File name: Pandora178s1_FountainHillsAZ_20260717_L2Fit_fwvt1c10d20250717p1-8.txt File generation date: 20260718T074332.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 178 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora178_OF_v2d20231129.txt Instrument calibration file used: Pandora178s1_CF_v10d20250717.txt Level 1 file used: Pandora178s1_FountainHillsAZ_20260717_L1_smca1c10d20250717p1-8.txt Full location name: Phoenix, Arizona - Fountain Hills Short location name: FountainHillsAZ Country of location: United States Location latitude [deg]: 33.6109 Location longitude [deg]: -111.7253 Location altitude [m]: 505 Local noon date: 20260717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1633 1782 Nominal wavelengths inside fitting window [nm]: 492.1078 492.2289 492.3501 492.4712 492.5924 492.7135 492.8346 492.9556 493.0767 493.1977 493.3187 493.4397 493.5607 493.6817 493.8027 493.9236 494.0445 494.1654 494.2863 494.4072 494.5280 494.6489 494.7697 494.8905 495.0113 495.1321 495.2528 495.3736 495.4943 495.6150 495.7357 495.8564 495.9770 496.0976 496.2183 496.3389 496.4595 496.5800 496.7006 496.8211 496.9416 497.0621 497.1826 497.3031 497.4236 497.5440 497.6644 497.7848 497.9052 498.0256 498.1459 498.2663 498.3866 498.5069 498.6272 498.7474 498.8677 498.9879 499.1082 499.2284 499.3485 499.4687 499.5889 499.7090 499.8291 499.9492 500.0693 500.1894 500.3094 500.4295 500.5495 500.6695 500.7895 500.9094 501.0294 501.1493 501.2692 501.3891 501.5090 501.6289 501.7487 501.8685 501.9884 502.1082 502.2279 502.3477 502.4675 502.5872 502.7069 502.8266 502.9463 503.0659 503.1856 503.3052 503.4248 503.5444 503.6640 503.7836 503.9031 504.0226 504.1421 504.2616 504.3811 504.5006 504.6200 504.7395 504.8589 504.9783 505.0976 505.2170 505.3363 505.4557 505.5750 505.6943 505.8135 505.9328 506.0520 506.1713 506.2905 506.4097 506.5288 506.6480 506.7671 506.8862 507.0053 507.1244 507.2435 507.3626 507.4816 507.6006 507.7196 507.8386 507.9576 508.0765 508.1955 508.3144 508.4333 508.5522 508.6710 508.7899 508.9087 509.0275 509.1463 509.2651 509.3839 509.5026 509.6214 509.7401 509.8588 509.9775 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260717T142445.8Z 9694.600530 97 1 47.45 2 68.10 78.51 110.49 65.86 0.00 1 0.00 1 0 15 2.376e-03 2.355e-03 2.199e-04 2.195e-04 7.457347e+03 1.537276e+01 4.927192e+02 -6.000000e+00 1.404758e+02 290.50 -2.00 20.00 -2.00 505.27 0.00e+00 4.543256e-04 6.248406e-06 4.049570e-05 -6.000000e+00 6.889805e-05 290.50 -2.00 20.00 -2.00 500.42 0.00e+00 2.054275e-01 4.413945e-03 4.792547e-02 -6.000000e+00 4.759380e-02 231.34 -2.00 3.34 -2.00 502.02 0.00e+00 2.657 0.000 489.00 513.00 1 4.3586e+00 3.3999e-04 5.4959e-03 -6.0000e+00 3.6687e-03 -1.2255e-03 8.5630e-05 1.1585e-03 -6.0000e+00 9.3573e-04 1.6950e-02 1.9056e-03 2.2156e-05 4.1872e-05 -6.0000e+00 2.5388e-04 2.7456e-03 -1.4659e-05 10 0 0 10 0 0 99.92 22.89 1.57 0.00275 0.01596 301 79 1 4 0 157.640 26.32 20.00 22.89 28.77 17.6 963.82 -193 -266 235 277 -175 126 323 342 244 -155 82 152 -134 -58 -55 -133 -241 142 421 -21 59 100 -21 173 192 -40 195 485 -102 -457 35 -308 -313 461 356 -149 -118 55 -52 -92 98 45 -24 124 107 18 -121 -83 99 -150 -401 -307 -570 -352 39 67 125 4 25 -99 188 272 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SQ 20260717T150849.2Z 9694.631125 130 1 47.92 2 59.04 83.93 102.34 72.80 0.00 1 0.00 1 0 15 2.618e-03 2.601e-03 8.978e-04 8.947e-04 6.122165e+03 6.192993e+01 4.098267e+02 -6.000000e+00 1.547721e+02 290.51 -2.00 20.00 -2.00 505.25 0.00e+00 3.520449e-04 2.543870e-05 3.339132e-05 -6.000000e+00 7.590795e-05 290.51 -2.00 20.00 -2.00 500.33 0.00e+00 1.265678e-01 1.807704e-02 3.939921e-02 -6.000000e+00 5.242811e-02 231.34 -2.00 3.34 -2.00 501.94 0.00e+00 1.936 0.000 489.00 513.00 1 7.1899e+00 1.3928e-03 4.3087e-03 -6.0000e+00 4.0414e-03 9.4227e-03 3.5159e-04 9.4996e-04 -6.0000e+00 1.0306e-03 1.1117e-03 1.5145e-03 9.0679e-05 3.4695e-05 -6.0000e+00 2.7931e-04 7.1008e-04 1.2154e-05 11 1 0 11 8 0 99.95 22.88 1.59 0.00071 0.01122 27 7 1 4 0 1774.640 26.32 19.99 22.88 30.49 17.6 968.85 -87 -48 345 201 -300 -265 385 212 78 -57 -22 -74 244 -103 102 -400 -105 33 574 -215 334 122 -64 -3 349 67 366 345 -229 -353 275 -421 -217 545 245 -236 -69 103 -93 -134 220 114 -169 -62 216 -121 -139 -61 137 -274 -374 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174 227 33 188 101 35 -32 -119 -337 -564 -347 -232 SQ 20260717T152926.0Z 9694.645440 140 1 46.09 2 54.77 86.56 98.41 75.82 0.00 1 0.00 1 0 15 3.318e-03 3.293e-03 1.194e-03 1.190e-03 6.289271e+03 8.243480e+01 4.237871e+02 -6.000000e+00 1.961746e+02 290.51 -2.00 20.00 -2.00 505.24 0.00e+00 3.870543e-04 3.383954e-05 3.336316e-05 -6.000000e+00 9.621736e-05 290.51 -2.00 20.00 -2.00 500.33 0.00e+00 1.207360e-01 2.403555e-02 3.940986e-02 -6.000000e+00 6.647241e-02 231.34 -2.00 3.34 -2.00 501.94 0.00e+00 1.728 0.000 489.00 513.00 1 7.7239e+00 1.8512e-03 4.1547e-03 -6.0000e+00 5.1239e-03 6.7564e-03 4.6774e-04 9.5684e-04 -6.0000e+00 1.3070e-03 6.6999e-04 1.7545e-03 1.1920e-04 3.6703e-05 -6.0000e+00 3.5496e-04 -1.7481e-03 5.7762e-06 11 1 0 11 32 0 93.67 22.86 1.77 -0.00175 0.01042 13 3 1 4 0 3545.400 26.32 20.01 22.86 31.57 17.6 972.54 -83 267 46 50 -462 -230 386 381 -73 -76 72 110 266 -234 -223 -568 59 208 829 -327 191 60 31 -34 285 177 479 485 -397 -106 620 -412 -400 612 285 -172 -319 -163 -386 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