000 59875 27259 312103 900000 89117 6381 153370 -27928 17665 -13078 69202 57652 -817 71751 193718 900000 68534 79780 39076 155351 18393 900000 82864 51697 900000 -37479 53445 900000 7666 115995 31650 45738 -33932 115810 900000 900000 900000 -50304 81154 900000 56442 14375 115547 900000 18233 900000 22838 13105 56959 900000 6484 9567 -48308 21876 169643 900000 14817 16848 149700 8194 81893 17150 55172 -39182 5944 25777 -14838 41088 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 48383 900000 900000 900000 47314 -14039 900000 46075 -17934 40565 37540 -46755 900000 38789 900000 47374 900000 900000 900000 -77140 900000 43594 13823 -14366 41522 900000 900000 900000 39086 39936 900000 29429 36377 900000 49159 7972 17008 43470 16287 900000 49820 41077 -5198 16284 15244 34636 51812 47378 22120 -57553 -16587 -133344 48635 -23301 900000 49354 46930 900000 51450 44223 900000 42675 25746 61095 900000 45625 7307 42663 -43735 17636 -17047 41334 38486 -933 41776 37920 900000 40591 42046 30023 39213 17463 900000 43255 36937 900000 -66727 41324 900000 9442 49488 28862 35158 -55352 44759 900000 900000 900000 -86513 38524 900000 34527 13451 41844 900000 18186 900000 22672 14293 40248 900000 7132 10211 -90384 21003 40871 900000 15814 17746 43956 9510 46919 18224 39600 -67634 6548 23547 -19994 33129 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 SQ 20251225T162343.8Z 9490.683146 87 1 7.27 2 71.78 136.08 113.38 85.54 0.00 1 0.00 1 0 15 2.344e-03 2.325e-03 1.929e-04 1.925e-04 4.282058e+03 1.232633e+01 3.011377e+02 -6.000000e+00 1.329493e+02 279.87 -2.00 20.00 -2.00 505.27 0.00e+00 4.054004e-04 5.337157e-06 3.100152e-05 -6.000000e+00 6.624058e-05 279.87 -2.00 20.00 -2.00 500.46 0.00e+00 1.395920e-01 3.846847e-03 3.202884e-02 -6.000000e+00 4.681039e-02 223.86 -2.00 3.34 -2.00 502.06 0.00e+00 3.157 0.000 489.00 513.00 1 2.0089e+00 2.9535e-04 5.1014e-03 -6.0000e+00 3.5964e-03 -1.5864e-04 7.4770e-05 7.9846e-04 -6.0000e+00 9.1835e-04 1.6818e-01 1.9769e-03 1.9778e-05 3.3808e-05 -6.0000e+00 2.4977e-04 1.7736e-02 -1.0623e-05 10 0 0 10 0 0 99.77 22.91 1.61 0.01774 0.03145 514 135 1 4 0 14.130 26.32 20.00 22.91 21.53 22.4 962.11 -198 -247 232 215 -160 131 351 340 246 -158 149 95 -117 -88 -68 -153 -295 143 404 -25 82 93 -21 194 223 -33 204 470 -105 -430 44 -320 -285 390 356 -174 -148 48 -51 -39 78 62 2 148 99 53 -127 -109 88 -170 -324 -271 -550 -350 26 42 113 35 13 -76 146 243 210 262 64 -62 -88 119 42 -331 -217 -135 -248 134 150 -221 -408 -257 -205 -398 -97 -155 -452 -201 6 -85 -100 -118 -10 -92 -256 154 388 -26 -153 32 -52 -26 -205 -381 -383 -611 -216 299 -51 -159 -105 -370 -161 204 188 170 285 257 136 200 430 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3.988342e-04 1.213992e-05 3.075648e-05 -6.000000e+00 6.390248e-05 279.87 -2.00 20.00 -2.00 500.40 0.00e+00 1.654930e-01 8.767002e-03 3.161923e-02 -6.000000e+00 4.515835e-02 223.86 -2.00 3.34 -2.00 502.00 0.00e+00 3.154 0.000 489.00 513.00 1 3.4389e+00 6.7338e-04 5.0815e-03 -6.0000e+00 3.4696e-03 2.1317e-03 1.7040e-04 7.9207e-04 -6.0000e+00 8.8583e-04 4.0185e-02 1.8195e-03 4.5137e-05 3.3372e-05 -6.0000e+00 2.4101e-04 1.6563e-02 6.0757e-06 10 0 0 10 0 0 98.31 22.91 1.57 0.01656 0.02918 514 135 1 4 0 14.130 26.32 20.00 22.91 21.53 22.4 962.11 -136 -181 267 205 -161 101 251 306 279 -138 156 155 -198 -45 -80 -147 -315 189 402 -100 90 147 -3 114 126 -74 224 488 -136 -460 131 -284 -267 495 309 -190 -83 32 -65 -34 131 -46 -6 60 86 -27 -121 -26 84 -182 -285 -268 -550 -388 41 154 90 -9 25 -69 90 161 185 196 117 -3 -97 149 -7 -313 -130 -172 -299 70 129 -72 -348 -243 -191 -362 -159 -52 -455 -209 58 -17 -142 -147 -1 -121 -206 123 356 -6 -99 39 -85 -103 -134 -373 -335 -592 -232 237 -82 -103 -114 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